Isotropic microporous syndiotactic polystyrene membranes and processes for preparing the same

• US 5,015,275 A
• Filed: 07/14/1989
• Issued: 05/14/1991
• Est. Priority Date: 07/14/1989
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Lundgard, Richard A., Wan, Hawk S., Mahoney, Robert D., Beck, Henry N.
• Primary Examiner(s): Spitzer, Robert
• Application Number:
  US07/380,227
• Time in Patent Office: 669 Days
• Field of Search: 55/16, 55/158, 210/500.34, 264/46.1, 264/46.3
• US Class Current: 210/500.34
• CPC Class Codes: B01D 2323/08 Specific temperatures applied
• CPC Class Codes: B01D 2323/081 Heating
• CPC Class Codes: B01D 2323/12 Specific ratios of components used
• CPC Class Codes: B01D 2325/02 Details relating to pores or porosity of the membranes
• CPC Class Codes: B01D 2325/0283 Pore size
• CPC Class Codes: B01D 67/0009 by phase separation, sol-gel transition, evaporation or solvent quenching
• CPC Class Codes: B01D 67/00091 by evaporation
• CPC Class Codes: B01D 67/0027 by stretching
• CPC Class Codes: B01D 67/003 by selective elimination of components, e.g. by leaching
• CPC Class Codes: B01D 71/28 Polymers of vinyl aromatic compounds
• CPC Class Codes: B01D 71/281 Polystyrene

Abstract

This invention relates to semi-permeable isotropic syndiotactic polystyrene microporous membranes and processes for preparing such membranes.

Claims

1. A semi-permeable membrane comprising a thin isotropic syndiotactic polystyrene microporous membrane.

2. The membrane of claim 1 wherein the membrane is in hollow fiber form.

3. The membrane of claim 1 wherein the porosity is in the range of about 5 to about 90 percent.

4. The membrane of claim 3 wherein the membrane is useful for ultrafiltration, microfiltration, membrane distillation, membrane stripping, and/or as a support for a composite gas or liquid separation membrane.

5. The membrane of claim 4 wherein the mean pore size is in the range of about 5 to about 1000 Angstroms for ultrafiltration membranes and about 0.02 to about 10 microns for microfiltration, membrane distillation, and/or membrane stripping membranes.

6. The membrane of claim 5 wherein the membrane is useful for ultrafiltration and possesses a maximum pore size which exhibits a bubble point with denatured alcohol in the range of about 90-100 psig or greater.

7. The membrane of claim 5 wherein the gas flux for nitrogen is at least ##EQU10##

8. The membrane of claim 5 wherein the flux of water at 50 psig is at least about 1 GFD.

9. A process for preparing a semi-permeable isotropic syndiotactic polystyrene microporous membrane comprising the steps of;

A. forming a mixture comprising;

(i) syndiotactic polystyrene, and

(ii) at least one solvent for the syndiotactic polystyrene;

B. heating the mixture to a temperature under conditions such that a homogeneous fluid is formed which possesses sufficient viscosity to be formed into a membrane;

C. extruding or casting the homogeneous fluid into a membrane;

D. quenching or coagulating the membrane by passing the membrane through one or more zones under conditions such that the membrane solidifies; and

E. simultaneously or consecutively leaching the membrane by passing the membrane through one or more zones under conditions such that at least a substantial portion of the solvent for the syndiotactic polystyrene is removed from the membrane;

wherein the semi-permeable membrane so formed possesses isotropic microporous structure.

10. A process for preparing a semi-permeable isotropic syndiotactic polystyrene microporous membrane comprising the steps of;

A. forming a mixture comprising;

(i) syndiotactic polystyrene,

(ii) at least one solvent for the syndiotactic polystyrene, and

(iii) at least one non-solvent for the syndiotactic polystyrene;

B. heating the mixture to a temperature under conditions such that a homogeneous fluid is formed which possesses sufficient viscosity to be formed into a membrane;

C. extruding or casting the homogeneous fluid into a membrane;

D. quenching or coagulating the membrane by passing the membrane through one or more zones under conditions such that the membrane solidifies; and

E. simultaneously or consecutively leaching the membrane by passing the membrane through one or more zones under conditions such that at least a substantial portion of the solvent and non-solvent for the syndiotactic polystyrene is removed from the membrane;

wherein the semi-permeable membrane so formed possesses isotropic microporous structure.

11. The process of claim 9 or 10 which further comprises;

F. drawing the membrane before, during, and/or after leaching at a temperature at or above ambient temperature and below the melting point of the syndiotactic polystyrene or the depressed melting point of the mixture to elongate the membrane and to induce orientation of the syndiotactic polystyrene in the membrane.

12. The process of claim 11 wherein the amount of syndiotactic polystyrene in the mixture is between about 5 and about 90 weight percent.

13. The process of claim 12 wherein the homogeneous fluid is extruded or cast at a temperature of between about 25 and about 325°

C.

14. The process of claim 13 wherein the membrane is quenched by passing the membrane through an air zone wherein the membrane begins to solidfy.

15. The process of claim 14 wherein the temperature of the air quench zone is between about 0 and about 100°

C.

16. The process of claim 11 which further comprises:

G. before or after leaching and/or drawing, the membrane is annealed by exposing the membrane to a temperature above the glass transition temperature of the syndiotactic polystyrene or the mixture and about 10°

C. below the melting point of the syndiotactic polystyrene or the depressed melting point of the mixture for a period of time between about 30 seconds and about 24 hours.

17. The processing of claim 10 wherein the membrane is quenched by:

(i) passing the membrane through one or more liquid zones comprising a liquid which is a solvent for the syndiotactic polystyrene solvent and non-solvent and which is not a solvent for the syndiotactic polystyrene, wherein the membrane is solidified and a portion of the syndiotactic polystyrene solvent and non-solvent is removed;

or

(ii) passing the membrane through one or more liquid zones comprising a liquid which is not a solvent for the syndiotactic polystyrene solvent and non-solvent and which is not a solvent fore the syndiotactic polystyrene, wherein the membrane is solidified.

18. The process of claim 17 wherein the temperature of the liquid quench zone(s) is between about 0 and about 100°

C.

19. The process of claim 18 wherein the quench liquid is water, a lower alcohol, a halogenated hydrocarbon, or a perhalogenated carbon compound.

20. The process of claim 19 wherein the membrane is drawn at a temperature of between about 10 and about 280°

C.

21. The process of claim 20 wherein the membrane is drawn to an elongation ratio of between about 1.05 and about 10.