Electromagnet for an atomic absorption spectrometer

• US 5,015,093 A
• Filed: 11/07/1989
• Issued: 05/14/1991
• Est. Priority Date: 03/18/1988
• Status: Expired due to Fees

• Current Assignee: Berthold GmbH & Company KG
• Original Assignee: Bodenseewerk Perkin-Elmer GmbH (Revvity, Inc.)
• Inventors: Rogasch, Klaus P.
• Primary Examiner(s): Evans, F. L.
• Application Number:
  US07/435,431
• Time in Patent Office: 553 Days
• Field of Search: 356/307, 356/315, 356/312, 356/319
• US Class Current: 356/307
• CPC Class Codes: G01N 2021/3111 using Zeeman split
• CPC Class Codes: G01N 21/3103 Atomic absorption analysis
• CPC Class Codes: G01N 21/74 using flameless atomising, e.g. graphite furnaces
• CPC Class Codes: H01F 7/20 without armatures cores H01F3/00; coils H01F5/00 ; shaping metal by applying magnetic forces B21D26/14; electromagnets specially adapted for NMR applications G01R33/381

Abstract

A solenoid serves for generating a magnetic field at the location of a sample which is to be atomized in an atomic absorption spectrometer. A shift of the absorption lines of the atoms in a sample relatively to the emission lines in a measuring light beam (18) passed through the atomized sample is effected by the magnetic field due to the Zeeman effect. The solenoid (44) comprises a pair of pole pieces (46, 48) between which an air gap is formed. An atomizing device atomizes the sample within this air gap. Field coils generate a magnetic flux through the pole pieces (46, 48), the air gap and a magnetic return path (76). The field coils (60, 62) are arranged on pole pieces (46, 48) close to the air gap. The windings of the field coils (60, 62) are formed by tubes (216) which are designed to permit passage of a cooling liquid therethrough.

Claims

1. Solenoid for generating a magnetic field at the location of a sample in an atomic absorption spectrometer, wherein a shift of the absorption lines of the atoms of the element looked for in the sample relative to the emission lines of this element in a measuring light beam passed through an atomized sample is caused by the magnetic field due to the Zeeman effect, comprising

(a) a pair of pole pieces (46, 48) between which an air gap is formed, an atomizing device atomizing the sample within this air gap,

(b) a magnetic return path (76) connecting the pole pieces (46, 48),

(c) field coils (60, 62) for generating a magnetic flux through the pole pieces (46, 48), the air gap and the magnetic return path (76),

characterized in that

(d) the field coils (60, 62) are arranged on the pole pieces (46, 48) close to the air gap, and

(e) the windings of the field coils (60, 62) are formed by tubes through which a cooling liquid can be passed.

2. Solenoid as set forth in claim 1, characterized in that

(a) the pole pieces (46, 48) are provided with aligned apertures (50, 52) for the passage of the measuring light beam (18),

(b) a contact carrier is arranged on the pole pieces (48, 50), a contact the axis of which extends parallel to the axis of the measuring light beam (18) being supported in the contact carrier for holding a transversely heated furnace (130) for the electrothermal atomization of the sample in the air gap of the solenoid (44) and for the current supply to this furnace (130).

3. Solenoid as set forth in claim 2, characterized in that the contact carrier is integral with coil holders (56, 58) which carry the field coils (60, 62) and is attached to both pole pieces with the coil holders (56, 58).

4. Solenoid as set forth in claim 1, characterized in that the pole pieces (46, 48) are frustro conically tapered at their ends facing each other.

5. Solenoid as set forth in claim 4, characterized in that pole faces (47 and 49, respectively) formed by the frustro conical tapering correspond to saturation induction.

6. Solenoid is set forth in claim 4, characterized in that the surface lines of frustro-conically tapered sections of the pole pieces (46, 48) form an angle of 63°

with the axes of the pole pieces.

7. Solenoid as set forth in claim 4, characterized in that

(a) coil holders (56, 58) are attached to the pole pieces (46, 48) consisting of a hub portion (106, 108) matching the shape of the pole piece (46, 48) and of flanges (98, 100;

102,

     104) projecting radially from the ends of the hub portion, and

(b) the windings of the field coils (60,

     62) are wound close to the pole surface (47 and 49, respectively) on the coil holders (106,

     108) in the area of the frustro conically tapered sections.

8. Solenoid as set forth in claim 1, characterized in that the pole pieces (46, 48) are made of a glued metal powder compound material.

9. Solenoid as set forth in claim 1, characterized in that the windings of the field coils (60, 62) are wound on slotted coil holders (56, 58) and consist of heat conductive material.