Injection moldable composite

• US 5,034,157 A
• Filed: 03/16/1990
• Issued: 07/23/1991
• Est. Priority Date: 03/16/1990
• Status: Expired due to Fees

• Current Assignee: ITT Corporation (ITT, Inc.)
• Original Assignee: ITT Corporation (ITT, Inc.)
• Inventors: Merrell, Kenneth C., Rogers, Gerald A.
• Primary Examiner(s): Barr, Josephine
• Assistant Examiner(s): Swope, Bradley A.
• Application Number:
  US07/495,238
• Time in Patent Office: 494 Days
• Field of Search: 252/512, 252/518, 252/513, 524/439, 523/205
• US Class Current: 252/512
• CPC Class Codes: B29C 70/882 partly or totally electrically conductive, e.g. for EMI shielding conductive floors or floor coverings H05F3/025; EMI shielding in general H05K9/00
• CPC Class Codes: B29K 2995/0005 Conductive
• CPC Class Codes: C08K 7/06 Elements
• CPC Class Codes: C08K 7/14 Glass
• CPC Class Codes: C08L 71/10 from phenols
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys

Abstract

An injection moldable composite comprising an admixture of a polyetherketone such as polyetheretherketone (PEEK) matrix resin, a metal filler such as stainless steel fiber coated with a resin sizing soluble in the matrix resin, and glass fiber. The resulting molded form of the composite being electrically conductive and aluminum galvanic compatible.

Claims

1. An injection moldable, electrically conductive, aluminum galvanic compatible composite comprising:

approximatley 50 to 84 percent by weight of polyetherketone resins;

approximately 10 to 40 percent by weight of a dispersion of glass fibers; and

approximately 6 to 10 percent by weight of a dispersion of individual stainless steel fibers coated with a sizing soluble in and wettable by said resin.

2. The composite according to claim 1 wherein said sizing is a polyetherketone resin sizing or a polysulfone resin sizing.

3. The composite according to claim 1 wherein said stainless steel fibers are 302 stainless steel fibers.

26. The composite according to claim 1 in which the resin is a polyarylene ether ketone resin.

27. The composite according to claim 26 in which the resin has a repeating unit of the formula:

##STR2##

4. An injection moldable composite comprising:

a polyetherketone thermoplastic molding base resin containing a dispersion of a mixture in an amount to form in percent by weight of the composite, approximately 30 percent by weight of glass fiber and 6 to 10 percent by weight of individual, stainless steel fiber coated with a sizing soluble in and wettable by said resin.

5. The composite of cliam 4 wherein said sizing is a PEEK resin or a polysulfone resin.

6. The composite of claim 5 wherein said sizing is present in an amount equal to approximately 5 to 15 percent by weight based on the total weight of the sized stainless steel fiber.

7. An injection moldable composite for forming a valve body that is electrically conductive and aluminum galvanic compatible, the composite forming the valve body comprising:

approximatley 50 to 84 percent by weight of polyetherketone resin;

approximately 10 to 40 percent of glass fibers; and

approximately 6 to 10 percent by weight of individual stainless steel fibers coated with a sizing thereon that is soluble in and wettable by said resin.

8. The composite according to claim 7 wherein said sizing is a polyetherketone resin sizing or a polysulfone resin sizing.

9. The composite according to claim 8 wherein said stainless steel fibers are 302 stainless steel fibers.

10. A valve body injection molded from a composite comprising:

a polyetherketone thermoplastic molding base resin; and

a mixture in an amount to form in percent by weight of the composite, approximately 30 percent by weight of glass fiber and 6 to 10 percent by weight of polyetherketone resins sized, individual stainless steel fiber, said sizing being soluble in and wettable by said base resin.

11. A mixture for an injection molded body that is electrically conductive, aluminum galvanic compatible, the mixture comprising:

approximatley 50 to 84 percent by weight of polyetherketone thermoplastic molding resin;

approximately 10 to 40 percent by weight glass fibers; and

approximately 6 to 10 percent by weight resin sized, individual, stainless steel fibers, said sizing resin being soluble in and wettable by said molding resin.

12. The mixture according to claim 11 wherein said stainless steel fibers are 300 type stainless steel fibers with sizing in an amount of 8 to 12 percent by weight based on the total weight of the sized stainless steel fibers.

13. An injection molded body being formed from a composite comprising:

a polyetherketone thermoplastic molding base resin; and

a mixture in an amount to form in percent by weight of the composite, approximately 30 percent by weight of glass fiber and 6 to 10 percent by weight of individual, sized stainless steel fiber coated with a sizing soluble in and wettable by said molding resin.

14. The composite of cliam 13 wherein said sizing is PEEK resin sizing or a polysulfone resin sizing.

15. The composite of cliam 14 wherein said stainless steel fiber is a 300 series stainless steel fiber.

16. An injection molded valve body, electrically conductive aluminum galvanic compatible, molded from a composite consisting of:

a polyetherketone thermoplastic molding base resin; and

a mixture of approximately 30 percent by weight of glass fiber and 8 percent by weight of resin sized, individual, stainless steel fibers coated with a resin sizing soluble in and wettable by said molding resin.

17. An injection molding composition comprising in combination, an admixture of:

approximatley 62 percent by weight of polyetherketone thermoplastic molding resin;

approximately 30 percent by weight of glass fibers; and

approximately 8 percent by weight of individual, stainles steel fibers sized with resin soluble in and wettable by said molding resin.

19. A resin composition according to claim 17 in which the sized metal fibers are coated with a sizing resin capable of dispersing the metal fibers in the matrix resin.

20. A filled resin composition according to claim 19 in which the sizing is soluble in the matrix resin.

21. A filled resin composition according to claim 20 which the sizing resin is selected from polyetherketone or polysulfone.

22. A filled resin composition according to claim 21 in which the sizing resin is present on the metal fibers in an amount of from 5 percent by weight to 15 percent by weight based on the total weight.

23. A filled resin composition according to claim 22 in which the metal fiber is stainless steel.

24. A filled resin composition according to claim 23 in which the polyetherketone is present in the composition in an amount from at least 50 to 84 percent by weight.

25. A filled resin composition according to claim 24 in which the glass fibers are present in the composition in an amount from 10 to 40 percent by weight.

18. A resin composition for forming an injection moldable, electrically conductive, aluminum glavanic-compatible composite comprising:

approximately 50 to 84 percent by weight of PEEK matrix resin;

approximately 10 to 40 percent by weight of glass reinforcement fibers dispersed therein; and

approximately 6 to 10 percent by weight of sized, individual metal fibers dispered in said resin in an amount providing electrical conductivity, said sizing being soluble in and wettable by said matrix resin.