Water-based composites with superior cure in thick films, and chemical and shock resistance

• US 5,017,632 A
• Filed: 12/14/1989
• Issued: 05/21/1991
• Est. Priority Date: 12/14/1989
• Status: Expired due to Fees

• Current Assignee: Rohm and Haas Company (Dow, Inc.)
• Original Assignee: Rohm and Haas Company (Dow, Inc.)
• Inventors: Schindler, Frederick J., Warburton, Charles E. Jr., Bredow, Charles W.
• Primary Examiner(s): Kight, III, John
• Assistant Examiner(s): Shelborne, Kathryne E.
• Application Number:
  US07/450,794
• Time in Patent Office: 523 Days
• Field of Search: 523/409, 523/413, 523/412, 523/406, 523/400
• US Class Current: 523/400
• CPC Class Codes: C04B 28/04 Portland cements
• CPC Class Codes: C04B 40/065 Two or more component mortars
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/4853 Epoxides
• CPC Class Codes: C04B 41/4857 Other macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C04B 41/4905 containing silicon
• CPC Class Codes: C04B 41/5035 Silica
• CPC Class Codes: C04B 41/63 Macromolecular compounds
• CPC Class Codes: C08K 5/5435 containing oxygen in a ring
• CPC Class Codes: C08K 5/544 containing nitrogen
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C09D 163/00 Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins

Abstract

A coating composition is used for coating or overlaying Portland cement concrete or metal. The composition includes a synthetic polymer latex, an amine-functional epoxy curing agent, an epoxy-functional or amine-functional silane, a liquid epoxy resin, and a filler having a fine particle size. The coating composition has superior crack resistance and low cost in comparison with epoxy/amine-type polymer concrete, and excellent strength development, chemical resistance, and rapid cure in thick films in comparison with latex-based cementitious compositions. The coating composition can be mixed from a pair of storage-stable components; a dry mix including the fine particle size filler and the epoxy resin, and optionally larger size aggregate, and a wet mix including the polymer latex, the silane, and the amine curing agent. The two components can be mixed on site to give a fluid coating composition having a long pot life and low viscosity, which rapidly develops strength, and ultimately develops high compressive strength, thermal shock resistance, and resistance to chemical attack, especially attack by aqueous acids.

Claims

1. A coating composition for use in coating or overlaying Portland cement concrete or metal, the composition comprising:

(a) a synthetic polymer latex;

(b) an amine-functional epoxy curing agent, the epoxy curing agent being soluble or dispersible in water;

(c) a silane selected from the class consisting of epoxy-functional silanes and amine-functional silanes;

(d) a liquid epoxy resin; and

(e) filler having a fine particle size.

2. A composition according to claim 1 wherein the synthetic polymer latex comprises a synthetic polymer selected from acrylic polymers, styrene/acrylic copolymers, styrene/butadiene copolymers, chlorinated vinyl polymers, and hydrophobic vinyl acetate copolymers.

3. A composition according to claim 2 wherein the glass transition temperature of the synthetic polymer is from about 0°

C. to 30°

C.

4. A composition according to claim 1 wherein the polymer latex includes less than about 2 percent by weight of polymer solids of nonionic emulsifier.

5. A composition according to claim 1 wherein the synthetic polymer latex provides from about 60 to 75 percent by weight of the total organic solids of the composition.

6. A composition according to claim 1 wherein the filler having a fine particle size is a silica.

7. A composition according to claim 6 wherein the fine particle size filler has a mean particle size of from about 2 to 50 microns.

8. A composition according to claim 7 wherein the mean particle size of the fine particle size silica is from about 2 to 20 microns.

9. A composition according to claim 8 wherein the mean particle size of the fine particle size silica is from about 4 to 6 microns.

10. A composition according to claim 1 additionally comprising coarse aggregate.

11. A composition according to claim 10 wherein the coarse aggregate is sand.

12. A composition according to claim 11 wherein the sand is a mixture of a first sand having particles with an average particle size of about 20 to 30 mesh and a second sand having an average particle size of about 70 mesh.

13. A composition according to claim 1 wherein the silane is an aminoalkyltrialkoxysilane.

14. A composition according to claim 1 wherein the silane is a glycidyloxyalkyltrialkoxysilane.

15. A composition according to claim 1 wherein the amine-functional epoxy curing agent is a diamine oligomer of ethylene glycol.

16. A composition according to claim 1 wherein the amine-functional epoxy curing agent is a diamine oligomer of propylene glycol.

17. A curable latex composition for use in preparing a composition for coating or overlaying Portland cement concrete, the curable latex composition comprising:

(a) a synthetic polymer latex;

(b) an amine-functional epoxy curing agent, the epoxy curing agent being soluble or dispersible in water; and

(c) a silane selected from the class consisting of epoxy-functional silanes and amine-functional silanes.

18. A two-component composition for use in coating or overlaying Portland cement concrete, the composition comprising:

(a) a first component including;

(1) a synthetic polymer latex;

(2) an amine-functional epoxy curing agent, the epoxy curing agent being soluble or dispersible in water; and

(3) a silane selected from the class consisting of epoxy-functional silanes and amine-functional silanes; and

(b) a second component including;

(1) a liquid epoxy resin; and

(2) filler having a fine particle size,

the first component and second component being mixed to provide the coating composition.

19. A process for protecting a Portland cement concrete surface, the process comprising:

(a) applying a fluid protective coating composition to the surface, the coating composition comprising;

(1) a synthetic polymer latex;

(2) an amine-functional epoxy curing agent, the epoxy curing agent being soluble or dispersible in water;

(3) a silane selected from the class consisting of epoxy-functional silanes and amine-functional silanes;

(4) a liquid epoxy resin; and

(5) filler having a fine particle size; and

(b) permitting the coating composition to cure to form a protective coating.

20. A composite comprising a Portland cement concrete substrate and a protective coating, where the protective coating is on a least a portion of the substrate and where the protective coating comprises:

(a) a synthetic polymer latex;

(b) an amine-functional epoxy curing agent, the epoxy curing agent being soluble or dispersible in water;

(c) a silane selected from the class consisting of epoxy-functional silanes and amine-functional silanes;

(d) a liquid epoxy resin; and

(e) filler having a fine particle size.