Structured aqueous detergent compositions containing salting-out electrolytes and surfactants and methods of forming them

• US 5,021,195 A
• Filed: 02/08/1989
• Issued: 06/04/1991
• Est. Priority Date: 02/10/1988
• Status: Expired due to Term

• Current Assignee: Lever Brothers Company, Division Of Conopco, Inc.
• Original Assignee: Lever Brothers Company (Unilever PLC)
• Inventors: Buytenhek, Cornelis, Naik, Appaya, Machin, David, van de Pas, Johannes C.
• Primary Examiner(s): Willis, Prince E.
• Assistant Examiner(s): SILBERMANN, JAMES M
• Application Number:
  US07/308,343
• Time in Patent Office: 846 Days
• Field of Search: 252/532, 252/533, 252/534, 252/528, 252/135, 252/173, 252/174.25, 252/DIG. 14, 252/113, 252/116, 252/128, 252/174.23, 252/545, 252/547, 252/548, 252/174.2 1
• US Class Current: 510/397
• CPC Class Codes: C11D 17/0026 Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
• CPC Class Codes: C11D 3/14 Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures dyes, pigments C11D3/40

Abstract

A structured aqueous detergent composition containing detergent-active material in the form of at least one detergent-active component and at least one electrolyte and having the following phases:

(a) an isotropic aqueous solution forming a continuous phase;

(b) distributed and suspended in said solution (a) discrete units of one or more non-network-forming phases, each selected from the following:

(i) solid particles containing detergent-active material,

(ii) lyotropic liquid crystals containing detergent-active material; and

(iii) non-encapsulated liquid droplets containing detergent-active material,

(c) one or more suspending phases which cause the composition to be structured so as to suspend the non-network-forming phase (b); said non-network-forming phase (b) having a higher concentration by weight of detergent-active material than said aqueous solution (a).

Claims

1. A structured aqueous detergent composition containing detergent-active material in the form of at least one detergent-active component and at least one electrolyte and having the following phases:

(a) an isotropic aqueous solution forming a continuous phase;

(b) distributed and suspended in said solution (a) discrete units of one or more non-network-forming phases, each selected from the following;

(i) solid particles containing detergent-active material,

(ii) lyotropic liquid crystals containing detergent-active material; and

(iii) non-encapsulated liquid droplets containing detergent-active material,

(c) one or more suspending phases which cause the composition to be structured so as to suspend the non-network-forming phase (b);

said non-network-forming phase (b) having a higher concentration by weight of detergent-active material than said aqueous solution (a);

said composition having a viscosity of less than 2.5 Pas and a shear rate of 21S^-1 and, if phase (b)(i) or (b)(ii) is present, the composition giving substantially no clear layer formation upon centrifuging at 800 G at 25°

C. for 17 hours.

2. An aqueous detergent composition according to claim 1, wherein the suspending phase (c) is a lamellar phase in the form of spherulites or multi-layered vesicles of detergent-active material.

3. An aqueous detergent composition according to claim 1, wherein the suspending phase (c) is a non-surfactant structuring material in the form of a polymer and/or an inorganic colloid.

4. An aqueous detergent composition according to claim 1, wherein the suspending phase (c) is a filamentary structuring material in the form of soap crystals or cellulose.

5. An aqueous detergent composition according to claim 1, also comprising a further suspended phase (d) of solid particles selected from mineral abrasive particles, builder particles, softener particles and substantially water-insoluble bleaching agent particles.

6. An aqueous detergent composition according to claim 1, comprising one or more non-alkoxylated anionic surfactants which at least predominantly form said non-network-forming phase b(i) and/or b(ii), and one or more further detergent-active materials selected from:

alkoxylated anionic surfactants;

alkoxylated nonionic surfactants;

mono-and di-alkanolamides;

amine oxides;

betaines;

sulphobetaines;

sugar ethers,

which further materials at least partly form said lamellar phase c together with said non-alkoxylated anionic surfactant.

7. An aqueous detergent composition according to claim 1, comprising at least 20% by weight of detergent-active material.

8. A method of forming a structured aqueous detergent composition according to claim 1, in which the non-network-forming phase (b) (i) and/or the non-network forming phase (b)(ii) is/are present and the lamellar phase c(i) is present, the method comprising the successive steps:

(A) preparing an aqueous solution comprising a first non-alkoxylated detergent-active component,

(B) adding electrolyte to the aqueous solution so produced in order to cause said first component to form said non-network-forming phase(s) (b)(i) and/or b(ii),

(C) forming said lamellar phase (c)(i) by at least one of the following steps;

(C1) dissolving in the solution a second detergent active component more soluble in water than said first component,

(C2) adding further electrolyte to the solution.

9. A method according to claim 8, in which said electrolyte added in step (B) has a monovalent anion while said electrolyte added in step (C2) has a polyvalent anion.

10. A method according to claim 8, wherein said electrolyte is added in less than 4% by weight and is selected from the group consisting of mono- and divalent ions.

11. A method according to claim 10, wherever said electrolyte is sodium hydroxide.

12. A structured aqueous detergent composition according to claim 1 containing detergent-active material in the form of at least one detergent-active component and at least one electrolyte and having the following phases:

(a) an isotropic aqueous solution forming a continuous phase;

(b) distributed and suspended in said solution (a) discrete units of one or more non-network forming phases, each selected from the following;

(i) solid particles containing detergent-active material,

(ii) lyotropic liquid crystals containing detergent-active material; and

(iii) non-encapsulated liquid droplets containing detergent-active material; and

(c) one or more suspending phases which cause the composition to be structured so as to suspend the non-network forming phase (b);

said non-network forming phase (b) having a higher concentration by weight of detergent-active material than said aqueous solution (a);

wherein, when said discrete units of non-network forming phase are defined as in (b) (i) or (b) (ii), the discrete units are formed in situ, and when said discrete units are defined as in (b) (iii), the discrete units are formed by dissolving the active materials including the detergent active materials in water and adding electrolyte with stirring to form phase (b) (iii) and (c).

13. A structured aqueous detergent composition according to claim 12, wherein discrete units (b) (i) and (b) (ii) which are formed in situ are formed before the formation of suspending phase (c).