Process for sizing particles using condensation nucleus counting

• US 5,026,155 A
• Filed: 09/06/1989
• Issued: 06/25/1991
• Est. Priority Date: 09/06/1989
• Status: Expired due to Term

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Schwarz, Alexander, Ockovic, Richard C., McDermott, Wayne T.
• Primary Examiner(s): McGraw, Vincent P.
• Application Number:
  US07/403,646
• Time in Patent Office: 657 Days
• Field of Search: 356/37, 356/335, 356/356
• US Class Current: 356/37
• CPC Class Codes: G01N 15/0205 by optical means
• CPC Class Codes: G01N 15/065 using condensation nuclei counters
• CPC Class Codes: G01N 15/14 Optical investigation techniques, e.g. flow cytometry

Abstract

A process for counting and sizing particles in gases in the size range of 0.0025 micrometers or greater using condensation nucleus counting wherein the condensing temperature of a saturated working fluid is incrementally adjusted to adjust sensitivity to differing sizes of particles and thus discriminate according to size.

Claims

1. A continuous process for sizing particles in a particle-containing gas using condensation nucleus counting, comprising:

(a) passing a particle-containing gas mixed with a working fluid vapor into a condensation zone,

(b) condensing working fluid on that portion of the particles of a minimum size corresponding to a minimum temperature of the condensation zone to form droplets,

(c) detecting the resulting droplets and counting the number of droplets by appropriate sensing of scattered light for each droplet and tabulation,

(d) incrementally adjusting the degree of saturation of the working fluid in the gas by incrementally adjusting the temperature of the condensation zone to increase the degree of saturation at lower temperatures, and

(e) performing step c) at each increment of temperature adjustment.

2. The process of claim 1 wherein the temperature of the condensation zone is incrementally adjusted downwardly to detect incrementally smaller particles.

3. The process of claim 1 wherein the particles are in the range of approximately 0.0025 micrometer to 0.2 micrometer.

4. The process of claim 1 wherein the working fluid-containing gas is supersaturated.

5. The process of claim 1 wherein the working fluid is a vapor at condensation zone conditions.

6. The process of claim 1 wherein the working fluid is selected from the group consisting of water, alcohols and perfluorinated organic compounds.

7. The process of claim 1 wherein the working fluid is butanol.

8. The process of claim 1 wherein the working fluid is perfluorodimethyldecalin.

9. The process of claim 1 wherein the temperature of the condensation zone is varied over the range of approximately -3.6°

C. to 27°

C.

10. The process of claim 1 wherein the particles are detected at an at least approximately 50% counting efficiency.

11. The process of claim 1 wherein the gas is selected from the group consisting of oxygen, nitrogen, hydrogen, helium, argon, krypton, nitrogen trifluoride, chlorine, fluorine, air and mixtures thereof.

12. The process of claim 1 wherein the droplets are detected by light scattering by the droplets.

13. The process of claim 1 wherein the temperature of the saturation zone is held at approximately 65°

C.

14. The process of claim 1 wherein the working fluid is saturated in a gas in a saturation zone before the working fluid-containing gas is introduced into the condensation zone.

15. The process of claim 14 wherein the working fluid-containing gas is derived from a portion of the particle-containing gas.