Rubber composition and tire with component(s) thereof

• US 5,021,493 A
• Filed: 03/21/1990
• Issued: 06/04/1991
• Est. Priority Date: 03/21/1990
• Status: Expired due to Term

• Current Assignee: Goodyear Tire & Rubber Company
• Original Assignee: Goodyear Tire & Rubber Company
• Inventors: Sandstrom, Paul H.
• Primary Examiner(s): Lieberman, Allan M.
• Application Number:
  US07/496,726
• Time in Patent Office: 440 Days
• Field of Search: 524/335, 524/337, 524/323, 524/347, 525/384, 152/209 R
• US Class Current: 152/209.5
• CPC Class Codes: C08K 5/13 Phenols; Phenolates
• CPC Class Codes: C08L 21/00 Compositions of unspecified rubbers

Abstract

A sulfur curable rubber compound containing a 2,5-diorganohydroquinone. The invention particularly relates to a pneumatic rubber tire having at least one component compound of such rubber compound.

Claims

1. A sulfur curable rubber composition which is comprised of at least one of natural rubber and synthetic rubber and is characterized by containing, based on 100 parts by weight of said rubber, from about 0.5 to about 5 parts by weight of 2,5-diorganohydroquinone having the structure:

##STR2## where R₁ and R₂ are the same or different hydrocarbon radicals containing from 1 to 20 carbon atoms selected from saturated alkyl and cycloalkyl radicals containing 3 to 20 carbon atoms and from aryl and hydrocarbon substituted aryl radicals (alkaryl radicals) and aralkyl radicals containing from 6 to 20 carbon atoms;

wherein said rubber composition is prepared by mixing essentially all of the 2,5-diorganohydroquinone in the absence of sulfur and vulcanization accelerators in a first, nonproductive, stage, of a multiple stage rubber mixing process.

2. The rubber composition of claim 1 where said hydrocarbon radicals are selected from branched, saturated alkyl and cycloalkyl radicals containing 4 to 6 carbon atoms.

3. The rubber composition of claim 1 where said alkyl radicals are selected from methyl, ethyl, propyl, butyl, amyl, hexyl, heptyl, octyl, nonyl and decyl radicals and their isomeric forms.

4. The rubber composition of claim 3 where said radicals are tertiary radicals selected from tertiary butyl, amyl, hexyl, heptyl and octyl radicals.

5. The rubber composition of claim 1 where said 2,5-diorganohydroquinone is a ditertiaryalkylhydroquinone where its tertiary alkyl groups are saturated alkyl radicals selected from butyl, amyl and hexyl radicals.

6. The rubber composition of claim 1 where said 2,5-diorganohydroquinone is 2,5-ditertiaryamylhydroquinone.

7. The rubber compound of claim 1 where said synthetic rubber is selected from at least one of cis 1,4-polybutadiene, 3,4-polyisoprene, styrene/butadiene copolymers, styrene/isoprene/butadiene copolymers and butadiene/acrylonitrile copolymers and if used therein, then as a minor amount of EPDM rubber, butyl and/or halobutyl rubber.

8. The rubber composition of claim 6 where said synthetic rubber is selected from at least one of cis 1,4-polybutadiene, 3,4-polyisoprene, styrene/butadiene copolymers, styrene/isoprene/butadiene copolymers and butadiene/acrylonitrile copolymers and if used therein, then as a minor amount of EPDM rubber, butyl and/or halobutyl rubber.

9. A pneumatic rubber tire containing at least one component as the rubber composition of claim 1.

10. A pneumatic rubber tire having at least one of its carcass or sidewall components as containing the rubber composition of claim 6.

11. A pneumatic rubber tire having a tread composed of a sulfur cured rubber composition of claim 1.

12. The pneumatic rubber tire of claim 11 where the said rubber composition is a tread base in a tread cap/base construction.

13. A pneumatic rubber tire having a tread composed of a sulfur cured rubber composition of claim 4.

14. A pneumatic rubber tire having a tread composed of a sulfur cured rubber composition of claim 5.

15. A pneumatic rubber tire having a tread composed of a sulfur cured rubber composition of claim 6.

16. The pneumatic rubber tire of claim 15 where the said rubber composition is a tread base in a tread cap/base construction.

17. A pneumatic rubber tire having a tread composed of a sulfur cured rubber composition of claim 7.