Asymmetric gas separation membranes having improved strength

• US 5,013,767 A
• Filed: 09/27/1989
• Issued: 05/07/1991
• Est. Priority Date: 09/27/1989
• Status: Expired due to Fees

• Current Assignee: Permea Incorporated St Louis Missouri
• Original Assignee: Permea Incorporated (Linde Plc)
• Inventors: Malon, Raymond F., Cruse, Clint A.
• Primary Examiner(s): Foelak, Morton
• Application Number:
  US07/413,137
• Time in Patent Office: 587 Days
• Field of Search: 521/61, 521/64, 210/500.23, 210/500.41, 524/609
• US Class Current: 521/64
• CPC Class Codes: B01D 2323/08 Specific temperatures applied
• CPC Class Codes: B01D 2325/022 Asymmetric membranes
• CPC Class Codes: B01D 67/00111 Polymer pretreatment in the casting solutions
• CPC Class Codes: B01D 69/02 characterised by their properties
• CPC Class Codes: B01D 69/08 Hollow fibre membranes manufacture of hollow fibres D01D5/24, D01F1/08
• CPC Class Codes: B01D 69/085 Details relating to the spinneret
• CPC Class Codes: B01D 69/087 Details relating to the spinning process
• CPC Class Codes: D01D 5/24 with a hollow structure; Spinnerette packs therefor D01D5/38 takes precedence; producing tubes of plastic material B29D; addition of agents forming hollow filaments D01F1/08

Abstract

A dope for forming membranes and the resulting asymmetric gas separation membranes are disclosed, the membranes having graded density skins which exhibit improved permeability characteristics and increased failure pressure strength. The membranes are produced from a process utilizing membrane forming dopes of complexing solvent systems formulated from two non-solvents and one or more solvents. The non-solvents are chosen one each, from non-solvents grouped according to non-solvent strength, i.e., one strong non-solvent and one weak non-solvent which are combined with one or more solvents in an acid:base complex solvent system for dissolving high weight percent total solids of membrane forming polymers. The process for forming the membranes is also disclosed.

Claims

1. A dope suitable for use in the preparation of an asymmetric, substantially macrovoid-free membrane having potential for gas separation which do is comprised of:

(a) an aromatic sulfone polymer; and

(b) a solvent system being capable of dissolving the hydrophobic polymer in amounts greater than 30% by weight, the solvent system being comprised of;

(1) two non-solvents, being comprised of a weak non-solvent being a Lewis acid and having a Δ

σ

(σ

non-solvent-σ

polymer) of less than about ±

6 cal⁰.5 /cm¹.5 and a strong non-solvent having a Δ

σ

greater than about ±

6 cal⁰.5 /cm¹.5, the weak non-solvent and the strong non-solvent being present in amounts sufficient to lower the coagulation (g) value to less than about 2;

(2) one or more solvents being a Lewis base; and

(3) one or more complexes of solvents being a Lewis acid;

base complex.

2. The membrane forming dope according to claim 1, wherein the Lewis acid has an AN value from 47 to 63 and the Lewis base has a DN value from 26 to 30.

3. The dope according to claim 1, wherein the solvent system is miscible with water and the complex is readily disassociated by water with the component molecules of the disassociated complex being miscible with water.