Process of aligning and realigning liquid crystal media

• US 5,032,009 A
• Filed: 08/13/1990
• Issued: 07/16/1991
• Est. Priority Date: 03/08/1989
• Status: Expired due to Term

• Current Assignee: Elsicon Incorporated
• Original Assignee: Hercules Incorporated (Ashland Global Holdings, Inc.)
• Inventors: Gibbons, Wayne M., Swetlin, Brian J., Sun, Shao-Tang
• Primary Examiner(s): Miller, Stanley D.
• Assistant Examiner(s): MAI, HUY KIM
• Application Number:
  US07/567,047
• Time in Patent Office: 337 Days
• Field of Search: 350/341, 350/350 S, 350/340, 350/346, 350/349, 350/350 R, 350/351, 350/345
• US Class Current: 349/124
• CPC Class Codes: C09K 19/56 Aligning agents
• CPC Class Codes: C09K 19/60 Pleochroic dyes
• CPC Class Codes: C09K 19/606 Perylene dyes
• CPC Class Codes: G02F 1/133711 by organic films, e.g. polymeric films
• CPC Class Codes: G02F 1/133788 by light irradiation, e.g. linearly polarised light photo-polymerisation
• CPC Class Codes: G02F 1/13725 based on guest-host interaction G02F1/13762, G02F1/13737, take precedence
• CPC Class Codes: G11B 7/00555 involving liquid crystal media
• CPC Class Codes: G11B 7/25 containing liquid crystals
• CPC Class Codes: Y10S 359/90 Methods

Abstract

A process of aligning or realigning a liquid crystal medium adjacent to a substrate which process comprises (1) exposing anisotropically absorbing molecules disposed on the substrate, disposed in the liquid crystal medium or which themselves are the liquid crystal medium to linearly polarized light of a wavelength or wavelengths within the absorption band of the anisotropically absorbing molecules, wherein (a) the exposed anisotropically absorbing molecules induce alignment of the liquid crystal medium at an angle + and - θ with respect to the direction of the linear polarization of the incident light beam and along a surface of the liquid crystal medium, (b) the liquid crystal medium comprises liquid crystals having a molecular weight of less than 1500, and (c) the anisotropically absorbing molecules are exposed by (i) linearly polarized light transmitted through at least one mask having a pattern, (ii) a beam of linearly polarized light scanned in a pattern or (iii) patterns created by interference of coherent linearly polarized light beams, and (2) terminating exposure, whereby the liquid crystal medium aligned or realigned by the exposure step remains aligned or realigned and has two or more discrete regions having different alignments, and liquid crystal devices prepared by this process, are disclosed.

Claims

1. A process of aligning or realigning a liquid crystal medium adjacent to a substrate which process comprises (1) exposing anisotropically absorbing molecules disposed on the substrate, disposed in the liquid crystal medium or which themselves are the liquid crystal medium to linearly polarized light of a wavelength or wavelengths within the absorption band of the anisotropically absorbing molecules, wherein (a) the exposed anisotropically absorbing molecules induce alignment of the liquid crystal medium at an angle + and - θ

with respect to the direction of the linear polarization of the incident light beam and along a surface of the liquid crystal medium, (b) the liquid crystal medium comprises liquid crystals having a molecular weight of less than 1500, and (c) the anisotropically absorbing molecules are exposed by (i) linearly polarized light transmitted through at least one mask having a pattern, (ii) a beam of linearly polarized light scanned in a pattern or (iii) patterns created by interference of coherent linearly polarized light beams, and (2) terminating exposure, whereby the liquid crystal medium aligned or realigned by the exposure step remains aligned or realigned and has two or more discrete regions having different alignments.

2. The process as claimed in claim 1 wherein the anisotropically absorbing molecules are exposed by the linearly polarized light transmitted through at least one mask having a pattern.

3. The process as claimed in claim 1 wherein the anisotropically absorbing molecules are exposed by the beam of linearly polarized light scanned in a pattern.

4. The process as claimed in claim 1 wherein the anisotropically absorbing molecules are exposed by the patterns created by interference of coherent linearly polarized light beams.

5. The process as in claim 1 wherein the linearly polarized light has a wavelength between about 150 nm and about 2000 nm.

6. The process as claimed in claim 1 wherein the linearly polarized light is emitted from a laser.

7. The process as claimed in claim 6 wherein the laser light is emitted from an argon, helium-neon or helium-cadmium laser.

8. The process of claim 1 wherein the anisotropically absorbing molecules are selected from the group consisting of thermotropic liquid crystal compounds and dichroic dyes which exhibit dichroic absorption bands between about 150 nm and about 2000 nm.

9. The process as in claim 1 wherein the liquid crystal medium contains the anisotropically absorbing molecules.

10. The process as in claim 9 wherein the anisotropically absorbing molecules are thermotropic liquid crystals.

11. The process as claimed in claim 1 wherein the liquid crystal medium comprises at least one thermotropic liquid crystal compound selected from the group consisting of nematic and smectic liquid crystal compounds.

12. The process as claimed in claim 11 wherein the liquid crystal medium comprises the nematic liquid crystal compounds.

13. The process as claimed in claim 11 wherein the liquid crystal medium comprises the smectic liquid crystal compounds.

14. The process as claimed in claim 13 wherein the smectic liquid compounds are ferroelectric liquid crystal compounds.

15. The process as claimed in claim 1 wherein the liquid crystal medium comprises at least one dichroic dye which exhibits dichroic absorption between about 150 nm and about 2000 nm dissolved in at least one thermotropic liquid crystal compound.

16. The process as claimed in claim 15 wherein the dichroic dye is selected from the group consisting of azo, diazo, triazo, tetraazo, pentaazo, anthraquinone, mericyanine, methine, 2-phenylazothiazole, 2-phenylazobenzthiazole, 4,4'"'"'-bis(arylazo)stilbenes, perylene and 4,8-diamino-1,5-naphthoquinone dyes that exhibit dichroic absorption bands between about 150 nm and about 2000 nm.

17. The process as claimed in claim 15 wherein the anisotropically absorbing molecules are one or more of the dichroic dyes.

18. The process as claimed in claim 1 wherein the liquid crystal composition does not contain a dichroic dye.

19. The process as claimed in claim 1 further comprising that the liquid crystal medium is filled into a cell comprising a front and rear substrate.

20. The process of claim 19 wherein exposure to linearly polarized light is carried out after the cell is filled.

21. The process of claim 19 wherein at least one of the substrates is coated with a rubbed alignment layer.

22. The process as claimed in claim 21 wherein the anisotropically absorbing molecules comprise at least one dichroic dye which exhibit dichroic absorption between about 150 nm and about 2000 nm which is part of the alignment layer.

23. The process as claimed in claim 22 wherein the liquid crystal medium also contains anisotropically absorbing molecules comprising at least one dichroic dye which exhibit dichroic absorption between about 150 nm and about 2000 nm.

24. The process as claimed in claim 1 wherein the liquid crystal medium is aligned into two or more discrete regions having different homogeneous alignments.

25. The process as claimed in claim 1 wherein the liquid crystal medium has a negative dielectric anisotropy.

26. The process as claimed in claim 1 wherein the anisotropically absorbing molecules are selected from the group consisting of dichroic dyes which exhibit dichroic absorption between about 150 nm and about 2000 nm and the dichroic dyes are coated on at least one inner surface of a cell substrate prior to exposure.

27. The process as claimed in claim 1 wherein the liquid crystal medium comprises liquid crystals having a molecular weight of 1000 or less.

28. The process as claimed in claim 1 wherein the liquid crystal medium comprises liquid crystals having a molecular weight of 650 or less.