Protected silvered substrates and mirrors containing the same

• US 5,019,458 A
• Filed: 04/19/1989
• Issued: 05/28/1991
• Est. Priority Date: 05/12/1988
• Status: Expired due to Term

• Current Assignee: Solel Solar Systems Ltd. (Siemens AG)
• Original Assignee: LUZ Industries Israel Ltd.
• Inventors: Elgat, Zvi, Warschawski, Joel P.
• Primary Examiner(s): Dean, R.
• Assistant Examiner(s): WYSZOMIERSKI, GEORGE P
• Application Number:
  US07/340,421
• Time in Patent Office: 769 Days
• Field of Search: 428/630, 428/632, 428/633, 428/673, 428/432, 428/433, 428/434, 350/641, 350/642, 126/417
• US Class Current: 428/630
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3615 Coatings of the type glass/metal/other inorganic layers, at least one layer being non-metallic
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3621 one layer at least containing a fluoride
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3663 specially adapted for use as mirrors
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant
• CPC Class Codes: Y10T 428/12597 Noncrystalline silica or noncrystalline plural-oxide component [e.g., glass, etc.]
• CPC Class Codes: Y10T 428/12611 Oxide-containing component
• CPC Class Codes: Y10T 428/12618 Plural oxides
• CPC Class Codes: Y10T 428/12896 Ag-base component

Abstract

The invention provides a protected silvered substrate of the type comprising in combination, a substrate having a layer of substantially silver deposited thereon, a layer of aluminum oxide secured to the silver layer, and a layer of silicon dioxide secured to the layer of aluminum oxide, characterized by a layer of zinc sulfide between the layer of substantially silver and the layer of aluminum oxide to improve the adhesion of the alumina to the silver and front surface mirrors and low emissivity glass utilizing the same.

Claims

1. A protected silvered substrate comprising in combination, a substrate having a layer of substantially silver deposited thereon, a layer of aluminum oxide secured to said silver layer, and a layer of silicon dioxide secured to said layer of aluminum oxide, and including a layer of zinc sulfide between said layer of substantially silver and said layer of aluminum oxide to improve the adhesion of said alumina to said silver, and further including a layer of Al₂ O₃ or chromium-nickel alloy between said substrate and said layer of substantially silver to improve the adhesion of said silver layer to said substrate.

2. A protected silvered substrate according to claim 1 wherein said silver layer is substantially pure silver.

3. A protected silvered substrate according to claim 1 wherein said silver layer is comprised of a silver metal alloy selected from the group:

nickel-chromium-iron-silver, chromium-nickel-silver and chromium-silver.

4. A protected silvered substrate according to claim 1 wherein said Al₂ O₃ and SiO₂ are deposited using sputtering, electron beam evaporation and/or cathodic arc plasma deposition techniques.

5. A weather and abrasion resistance front surface solar concentrator mirror comprising a substrate having a layer of substantially silver, deposited on the outer surface thereof, a layer of zinc sulfide secured to said silver layer, a layer of aluminum oxide secured to said layer of zinc sulfide and a layer of silicon dioxide secured to said layer of aluminum oxide, and further including a layer of Al₂ O₃ or chromium-nickel alloy between said substrate and said layer of substantially silver to improve the adhesion of said silver layer to said substrate.

6. Low-emissivity glass comprising a pane of glass having a layer of about 50 A-200 A silver deposited on the outer surface thereof, a layer of zinc sulfide secured to said silver layer, a layer of aluminum oxide secured to said layer of zinc sulfide and a layer of silicon dioxide secured to said layer of aluminum oxide, and further including a layer of Al₂ O₃ or chromium-nickel alloy between said pane of glass and said layer of silver to improve the adhesion of said silver layer to said pane of glass.

7. A weather and abrasion resistant front surface mirror comprising a substrate having a layer of substantially silver deposited on the outer surface thereof, a layer of zinc sulfide secured to said silver layer and a layer of aluminum oxide secured to said layer of zinc sulfide, and further including a layer of Al₂ O₃ or chromium-nickel alloy between said substrate and said layer of substantially silver to improve the adhesion of said silver layer to said substrate.