Polyphenylene ether compositions having improved flow

• US 5,034,459 A
• Filed: 02/02/1989
• Issued: 07/23/1991
• Est. Priority Date: 11/18/1987
• Status: Expired due to Term

• Current Assignee: Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Axelrod, Robert J., Haaf, William R.
• Primary Examiner(s): Ziegler, Jacob
• Application Number:
  US07/291,849
• Time in Patent Office: 901 Days
• Field of Search: 525/92, 525/905, 525/68
• US Class Current: 525/68
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 51/04 grafted on to rubbers
• CPC Class Codes: C08L 71/123 not modified by chemical after-treatment
• CPC Class Codes: Y10S 525/905 Polyphenylene oxide

Abstract

The melt flow behavior of blends of polyphenylene ether resins and alkenyl aromatic resins such as high impact polystyrene can be markedly improved by incorporation therein of effective amounts of styrene-alpha methyl styrene copolymers.

Claims

1. A thermoplastic composition having improved melt flow behavior, comprising:

(a) a polyphenylene ether resin;

(b) a rubber-modified alkenyl aromatic resin;

(c) a low molecular weight copolymer of styrene and alpha methyl styrene in an amount which improves the melt flow of the combination of (a) and (b); and

(d) a thermoplastic elastomer in an amount sufficient to improve the impact strength of the combination of components (a), (b), and (c).

2. A composition as in claim 1 wherein said thermoplastic elastomer is a block copolymer primarily comprised of styrenic units and diene rubber units.

3. A composition as in claim 2 wherein said thermoplastic elastomer is present in an amount of about 2 to about 20 parts by weight based upon the weight of 100 parts of (a) and (b) combined.

4. A composition as in claim 2 wherein said thermoplastic elastomer is a block copolymer of the A-B or A-B-A'"'"' type wherein the A and A'"'"' blocks are a styrenic polymer and the B block is a rubbery diene polymer.

5. A composition as in claim 4 wherein the A or A'"'"' block is styrene and the B block is polybutadiene.

6. A composition as in claim 5 wherein the rubbery diene polymer is partially or completely hydrogenated.