Extrusion isolation of blends of rubber and asphalt

• US 5,025,044 A
• Filed: 09/25/1990
• Issued: 06/18/1991
• Est. Priority Date: 10/31/1989
• Status: Expired due to Fees

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Kafka, Fred Y., Christell, Lance A.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US07/586,855
• Time in Patent Office: 266 Days
• Field of Search: 523/334, 523/339, 524/59, 524/71, 528/502, 528/936
• US Class Current: 523/334
• CPC Class Codes: B29B 7/489 Screws B29B7/482 takes precedence
• CPC Class Codes: B29B 7/603 in measured doses, e.g. proportioning of several materials
• CPC Class Codes: B29B 7/7495 for mixing rubber
• CPC Class Codes: B29B 7/845 Venting, degassing or removing evaporated components in devices with rotary stirrers
• CPC Class Codes: B29B 7/86 for working at sub- or superatmospheric pressure B01F33/70 takes precedence
• CPC Class Codes: B29B 7/94 Liquid charges
• CPC Class Codes: B29C 48/03 characterised by the shape of the extruded material at extrusion
• CPC Class Codes: B29C 48/2886 of fibrous, filamentary or filling materials, e.g. thin fibrous reinforcements or fillers
• CPC Class Codes: B29C 48/29 in liquid form
• CPC Class Codes: B29C 48/297 at several locations, e.g. using several hoppers or using a separate additive feeding
• CPC Class Codes: B29C 48/76 Venting , drying means; Degassing means
• CPC Class Codes: B29C 48/919 using a bath, e.g. extruding into an open bath to coagulate or cool the material
• CPC Class Codes: B29K 2105/0005 containing compounding ingredients releasing, lubricating or separating agents B29C33/56, fibers B29K2105/08, B29K2105/12; fillers B29K2105/16, recycled material B29K2105/26
• CPC Class Codes: B29K 2105/16 Fillers
• CPC Class Codes: C08J 3/005 Processes for mixing polymers
• CPC Class Codes: C08L 2666/08 Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof
• CPC Class Codes: C08L 95/005 Aqueous compositions, e.g. emulsions
• CPC Class Codes: Y10S 528/936 Coagulating

Abstract

Blends of asphalt emulsions or melts and aqueous elastomeric latices are prepared using a screw type extruder adapted to provide sufficient back pressure within the screw flights of the extruder to express the water from the blend through a vent provided in the extruder.

Claims

1. A process for blending elastomeric latices and asphalt comprising feeding an aqueous emulsion of elastomeric latex selected from the group consisting of chloroprene polymer latexes, polyisoprene latexes, polystyrene/butadiene latexes, and polybutadiene latexes containing 15 to 70 weight percent elastomer, and asphalt in the form of a melt or in the form of an emulsion containing 20-70 weight percent asphalt to a screw extruder having a flow restriction to apply a back pressure sufficient that water present in the aqueous emulsion is forced out of a vent provided in the extruder upstream from said flow restriction to apply back pressure, feeding asphalt and elastomer through said restriction and recovering the thus formed blend of 5 to 98 weight percent asphalt and 2 to 95 weight percent elastomer from said extruder.

2. The process of claim 1 wherein the asphalt fed to the extruder is in the form of an emulsion.

3. The process of claim 2 wherein the elastomeric latex is blended with an asphalt emulsion prior to feeding to the extruder.

4. The process of claim 1 wherein the asphalt is fed to the extruder in the form of a melt upstream of or at the pressure seal.

5. The process of claim 2 wherein the elastomer emulsion fed to the extruder contains 30-60 weight percent elastomer.

6. The process of claim 1 wherein the asphalt and elastomeric latex are fed separately to the extruder.

7. The process of claim 1 wherein the polymer is a chloroprene polymer.

8. The process of claim 1 wherein the asphalt used in the process has a viscosity from 500-8000 Poise.

9. The process of claim 7 wherein the asphalt used in the process has a viscosity from 500-2000 Poise.

10. The process of claim 7 wherein the chloroprene polymer consists essentially of repeating units derived from chloroprene and up to 20 weight percent of another monomer from the group consisting of 2,3-dichloro-1,3-butadiene and vinyl monomers copolymerizable with chloroprene and having a boiling point of from 0°

to 200°

C.

11. The process of claim 10 wherein the vinyl monomer is selected from the group consisting of acrylonitrile;

methacrylonitrile;

lower alkyl acrylates, methacrylates, acrylamides, methacrylamides, maleates, and fumarates;

acrylic acid;

methacrylic acid;

maleic acid and fumaric acid.

12. The process of claim 10 wherein the chloroprene polymer contains up to 35 weight percent gel.

13. The process of claim 10 wherein the other monomer in the chloroprene polymer is 2,3-dichloro-1,3-butadiene.