Cement/gypsum composites based cellulose-I

• US 5,021,093 A
• Filed: 06/09/1988
• Issued: 06/04/1991
• Est. Priority Date: 05/29/1985
• Status: Expired due to Fees

• Current Assignee: Alphons D. Beshay
• Original Assignee: Alphons D. Beshay
• Inventors: Beshay, Alphons D.
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US07/204,272
• Time in Patent Office: 1,090 Days
• Field of Search: 106/93, 106/97-99, 106/103, 106/601, 106/606, 106/607, 106/609, 106/618-619, 106/713-716, 106/720, 106/624, 106/625, 106/638, 106/780, 106/731, 106/653, 524/4-5, 524/13, 524/35, 524/47, 524/52, 524/577, 524/583, 524/588, 527/312, 523/203, 523/212, 523/213, 523/214
• US Class Current: 106/731
• CPC Class Codes: C08F 230/085 the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes
• CPC Class Codes: C08F 251/02 on to cellulose or derivatives thereof

Abstract

Composite materials based on cement or gypsum materials reinforced by mixing with cellulosic fibers grafted with silylating agents. Processes for preparing these reinforced composites are also disclosed.

Claims

1. A composite material comprising a cement material, cellulosic fibers and optionally water, wherein said cellulosic fibers are (essentially) pregrafted with a silylating agent by generating a free radical process.

2. The composite material of claim 1, wherein the silane grafted cellulosic material is selected from the group consisting of chemicalthermomechanical wood pulp derived from aspen and semichemical pulp of bagasse.

3. The composite material of claim 1, wherein the silylating agent is selected from the group consisting of gamma-aminopropyltriethoxysilane, gamma-methacryloxypropyltrimethoxysilane, propyltriethoxysilane, vinyltriethoxysilane, vinyltri(2-methoxyethoxy)silane, beta-(3,4-epoxycyclohexyl)-ethyltrimethoxysilane, gamma-glycidoxypropyltrimethoxysilane, gamma-mercaptopropyltrimethoxysilane, gamma-aminopropyltrimethoxysilane, n-beta-(aminoethyl)-gamma-aminopropyltrimethoxysilane, n-beta-(aminoethoxyl)-gamma-aminopropyltrimethoxysilane and gamma-chloropropyltrimethoxysilane or any other silylating agent having the general formula ##STR2## or an oligomer thereof, wherein R₁, R₂ and R₃ are the same or different and are selected from the group comprising alkoxy with 1 to 6 carbon atoms, alkyl, alkenyl, cycloalkyl with 1 to 6 carbon atoms, aryl, aralkyl and organo-functional radicals.

4. The composite material of claim 1 is additionally comprising inorganic filler material.

5. The composite material of claim 1, wherein the inorganic filler is selected from the group consisting of inorganic material of hydroxyl containing, clay, asbestos, sand, wollastonite, quartz, glass, mica, diatomaceous earth, silica, talc, kaolinite, hydrated or partially hydrated metal oxides, metal powders, metal compounds, carbon, graphite and ashes.

6. The composite material of claim 1, wherein the cement material is substituted with gypsum or a mixture thereof.

7. The composite material of claim 1, wherein the cellulosic fibers are treated with a salt solution before or after the silane grafting process.

8. The composite material of claim 7, wherein the salt solution is calcium chloride.