Process for vitrifying environmentally hazardous waste material in a glass melting furnace

• US 5,035,735 A
• Filed: 12/13/1989
• Issued: 07/30/1991
• Est. Priority Date: 12/13/1988
• Status: Expired due to Fees

• Current Assignee: Beteiligungen Sorg GmbH & Co., KG
• Original Assignee: Beteiligungen Sorg GmbH & Co., KG
• Inventors: Pieper, Helmut, Zschocher, Hartmut, Sorg, Helmut
• Primary Examiner(s): Woodard, Joye L.
• Application Number:
  US07/450,346
• Time in Patent Office: 594 Days
• Field of Search: 65/27, 65/29, 65/134, 65/136, 501/27, 501/30, 501/32, 501/155, 423/DIG. 20
• US Class Current: 65/134.8
• CPC Class Codes: B09B 3/0066 Disposal of asbestos
• CPC Class Codes: B09B 3/29 involving a melting or softening step
• CPC Class Codes: C03B 3/00 Charging the melting furnaces
• CPC Class Codes: C03B 5/005 of glass-forming waste materials disposal or transformation of solid waste in general B09B; treatment of radioactive waste G21F9/00
• CPC Class Codes: C03B 5/027 by passing an electric current between electrodes immersed in the glass bath, i.e. by direct resistance heating
• CPC Class Codes: C03B 5/262 Drains, i.e. means to dump glass melt or remove unwanted materials
• CPC Class Codes: C03B 7/02 Forehearths, i.e. feeder channels
• CPC Class Codes: C03C 1/00 Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
• CPC Class Codes: C03C 1/002 Use of waste materials, e.g. slags
• CPC Class Codes: G21F 9/305 Glass or glass like matrix C03B5/005 takes precedence; compositional aspects C03C
• CPC Class Codes: Y02P 40/50 Glass production, e.g. reusing waste heat during processing or shaping

Abstract

Process for vitrifying environmentally hazardous waste material in a glass melting furnace includes forming a batch including the waste material and no more than 30 weight percent additives including phonolite and SiO₂ containing substances. A gall layer 2-5 cm thick including alkali salts or alkaline earth salts is produced on the molten glass, and batch is added so that a batch layer over 5 cm thick is formed on top of the gall layer. After the batch layer is formed, the molten glass is heated solely by electrodes, and the thickness of the batch layer is maintained to produce a steep enough temperature gradient therein so that the furnace atmosphere remains relatively cool, and substantially all of the condensable components which emerge from the molten glass condense in the batch layer.

Claims

1. Process for vitrifying environmentally hazardous waste material in a glass melting furnace, comprising:

forming a glass melt having a surface in the furnace;

forming a batch containing the waste material and an additive consisting of at least one compound selected from the group consisting of phonolite and SiO₂ containing materials;

adding the batch to the furnace so that a batch layer is formed on the molten glass;

heating the molten glass after the batch layer is formed thereon, solely by devices in the molten glass;

producing a gall layer of glass gall on the surface of the glass melt between the glass melt and the batch layer, said glass gall consisting essentially of at least one of an alkali salt and an alkaline earth salt;

withdrawing glass gall from the gall layer as necessary and controlling the composition, supply, and distribution of the batch so that the gall layer and the batch layer are maintained at respective thicknesses which are sufficient to maintain the furnace atmosphere above the batch layer at a sufficiently low temperature so that substantially all of the condensable components which emerge from the molten glass and the gall layer condense in the batch layer; and

withdrawing the molten glass from the furnace via a first outlet means.

2. Process in accordance with claim 1 wherein said glass gall consists essentially of at least one compound selected from the group consisting of

CaSO₄, CaCl₂, MgSO₄, and MgCl₂ added during the melting process with said waste and/or as a separate additive, and

Na₂ SO₄, NaCl, K₂ SO₄, KCl, Li₂ SO₄, and LiCl produced by reaction with said CaSO₄, CaCl₂, MgSO₄, and MgCl₂.

3. Process in accordance with claim 1 characterized in that the thickness of the gall layer is from 2 cm to 5 cm.

4. Process in accordance with claim 1 wherein the thickness of the batch layer is more than 5 cm.

5. Process in accordance with claim 1 wherein during operation of the glass melting furnace, the required thermal energy is generated exclusively electrically by means of heating electrodes which extend into the glass melt.

6. Process in accordance with claim 1 wherein the necessary withdrawal of gall is carried out on a essentially horizontal plane and that the melted glass is separately withdrawn from the furnace while maintaining a constant level of the glass melt.

7. Process in accordance with claim 1 wherein the glass is withdrawn directly from inside the furnace from the depth of the melt.

8. Process in accordance with claim 7 wherein the first outlet means is a bottom outlet means.

9. Process in accordance with claim 1 wherein a second outlet means is provided for withdrawing the gall.

10. Process in accordance with claim 9 wherein the amount of withdrawn gall and, hence, gall layer thickness in the glass melting furnace are controlled by applying a strong vacuum at the second outlet means.

11. Process in accordance with claim 9 wherein the amount of withdrawn glass and, hence, the height of the glass melt level in the glass melting furnace are controlled by applying a strong vacuum at the first outlet means.

12. Process in accordance with claim 9 wherein the necessary withdrawal of gall from the second outlet means of the glass melting furnace is carried out discontinuously by means of tapping the furnace.

13. Process in accordance with claim 9 wherein the first and second outlet means are heated.

14. Process in accordance with claim 11 wherein the furnace has a bottom where a heavy metal melt gathers, and from time to time, the heavy metal melt is withdrawn from the furnace.

15. Process in accordance with claim 1 wherein exhaust gas emerging from the furnace falls within the range of 80°

to 400°

C.

16. Process as in claim 15 exhaust gas emerging from the furnace falls within the range from 100°

to 200°

C.