Contact lens

• US 5,008,354 A
• Filed: 04/26/1989
• Issued: 04/16/1991
• Est. Priority Date: 04/30/1988
• Status: Expired due to Term

• Current Assignee: Hoya Corporation
• Original Assignee: Hoya Corporation
• Inventors: Nomura, Masashi, Sawamoto, Takeyuki, Tarumi, Niro
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): SAROFIM, NABIL F
• Application Number:
  US07/343,389
• Time in Patent Office: 720 Days
• Field of Search: 526/246, 351/160 H
• US Class Current: 526/246
• CPC Class Codes: C08F 20/28 containing no aromatic rings in the alcohol moiety
• CPC Class Codes: C08L 33/14 of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
• CPC Class Codes: G02B 1/043 Contact lenses

Abstract

The contact lens of the present invention consisting of a polymer comprising, as an essential component, at least one fluorine-containing monomer represented by the general formula ##STR1## (R₁ and R₂ are independently H or CH₃ and may be the same or different, l is an integer of 1-5, m is an integer of 1-2, n is an integer of 4-10, p is an integer of 8 or more, q is an integer of 0 or more, and p+q=2n+1), has high transparency, improved oxygen permeability, flexibility, hydrophilicity and no water absorbability.

Claims

1. A contact lens having no water absorbability consisting of a polymer comprising, as an essential component, at least one fluorine-containing monomer represented by the general formula ##STR14## wherein R₁ and R₂ are independently H or CH₃ and may be the same or different, l is an integer of 1-5, m is an integer of 1-2, n is an integer of 4-10, p is an integer of 8 or more, q is an integer of 0 or more, and p+q=2n+1.

2. A contact lens having no water absorbability according to claim 1, consisting of a polymer comprising, as an essential component, at least one monomer selected from the group consisting of:

(a) fluorine-containing monomers of the general formula (I) in which R₂ is H and accordingly which have an oxyethylene group and are represented by the general formula ##STR15## wherein R₁, l, m, n, p and q have the same definitions as in the general formula (I),

(b) fluorine-containing monomers of the general formula (I) in which R₂ is CH₃ and accordingly which have an oxypropylene group and are represented by the general formula ##STR16## wherein R₁, l, m, n, p and q have the same definitions as in the general formula (I), and

fluorine-containing monomers of the general formula (I) in which R₂ is both of H and CH₃ and accordingly which have an oxyethylene-oxypropylene group and are represented by the general formula ##STR17## wherein R₁ m, n, p and q have the same definitions as in the general formula (I) and l₁ is an integer of 2-5.

3. A contact lens having no water absorbability according to claim 2, wherein the ##STR18## in the general formula (Ic) is a divalent group selected from the group consisting of:

(i) an oxyethylene-oxypropylene group consisting of (a) one oxyethylene group or 2-4 oxyethylene groups in block, bonded to the formula ##STR19## and (b) one oxypropylene group or 2-4 oxypropylene groups in block, bonded to the formula --(C H₂)_m --C_n F_p H_q, wherein the total number of the group(s) (a) and the group(s) (b) is 2-5,

(ii) an oxyethylene-oxypropylene group consisting of (a) one oxypropylene group or 2-4 oxypropylene groups in block, bonded to the formula ##STR20## and (b) one oxyethylene group or 2-4 oxyethylene groups in block, bonded to the formula --(C H₂)_m --C_n F_p H_q, wherein the total number of the group(s) (a) and the group(s) (b) is 2-5, and

(iii) an oxyethylene-oxypropylene group existing between the formula ##STR21## and the formula --(C H₂)_m --C_n F_p H_q, and consisting of at least one oxyethylene group and at least one oxypropylene group randomly arranged in their total group number of 3-5.

4. A contact lens having no water absorbability according to claim 2, consisting of a homopolymer of a monomer selected from the monomer group (a), (b) or (c).

5. A contact lens having no water absorbability according to claim 2, consisting of a copolymer of two or more monomers selected from the same monomer group (a), (b) or (c).

6. A contact lens having no water absorbability according to claim 2, consisting of a copolymer of two or more monomers selected from at least two different groups of the groups (a), (b) and (c).

7. A contact lens having no water absorbability according to claim 1, wherein at least one monomer represented by the general formula (I) is contained in an amount of 40% by weight or more.

8. A contact lens having no water absorbability according to claim 1, wherein the polymer further comprises at least one monomer represented by the general formula ##STR22## wherein R₃ is H or CH₃, R₄ is a straight chain fluoroalkyl group having 4-10 carbon atoms and 9-21 fluorine atoms or a straight chain alkyl group of 2-10 carbon atoms, and X is an integer of 1 or 2.

9. A contact lens having no water absorbability according to claim 1, wherein the polymer further comprises at least one hydrophilic monomer selected from the group consisting of 2-hydroxyethyl methacrylate, N-vinylpyrrolidone, acrylamide, acrylic acid, methacrylic acid, N,N-dimethylacrylamide and 2-hydroxyethyl acrylate.

10. A contact lens having no water absorbability according to claim 1, wherein the polymer comprises at least one crosslinking monomer selected from the group consisting of ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, allyl (meth)acrylate, glycerol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, triallyl isocyanurate, 1,4-butanediol di(meth)acrylate and divinylbenzene.

11. A contact lens having no water absorbability according to claim 1, consisting essentially of a (co)polymer obtained by (co)polymerizing a monomer mixture comprising, as an essential component, at least one fluorine-containing monomer represented by the general formula (I) and, as an optical component, at least one other monomer.

12. A contact lens having no water absorbability according to claim 1, wherein the amount of monomer of the general formula (I) is 50%-97% by weight.

13. A contact lens having no water absorbability according to claim 8, consisting essentially of a copolymer comprising 50%-097% by weight of at least one fluorine-containing monomer represented by the general formula (I) and 27%-47% by weight of at least one monomer represented by the general formula (II).

14. A contact lens having no water absorbability according to claim 10, consisting essentially of a copolymer comprising 50%.97% by weight of at least one fluorine-containing monomer represented by the general formula (I) and 1%-5% by weight of at least one cross-linking monomer.

15. A contact lens having no water absorbability according to claim 8 or 10, consisting essentially of a copolymer comprising 50%-97% by weight of at least one fluorine-containing monomer represented by the general formula (I), 27%-47% by weight of at least one monomer represented by the general formula (II) and 1%-5% by weight of at least one cross-linking monomer.