Thermosetting organosiloxane composition
First Claim
1. In a thermosetting organosiloxane composition comprising(A) an organopolysiloxane having at least two silicon-bonded alkenyl groups in each molecule and represented by the average unit formula
wherein R is a substituted or unsubstituted monovalent hydrocarbon radical an the value of a is from 1.0 to 2.3;
(B) an organohydrogenpolysiloxane containing at least two silicon-bonded hydrogen atoms in each molecule in an amount sufficient to cure said organopolysiloxane;
(C) an amount of a hydrosilylation-reaction catalyst sufficient to promote curing of said composition, where said catalyst is microencapsulated by a thermoplastic resin exhibiting a softening point of 40 to 250 degrees Centigrade;
the improvement comprising the presence in said composition of(D) a hydrosilylation reaction-inhibiting compound selected from the group consisting of (1) compounds containing at least 1 alkynyl group in each molecule, (2) organosilicon compounds selected from the group consisting of ##STR3## and (3) disiloxanes and cyclotetrasiloxanes containing at least one bonding unit in which an alkenyl radical is bonded to each of two silicon atoms joined through an oxygen atom bridge, where the amount of said inhibiting compound is sufficient to accelerate curing of said composition at temperatures above the softening point of said thermoplastic resin.
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Abstract
The combination of a microencapsulated hydrosilylation catalyst selected from the group consisting of metals from the platinum group of the periodic table and compounds of these metals and a known inhibitor for this type of catalyst impart excellent storage stability to organosiloxane compositions that cure by a hydrosilation reaction while enabling these compositions to rapidly cure at temperatures above the softening temperature of the thermoplastic resin used to encapsulate the hydrosilylation catalyst. The curing rate of the composition is faster relative to compositions containing the microencapsulated catalyst without the catalyst inhibitor.
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Citations
4 Claims
- 1. In a thermosetting organosiloxane composition comprising
(A) an organopolysiloxane having at least two silicon-bonded alkenyl groups in each molecule and represented by the average unit formula - space="preserve" listing-type="equation">R.sub.a SiO.sub.(4-a)/2
wherein R is a substituted or unsubstituted monovalent hydrocarbon radical an the value of a is from 1.0 to 2.3; (B) an organohydrogenpolysiloxane containing at least two silicon-bonded hydrogen atoms in each molecule in an amount sufficient to cure said organopolysiloxane; (C) an amount of a hydrosilylation-reaction catalyst sufficient to promote curing of said composition, where said catalyst is microencapsulated by a thermoplastic resin exhibiting a softening point of 40 to 250 degrees Centigrade; the improvement comprising the presence in said composition of (D) a hydrosilylation reaction-inhibiting compound selected from the group consisting of (1) compounds containing at least 1 alkynyl group in each molecule, (2) organosilicon compounds selected from the group consisting of ##STR3## and (3) disiloxanes and cyclotetrasiloxanes containing at least one bonding unit in which an alkenyl radical is bonded to each of two silicon atoms joined through an oxygen atom bridge, where the amount of said inhibiting compound is sufficient to accelerate curing of said composition at temperatures above the softening point of said thermoplastic resin. - View Dependent Claims (2, 3, 4)
Specification