Porous material and its preparation

• US 5,021,462 A
• Filed: 10/31/1990
• Issued: 06/04/1991
• Est. Priority Date: 04/24/1987
• Status: Expired due to Term

• Current Assignee: Unilever Patent Holdings BV (Unilever PLC)
• Original Assignee: Unilever Patent Holdings BV (Unilever PLC)
• Inventors: Sherrington, David C., Elmes, Alfred R., Hammond, Kevin
• Primary Examiner(s): Foelak, Morton
• Application Number:
  US07/606,937
• Time in Patent Office: 216 Days
• Field of Search: 521/63, 521/64
• US Class Current: 521/63
• CPC Class Codes: B01D 15/08 Selective adsorption, e.g. chromatography
• CPC Class Codes: B01D 15/361 Ion-exchange
• CPC Class Codes: B01J 20/28047 Gels
• CPC Class Codes: B01J 20/28069 Pore volume, e.g. total pore volume, mesopore volume, micropore volume
• CPC Class Codes: B01J 20/28078 Pore diameter
• CPC Class Codes: B01J 20/28097 being coated, filled or plugged with specific compounds
• CPC Class Codes: B01J 47/018 Granulation; Incorporation of ion-exchangers in a matrix; Mixing with inert materials
• CPC Class Codes: C07K 1/042 characterised by the nature of the carrier
• CPC Class Codes: C08J 2201/05 Elimination by evaporation or heat degradation of a liquid phase
• CPC Class Codes: C08J 9/28 by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
• CPC Class Codes: G01N 2030/528 Monolithic sorbent material

Abstract

A porous polymeric material has cell sizes within the range 100 to 0.5 μm and total pore volume with respect to the overall volume of the material in the range 75 to 98% and includes cross-linked polycondensation polymeric material. The material can be made from a high internal phase emulsion in which the cross-linked polycondensation polymer is formed in the continuous phase. The materials are preferably open interconnected cellular structures. They can be made of a wide range of polycondensation materials. The materials are thus highly porous and light weight and have a range of properties depending primarily on their constituent polycondensation materials.

Claims

1. A process for preparing a three-dimensional porous polymeric material having a void space consisting of a three-dimensional network of cells separated from each other by walls and interconnected by holes through said walls, the cells having diameters in the range 100 to 0.5 μ

m, and the void space being in the range 75 to 98% of the total volume of the polymeric material, wherein the polymeric material is a cross-linked polycondensation polymeric material,

said process comprising preparing an emulsion having a continuous phase containing polymerizable precursor materials for said polymeric material and an internal phase comprising 75 to 98 volume % of the emulsion and consisting of globules having dimensions in the range 100 to 0.5 μ

m and forming, in said continuous phase, by condensation polymerisation and condensation cross-linking, said cross-linked polycondensation polymeric material.

2. A process according to claim 1 including removing the internal phase.

3. A process according to claim 1 wherein the formation of the cross-linked polycondensation polymer is initiated by the addition of an acid or base to the emulsion or heating the emulsion or both.

4. A process according to claim 1 wherein the reactant materials to form the cross-linked polycondensation polymer are present in the emulsion being either both in the continuous phase or split between the phases.

5. A process according to claim 1 wherein the emulsion is prepared containing an acid or a base to initiate a polycondensation reaction.

6. A process according to claim 5 wherein the emulsion contains one reactant material in the continuous phase and is contacted with the second reactant material.

7. A process according to claim 1 wherein a polycondensation reaction is completed within 60 minutes.