Acrylate polymer-dispersed liquid crystal material and device made therefrom

• US 5,011,624 A
• Filed: 12/19/1989
• Issued: 04/30/1991
• Est. Priority Date: 12/30/1987
• Status: Expired due to Fees

• Current Assignee: Frederick G. Yamagishi, Leroy J. Miller
• Original Assignee: Frederick G. Yamagishi, Leroy J. Miller
• Inventors: Yamagishi, Frederick G., Miller, Leroy J.
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Treanor, Richard
• Application Number:
  US07/453,077
• Time in Patent Office: 497 Days
• Field of Search: 252/299.01, 252/299.5, 428/1, 350/350 R, 350/347 V, 350/320
• US Class Current: 252/299.5
• CPC Class Codes: C09K 19/544 as dispersing or encapsulating medium around the liquid crystal
• CPC Class Codes: C09K 2323/00 Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition

Abstract

A composite material includes droplets of a liquid crystal material dispersed within a matrix of a photopolymerized polymer. The material is prepared by forming a solution of the liquid crystal material and a monomer, and then polymerizing the monomer with light. The solubility of the liquid crystal material in the polymer is less than in the monomer. As polymerization progresses, a portion of the liquid crystal material separates as a second phase in the polymer matrix. The liquid crystal can be any suitable such material that is soluble in the monomer and less so in the polymer, and the monomer is a polymerizable acrylate or methacrylate. Liquid crystal devices are prepared by forming the composite material between two electrically conducting substrates.

Claims

1. A composite material, comprising a plurality of droplets of a liquid crystal material within a matrix of a polymer formed by mixing and then polymerizing by photoinduced reaction a mixture consisting essentially of a photopolymerizable monomer, a photoinitiator, and a liquid crystal having a solubility in the polymer that is less than its solubility in the corresponding monomer, wherein the monomer is selected from the group consisting of

an ester having the structure ##STR7## wherein R is selected from the group consisting of alkyl, aryl, hydroxyalkyl, and epoxyalkyl,

an ester having the structure ##STR8## wherein R is selected from the group consisting of alkyl, aryl, hydroxyalkyl, and epoxyalkyl, and

an amide having the structure ##STR9## wherein R is selected from the group consisting of alkyl, aryl, hydroxyalkyl, and epoxyalkyl.

2. The composite material of claim 1, wherein the liquid crystal material occupies from about 10 to about 60 percent of the volume of the composite material.

3. The composite material of claim 1, wherein the liquid crystal material is dispersed throughout the polymer matrix as discrete droplets.

4. The composite material of claim 1, wherein the polymer is a polymer of a monomer having the structure;

##STR10## where R is selected from the group consisting of alkyl, aryl, hydroxyalkyl, and epoxyalkyl.

5. The composite material of claim 1, wherein the polymer is a polymer of a monomer having the structure;

##STR11## where R is selected from the group consisting of alkyl, aryl, hydroxyalkyl, and epoxyalkyl.

6. The composite material of claim 1, wherein the polymer is a polymer of a monomer having the structure ##STR12## wherein R is selected from the group consisting of alkyl, aryl, hydroxyalkyl, and epoxyalkyl.

7. The composite material of claim 1, wherein the liquid crystal material is a cyanobiphenyl-containing mixture.

8. A liquid crystal display device, comprising:

a pair of spaced transparent conductive substrates; and

a composite material disposed between said substrates, said composite material comprising a plurality of droplets of a liquid crystal material within a matrix of a polymer formed by mixing and then polymerizing by photoinduced reaction a mixture consisting essentially of a photopolymerizable monomer, a photoinitiator, and a liquid crystal having a solubility in the polymer that is less than its solubility in the corresponding monomer, wherein the monomer is selected from the group consisting of an ester having the structure ##STR13## wherein R is selectected from the group consisting of alkyl, aryl, hydroxyalkyl, and epoxyalkyl,

an ester having the structure ##STR14## wherein R is selected from the group consisting of alkyl, aryl, hydroxyalkyl, and epoxyalkyl, and

an amide having the structure ##STR15## wherein R is selected from the group consisting of alkyl, aryl, hydroxyalkyl, and epoxyalkyl,

9. The display device of claim 8, wherein the liquid crystal material occupies from about 10 to about 60 percent of the volume of the composite material.

10. The display device of claim 8, wherein the liquid crystal material is dispersed throughout the polymer matrix as discrete droplets.

11. The display device of claim 8 wherein the polymer is a polymer of a monomer having the structure;

##STR16## where R is selected from the group consisting of alkyl, aryl, hydroxyalkyl, and epoxyalkyl.

12. The display device of claim 8 wherein the polymer is a polymer of a monomer having the structure;

##STR17## where R is selected from the group consisting of alkyl, aryl, hydroxyalkyl, and epoxyalkyl.

13. The display device of claim 8 wherein the polymer is a polymer of a monomer having the structure ##STR18## wherein R is selected from the group consisting of alkyl, aryl, hydroxyalkyl, and epoxyalkyl.

14. The display device of claim 8, wherein the liquid crystal material is a cyanobiphenyl-containing mixture.