Process for the production of plastic moulded articles with improved weathering resistance

• US 5,008,148 A
• Filed: 06/12/1989
• Issued: 04/16/1991
• Est. Priority Date: 06/23/1988
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Holm, Reimer, Thurm, Siegfried, Schrader, Lutz, Leuschke, Christian, Rathmann, Dietrich
• Primary Examiner(s): Pianalto, Bernard
• Application Number:
  US07/366,719
• Time in Patent Office: 673 Days
• Field of Search: 427/42, 427/255.3, 427/160, 427/294, 427/296, 427/248.1, 428/336, 428/412, 428/697, 428/702
• US Class Current: 428/336
• CPC Class Codes: C08J 2369/00 Characterised by the use of polycarbonates; Derivatives of polycarbonates
• CPC Class Codes: C08J 2381/02 Polythioethers; Polythioether-ethers
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/06 with compositions not containing macromolecular substances
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/31507 Of polycarbonate

Abstract

This invention relates to a process for coating moulded plastic articles of thermoplastic polycarbonates or thermoplastic polyarylene sulphides with metal oxides, to the moulded plastic articles obtainable by the process according to the invention and to their technological application for outdoor use, for example for the production of coverings or facings in the building industry.

Claims

1. Process for coating moulded plastic articles of thermoplastic polycarbonates or thermoplastic polyarylene sulphides, characterised in that the moulded plastic articles are directly coated with metal oxides which absorb electromagnetic radiation at wave lengths of from 250 nm to 400 nm.

2. Process according to claim 1, characterised in that the moulded plastic articles are coated with metal oxides which absorb radiation from 270 nm to 400 nm.

3. Moulded plastic articles obtainable by the process according to claim 1.

4. A process for coating molded plastic articles comprising applying directly to a surface of said article a layer of metal oxide capable of absorbing electromagnetic radiation at wave lengths of from 250 nm to 400 nm, said article being molded from thermoplastic polycarbonate or thermoplastic polyarylene sulphide and said metal oxide being selected from the group consisting of titanium dioxide, tin dioxide and zinc oxide.

5. A process for coating molded plastic articles comprising applying to a surface of said article a layer of metal oxide capable of absorbing electromagnetic radiation at wave lengths of from 250 nm to 400 nm, said article being molded from thermoplastic polycarbonate or thermoplastic polyarylene sulphide and said metal oxide being selected from the group consisting of titanium dioxide and zinc oxide.

6. A molded plastic article prepared by the process of claim 5.

7. A process for coating a molded plastic article comprising applying to a surface of said article a layer of non-conductive metal oxide having a thickness greater than 100 nm and smaller than 2000 nm and having the capability of absorbing electromagnetic radiation at wave length of from 250 nm to 400 nm, said article being molded from thermoplastic polycarbonate or thermoplastic polyarylene sulfide and said metal oxide being selected from the group consisting of titanium dioxide and zinc oxide.

8. The article prepared by the process of claim 7.

9. A process for coating a molded article comprising applying to a surface of said article a layer of titanium dioxide having a thickness of about 440 nm and the capability of absorbing electromagnetic radiation at wave length of from 250 to 400 nm, said article being molded from thermoplastic polycarbonate or thermoplastic polyarylene sulfide.

10. The article prepared by the process of claim 9.

11. A process for coating a molded plastic article comprising applying to a surface of said article a layer of non-conductive metal oxide having the capability of absorbing at least about 80% of the electromagnetic radiation at wave length of from 280 to 330 nm, said article being molded from thermoplastic polycarbonate or thermoplastic polyarylene sulfide and said metal oxide being selected from the group consisting of titanium dioxide and zinc oxide.

12. The article prepared by the process of claim 11.

13. A process for coating a molded plastic article comprising applying to a surface of said article a non-conductive layer of titanium dioxide having the capability of absorbing at least about 80% of the electromagnetic radiation at wave length of from 280 to 330 nm, said article being molded from thermoplastic polycarbonate or thermoplastic polyarylene sulfide.

14. The article prepared by the process of claim 13.