Dynamically cured thermoplastic olefin polymers and process for producing the same

• US 5,013,793 A
• Filed: 07/26/1990
• Issued: 05/07/1991
• Est. Priority Date: 07/26/1990
• Status: Expired due to Term

• Current Assignee: Advanced Elastomer Systems, L.P. (Exxon Mobil Corporation)
• Original Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Dharmarajan, Narayanaswami R., Powers, Kenneth W., Wang, Hsien C., Puydak, Robert C.
• Primary Examiner(s): SECCURO JR, CARMAN J
• Application Number:
  US07/558,698
• Time in Patent Office: 285 Days
• Field of Search: 525/240, 525/195, 525/221, 525/222, 525/227
• US Class Current: 525/195
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 3/26 Carbonates; Bicarbonates
• CPC Class Codes: C08L 2205/03 containing three or more polymers in a blend
• CPC Class Codes: C08L 23/0853 Vinylacetate
• CPC Class Codes: C08L 23/0869 Acids or derivatives thereof
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08L 23/12 Polypropene
• CPC Class Codes: C08L 23/142 at least partially crystalline copolymers of propene with other olefins
• CPC Class Codes: C08L 23/16 Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
• CPC Class Codes: C08L 23/283 Halogenated homo- or copolymers of iso-olefins
• CPC Class Codes: C08L 2312/00 Crosslinking
• CPC Class Codes: C08L 25/18 Homopolymers or copolymers of aromatic monomers containing elements other than carbon and hydrogen
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/06 Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
• CPC Class Codes: C08L 61/06 of aldehydes with phenols
• CPC Class Codes: C08L 91/00 Compositions of oils, fats or waxes; Compositions of derivatives thereof

Abstract

A dynamically vulcanized thermoplastic composition is provided which comprises a polymer blend of a thermoplastic olefinic resin, and an elastomeric halogen-containing copolymer of a C₄ to C₇ isomonoolefin and a paraalkylstyrene. A process for preparing the dynamically vulcanized composition is also provided.

Claims

1. A thermoplastic composition comprising a dynamically vulcanized polymer blend of a thermoplastic olefinic resin, and an elastomeric halogen-containing copolymer of a C₄ to C₇ isomonoolefin and a paraalkylstyrene.

2. The thermoplastic composition of claim 1, wherein said thermoplastic olefinic resin is present in an amount ranging from about 10 to 90 weight percent, and said elastomeric halogen-containing copolymer is present in an amount ranging from about 10 to 90 weight percent, based on said polymer blend.

3. The thermoplastic composition of claim 1, wherein said thermoplastic olefinic resin is present in an amount ranging from about 15 to 80 weight percent, said elastomeric halogen-containing copolymer is present in an amount ranging from about 20 to 80 weight percent, based on said polymer blend.

4. The thermoplastic composition of claim 1, wherein said elastomeric halogen-containing copolymer is present in said composition as particles dispersed in said thermoplastic olefinic resin.

5. The thermoplastic composition of claim 1, wherein said elastomeric halogen-containing copolymer is at least partially vulcanized.

6. The thermoplastic composition of claim 1, wherein said elastomeric halogen-containing copolymer is fully vulcanized.

7. The thermoplastic composition of claim 1, wherein said thermoplastic olefinic resin is selected from the group consisting of high density polyethylene, polypropylene, low density polyethylene, linear low density polyethylene, very low density polyethylene, ethylene copolymer resins, plastomeric copolymers of ethylene and 1-alkene, polybutylene, and mixtures thereof.

8. The thermoplastic composition of claim 1, wherein said thermoplastic olefinic resin is selected from the group consisting of polyethylene, polypropylene and mixtures thereof.

9. The thermoplastic composition of claim 1, wherein said thermoplastic olefinic resin is an ethylene copolymer resin selected from the group consisting of a copolymer of ethylene and vinyl acetate, a copolymer of ethylene and an alpha, beta monoethylenically unsaturated monocarboxylic acid, a copolymer of ethylene and an alkyl ester of an alpha, beta monoethylenically unsaturated carboxylic acid and mixtures thereof.

10. The thermoplastic composition of claim 9, wherein said ethylene copolymer resin is a copolymer of ethylene and vinyl acetate.

11. The thermoplastic composition of claim 9, wherein said ethylene copolymer resin is a copolymer of ethylene and an alkyl acrylate selected from the group consisting of methyl acrylate, ethyl acrylate, butyl acrylate, and mixtures thereof.

12. The thermoplastic composition of claim 1, wherein said elastomeric halogen-containing copolymer comprises from about 0.5 to about 25 weight percent of said para-alkylstyrene.

13. The thermoplastic composition of claim 1, wherein said elastomeric halogen-containing copolymer comprises from above zero to about 10 weight percent of said halogen.

14. The thermoplastic composition of claim 1, wherein said halogen is selected from the group consisting of chlorine, bromine, and mixtures thereof.

15. The thermoplastic composition of claim 1, wherein said halogen comprises bromine, and wherein said bromine is chemically bound to said para-alkylstyrene.

16. The thermoplastic composition of claim 1, wherein said isomonoolefin is isobutylene and said paraalkylstyrene is para-methylstyrene.

17. The thermoplastic composition of claim 1, additionally comprising an uncured rubber.

18. The thermoplastic composition of claim 1, additionally comprising a component selected from the group consisting of a filler, a rubber compounding additive, and mixtures thereof.

19. The thermoplastic composition of claim 1, additionally comprising an additive selected from the group consisting of rubber processing oils, plasticizers and mixtures thereof.

20. A process for preparing a vulcanized thermoplastic composition, which comprises the steps of:

(a) blending a thermoplastic olefinic resin, an unvulcanized elastomeric halogen-containing copolymer of a C₄ to C₇ isomonoolefin and a para-alkylstyrene, and a vulcanization agent capable of vulcanizing said elastomeric halogen-containing copolymer; and

(b) masticating and shearing the blend resulting from step (a) at vulcanization conditions for a time sufficient to produce a vulcanized thermoplastic composition.

21. The process of claim 20, wherein an additional rubber which is not vulcanizable by said vulcanizing agent is added before said step (b) or after said step (b).

22. The process of claim 20, wherein an additional rubber which is curable by said vulcanizing agent is added to said vulcanized thermoplastic composition after said vulcanizing agent has been fully consumed.

23. The process of claim 20, wherein said vulcanized thermoplastic composition comprises crosslinked discrete particles of said elastomeric halogen-containing copolymer dispersed in said thermoplastic olefinic resin.

24. The process of claim 20, wherein said vulcanization conditions include a temperature ranging from about the melting point of said thermoplastic olefinic resin to about 250°

C.

25. The process of claim 20, wherein said thermoplastic olefinic resin is selected from the group consisting of high density polyethylene, low density polypropylene, very low density polyethylene, ethylene copolymer resins, plastomeric copolymers of ethylene and 1-alkene, polybutylene, and mixtures thereof.

26. The process of claim 20, wherein said thermoplastic olefinic resin is an ethylene copolymer resin selected from the group consisting of a copolymer of ethylene and vinyl acetate, a copolymer of ethylene and an alpha, beta monoethylenically unsaturated monocarboxylic acid, a copolymer of ethylene and an alkyl ester of an alpha, beta monoethylenically unsaturated carboxylic acid and mixtures thereof.

27. The process of claim 26, wherein said ethylene copolymer resin is a copolymer of ethylene and vinyl acetate.

28. The process of claim 26, wherein said ethylene copolymer resin is a copolymer of ethylene and an alkyl acrylate selected from the group consisting of methyl acrylate, ethyl acrylate, butyl acrylate, and mixtures thereof.

29. The process of claim 20, wherein said elastomeric halogen-containing copolymer comprises from about 0.5 to about 25 weight percent of said paraalkylstyrene.

30. The process of claim 20, wherein said elastomeric halogen-containing copolymer comprises from above zero to about 10 weight percent of said halogen.

31. The process of claim 20, wherein said halogen is selected from the group consisting of chlorine, bromine, and mixtures thereof.

32. The process of claim 20, wherein said halogen comprises bromine and wherein said bromine is chemically bound to said para-alkylstyrene.

33. The process of claim 20, wherein said isomonoolefin is isobutylene and said para-alkylstyrene is para-methylstyrene.

34. The process of claim 20, wherein said vulcanized thermoplastic composition comprises from about 10 to about 90 weight percent of said thermoplastic olefinic resin, and from about 10 to about 90 weight percent of said elastomeric halogen-containing copolymer, based on the weight of said thermoplastic olefinic resin plus said elastomeric halogen-containing copolymer.