Mold with hydrogenated amorphous carbon film for molding an optical element

• US 5,026,415 A
• Filed: 08/15/1989
• Issued: 06/25/1991
• Est. Priority Date: 08/16/1988
• Status: Expired due to Term

• Current Assignee: Canon Ayutthaya Limited (Canon Inc.)
• Original Assignee: Canon Ayutthaya Limited (Canon Inc.)
• Inventors: Taniguchi, Yasushi, Yamamoto, Kiyoshi, Hirabayashi, Keiji, Ikoma, Keiko, Kurihara, Noriko
• Primary Examiner(s): Schor, Kenneth M.
• Assistant Examiner(s): Burns, Todd J.
• Application Number:
  US07/394,208
• Time in Patent Office: 679 Days
• Field of Search: 65/374.1, 65/374.15, 65/60.6, 65/374.11, 65/286, 65/305, 65/26, 65/24, 65/374.13, 425/808, 427/133, 427/135, 249/114.1, 249/134, 106/38.27, 106/38.28
• US Class Current: 65/305
• CPC Class Codes: C03B 11/086 of coated dies use of materials as release or lubricating compositions C03B40/02
• CPC Class Codes: C03B 2215/12 Ceramics or cermets, e.g. cemented WC, Al2O3 or TiC
• CPC Class Codes: C03B 2215/24 Carbon, e.g. diamond, graphite, amorphous carbon
• CPC Class Codes: C03B 2215/34 of ceramic or cermet material, e.g. diamond-like carbon
• CPC Class Codes: C04B 41/85 with inorganic materials

Abstract

This specification discloses a mold for use for press-molding an optical element, characterized in that at least the molding surface of a mold base material is coated with an a-C:H film containing 5-40 atom % of hydrogen therein and having a film density of 1.5 g/cm³ or more. Other mold coating films also disclosed are a hydrogenated amorphous carbon film with an intermediate carbide layer between the film and the molding surface, and a hard carbon film containing 0-5 atom % of hydrogen therein and having a spin density of 1×10¹⁸ spin/cm³ or less and a film densisy of 1.5 g/cm³ or more.

Claims

1. A mold for press-molding an optical element formed of glass comprising a pair of molding members, each molding member comprising a mold base and a glass contacting, hydrogenated amorphous carbon film thereon, said glass contacting film having an inner surface interfacing with said mold base and an outer surface for contacting said glass, wherein the hydrogen content of said glass contacting film decreases from a maximum concentration at the inner surface of said glass contacting film to a minimum concentration at said outer surface for contacting said glass.

2. A mold according to claim 1, wherein the hydrogen content of the glass contacting film is 60 atom % or less at the inner surface and is 5 atom % or more at the outer surface.

3. A mold according to claim 1, wherein the hydrogenized amorphous carbon film in which the hydrogen content decreases from the inner surface toward the outer surface is formed by two layers of films differing in the hydrogen content.

4. A mold according to claim 3, wherein the layer which is greater in the hydrogen content has a film thickness of 500-1000 Å

and contains 40-60 atom % of hydrogen therein, and the layer which is less in the hydrogen content has a film thickness of 4000-8000 Å and

contains 5-40 atom % of hydrogen therein.

5. A mold for press-molding an optical element, said mold comprising a pair of molding members, each of said molding members comprising, in sequence, (a) a mold base, (b) an intermediate layer comprising a carbide of an element of said mold base and (c) an outer coating of a hydrogenated amorphous carbon film for contacting a heated glass material.

6. A mold for press-molding an optical element said mold comprising a pair of molding members, each of said molding members comprising, in sequence, (a) a mold base, (b) an intermediate layer comprising a carbide of an element of said mold base and hydrogenated amorphous carbon and (c) an outer layer of a hydrogenated amorphous carbon film for contacting a heated glass material.