Method and means for refinery gas plant operation

• US 5,015,364 A
• Filed: 06/21/1989
• Issued: 05/14/1991
• Est. Priority Date: 06/21/1989
• Status: Expired due to Fees

• Current Assignee: Caterpillar Incorporated, Mobil Oil Corporation (Exxon Mobil Corporation)
• Original Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Inventors: Harandi, Mohsen N.
• Primary Examiner(s): Davis, Curtis R.
• Assistant Examiner(s): Diemler, William
• Application Number:
  US07/369,169
• Time in Patent Office: 692 Days
• Field of Search: 208/97, 208/236, 208/254 R, 208/289, 208/208 R, 423/229, 585/860
• US Class Current: 208/236
• CPC Class Codes: C10G 21/00 Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents C10G17/00, C10G19/00 take precedence
• CPC Class Codes: C10G 5/04 with liquid absorbents
• CPC Class Codes: C10G 70/048 by liquid-liquid extraction
• CPC Class Codes: C10G 70/06 by gas-liquid contact

Abstract

A process is disclosed for operating a refinery gas plant such as the unsaturated gas plant of a catalytic hydrocarbon conversion process that results in a reduction of the corrosive effect of acid gases on the gas plant vessels and equipment. The process comprises contacting acidic hydrocarbon feedstreams to an unsaturated gas plant separator zone with lean acid gas absorbing absorbent in an absorbtion zone comprising at least one liquid absorber bed and one vapor absorber bed. The liquid and vapor absorber beds are located upstream of the separator zone. The feedstreams to the gas plant comprise unstabilized, or wild, liquid gasoline and liquid and vapor output streams from the liquid-vapor separator for inter-stage wet gas compressor of the conversion process main fractionator. Accordingly, these feedstreams are deacidified before separation in the USGP deethanizer-absorber, sponge absorber, and debutanizer. This also eliminates the need for deacidification of the gas plant product stream.

Claims

1. A process for operating an unsaturated gas plant of a catalytic hydrocarbon conversion process, comprising;

contacting acidic hydrocarbon feedstreams to a gas plant separator zone with lean acid absorbing absorbent in an absorption zone comprising at least one liquid absorber bed and one vapor absorber bed upstream of said separator zone, said feedstreams comprising unstabilized liquid gasoline and liquid and vapor output streams from liquid-vapor separator for inter-stage liquids and compressor effluents from said conversion process main fractionator, whereby said feedstreams are deacidified.

2. The process of claim 1 wherein said separator zone comprises deethanizer zone and debutanizer zone.

3. The process of claim 2 further comprising introducing deacidified liquid and vapor effluent from said absorption zone to said deethanizer zone;

and separating an overhead stream comprising deacidified fuel gas and a bottoms stream comprising deacidified LPG and C₅ + hydrocarbons.

4. The process of claim 3 further comprising, passing said deacidified LPG and C₅ + hydrocarbons to debutanizer zone;

and separating an overhead stream comprising LPG and a bottoms stream comprising C₅ + hydrocarbons.

5. The process of claim 1 further comprising;

(a) combining said unstabilized gasoline and said liquid output stream and countercurrrently contacting combined streams with said lean absorbent in said liquid absorber bed to produce deacidified liquid hydrocarbon effluent;

(b) passing step (a) hydrocarbon effluent to said saparator zone;

(c) passing partially acidified absorbent from said liquid absorber bed to said vapor absorber bed;

(d) contacting said vapor output stream countercurrently with said partially acidified absorbent in said vapor absorber bed to produce deacidified vapor hydrocarbon effluent;

(e) passing step (d) vapor hydrocarbon effluent to said separator zone;

(f) withdrawing rich absorbent from said vapor absorber bed.

6. The process of claim 5 wherein fresh, lean absorbent is mixed with step (c) partially acidified absorbent.

7. The process of claim 1 wherein said absorption zone comprises a first and second liquid absorber bed and a vapor absorber bed.

8. The process of claim 7 further comprising;

deacidifying said liquid output stream in said first absorber bed in countercurrent contact with said lean absorbent;

passing partially acidified absorbent from said first bed to said second bed and deacidifying said gasoline therein in countercurrent contact with said partially acidified absorbent and fresh, lean absorbent;

passing partially acidified absorbent from said second bed to said vapor bed and deacidifying said vapor output therein in countercurrent contact with said partially acidified absorbent and fresh, lean absorbent;

passing deacidified liquid output stream, gasoline stream and vapor stream from said absorption zone to said separator zone.

13. The process of claim 1 wherein said lean absorbent comprises fresh absorbent.

9. A method for deacidifying acidic liquid and vapor hydrocarbon feedstreams to a catalytic hydrocarbon conversion process unsaturated gas plant, comprising:

contacting said liquid feedstreams in an absorber bed with acid absorbing absorbent in countercurrent flow;

withdrawing deacidified liquid feedstreams and passing said deacidified liquid feedstreams to said unsaturated gas plant deethanizer-debutanizer separator zone;

contacting said vapor feedstream in an absorber bed with acid absorbing absorbent in countercurrent flow;

withdrawing deacidified vapor feedstream and passing said deacidified vapor feedstream to said unsaturated gas plant deethanizer-debutanizer separator zone.

10. The method of claim 9 further comprising passing partially acidified absorbent from said liquid feedstreams absorber bed to said vapor feedstream absorber bed in combination with acid-lean absorbent;

and withdrawing acidrich absorbent therefrom.

11. The method of claim 9 wherein said acidic liquid and vapor hydrocarbon feedstreams comprise unstabilized liquid gasoline, plus the liquid and vapor output streams from a liquid-vapor separator of the cooled and combined streams comprising inter-stage liquid and the compressor effluent from said conversion process main fractionator.

12. The method of claim 9 wherein said absorbent is diethanolamine.