Photorefractive effect in bulk glass and devices made therefrom

• US 5,028,105 A
• Filed: 12/21/1989
• Issued: 07/02/1991
• Est. Priority Date: 12/21/1989
• Status: Expired due to Term

• Current Assignee: NetOptix Corp. (Corning Incorporated)
• Original Assignee: Galileo Electro-Optics Corps.
• Inventors: Cook, Lee M., Drexhage, Martin G., Margraf, Tracey L., Moynihan, Cornelius T.
• Primary Examiner(s): Lee, John D.
• Assistant Examiner(s): BARNS, STEPHEN
• Application Number:
  US07/454,646
• Time in Patent Office: 558 Days
• Field of Search: 350/96.30, 350/96.12, 430/494
• US Class Current: 385/33
• CPC Class Codes: C03C 23/0025 by a laser beam
• CPC Class Codes: C03C 3/321 Chalcogenide glasses, e.g. containing S, Se, Te
• CPC Class Codes: G02B 6/08 with fibre bundle in form of plate
• CPC Class Codes: G02B 6/13 Integrated optical circuits characterised by the manufacturing method
• CPC Class Codes: H01J 29/892 using fibre optics

Abstract

The photorefractive effect results in a change in the refractive index of bulk chalcogenide glass when it is exposed to certain wavelengths of light, in particular, sub-band-gap light. The effect results in a variety of device structures including a fiber optic faceplate; an optical waveguide; a fiber tap; a lens and a Bragg grating. Methods for fabricating the various devices are described.

Claims

1. A method of altering the refractive index in bulk chalcogenide glasses having an absorption coefficient of about 10³ cm^-1 at a wavelength defined as the band gap comprising:

exposing the bulk glass having a thickness greater than about 200μ

to sub-band-gap light for a time sufficient to result in an alteration of said refractive index of the glass.

2. A method of claim 1 wherein the bulk glass has an absorption coefficient of 1 cm^-1 at about 0.6 micrometers.

3. The method of claim 1 wherein the wavelength of the band-gap is about 0.5 micrometers.

4. The method of claim 1 wherein the sub-band-gap light is longer than about 0.5 micrometers.

5. The method of claim 1 wherein the alteration of the refractive index is reversible by application of heat in the vicinity of the glass transition temperature.

6. The method of claim 1 wherein the alteration of the refractive index results in an increase in the index of refraction.

7. The method of claim 1 further including the step of overcoating the altered glass with an overcoat of glass having an absorption coefficient higher the bulk glass.

8. The method of claim 7 wherein the overcoat glass is a chalcogenide.

9. The method of claim 7 wherein the absorption coefficient of the overcoat is at least one order of magnitude higher than that of the bulk glass.

10. The method of claim 9 wherein the bulk glass is susceptible to bleaching by band-gap light and the overcoat is opaque to band-gap light thereby preventing bleaching of the bulk glass.

11. The method of claim 1 wherein the bulk glass is exposed by application of a focused laser beam.

12. The method of claim 1 wherein the light penetrates the bulk glass to a depth of at least one millimeter.

13. The method of claim 1 wherein the exposure occurs by application of at least two focused laser beams crossing at a point within the bulk glass and the resulting alteration is in the form a Bragg grating.

14. The method of claim 1 wherein exposing the bulk glass to sub-band-gap light comprises selectively masking the bulk glass to produce a plurality of parallel fiber-like structures in the bulk glass.

15. The method of claim 14 further comprising coating the exposed bulk glass with an overcoat of glass having an absorption coefficient greater than the bulk glass.

16. The method of claim 1 further comprising drawing a fiber of the bulk glass and exposing a central core portion thereof to the sub-band-gap light for producing an optical fiber.

17. The method of claim 1 wherein the bulk glass comprises an optical fiber having a core and a cladding, and alteration of the glass occurs in the cladding.

18. The method of claim 1 wherein the bulk glass is an optical fiber having a core, a cladding and an end face, and alteration of the glass occurs in the core at the end face thereof for producing a lens.

19. The method of claim 1 wherein the step of exposing the bulk glass to sub-band-gap light comprises projecting the light onto the bulk glass from a binary phase grating.

20. A method of altering the refractive index in bulk chalcogenide glasses having an absorption coefficient of about 10³ cm^-1 a wavelength defined as the band-gap comprising:

exposing the bulk glass to sub-band-gap light for a time sufficient to result in an alteration of said refractive index of said glass; and

overcoating the altered glass with an overcoat of glass having an absorption coefficient higher the bulk glass.

21. The method of claim 20 wherein the overcoat glass is a chalcogenide.

22. The method of claim 20 wherein the absorption coefficient of the overcoat is at least one order of magnitude higher than that of the bulk glass.

23. The method of claim 22 wherein the bulk glass is susceptible to bleaching by band-gap light and the overcoat is opaque to band-gap light thereby preventing bleaching of the altered bulk glass.

24. A method of altering the refractive index in bulk chalcogenide glasses comprising:

exposing the bulk glass to sub-band-gap light for a time sufficient to result in an alteration of said refractive index of said glass; and

selectively masking the bulk glass to produce a plurality of parallel fiber-like waveguide structures in such glass.

25. A method of altering the refractive index in bulk chalcogenide glasses comprising:

exposing the bulk glass to sub-band-gap light for a time sufficient to result in an alteration of said refractive index of said glass; and

drawing a fiber of the bulk glass and exposing a central portion thereof to the sub-band-gap light for producing an optical fiber.

26. A method of altering the refractive index in bulk chalcogenide glasses having an absorption coefficient of about 10³ cm^-1 at a wavelength defined as the band gap comprising:

exposing the bulk glass having a thickness greater than thin films to sub-band-gap light for a time sufficient to result in an alteration of said refractive index of the glass.

27. The method of claim 26 wherein the bulk glass has a thickness greater than 100μ

.

28. The method of claim 26 wherein the bulk glass has a thickness greater than 1 mm.