Copper paste composition

• US 5,035,837 A
• Filed: 06/28/1990
• Issued: 07/30/1991
• Est. Priority Date: 10/27/1989
• Status: Expired due to Term

• Current Assignee: Dai-Ichi Kogyo Seiyaku Company Limited (DKS Co., Ltd.), Dowa Mining Company Limited (DOWA Holdings Company Limited)
• Original Assignee: Dia-Ichi Kogyo Seiyaku Company Limited, Dowa Mining Company Limited (DOWA Holdings Company Limited)
• Inventors: Okada, Susumu, Sakuraba, Masami, Echigo, Masashi, Saeki, Shuji, Suehiro, Masatoshi
• Primary Examiner(s): Dixon, Jr., William R.
• Assistant Examiner(s): Green, Anthony J.
• Application Number:
  US07/544,973
• Time in Patent Office: 397 Days
• Field of Search: 106/1.13, 106/1.18, 106/1.23-1.26, 252/512, 252/518, 501/19, 501/20, 501/32
• US Class Current: 252/512
• CPC Class Codes: B22F 1/10 Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
• CPC Class Codes: C04B 35/45 based on copper oxide or solid solutions thereof with other oxides
• CPC Class Codes: C04B 35/6365 Cellulose or derivatives thereof
• CPC Class Codes: C22C 32/0021 Matrix based on noble metals, Cu or alloys thereof
• CPC Class Codes: H01B 1/16 the conductive material comprising metals or alloys
• CPC Class Codes: H05K 1/092 Dispersed materials, e.g. conductive pastes or inks

Abstract

A copper paste composition for low temperature firing on a ceramic substrate is comprised of inorganic components and organic vehicle components. The inorganic components mainly consist of cooper powder, cuprous oxide powder, cupric oxide powder and glass powder. The mixing ratio off the inorganic components of this composition is 100 parts by weight of copper powder, about 10 to 15 parts by weight of cuprous oxide powder, about 12 to 17 parts by weight of cupric oxide powder, and about 7 to 12 parts by weight of glass powder. The mixing ratio of the inorganic components with the organic vehicle components is about 95 to 70 parts by weight of the organic vehicle components. Also the the average particle size of the copper powder is in a range of about 0.5 to 3 μm and the oxygen content of the copper powder is about 0.05 to 0.15 weight percent.

Claims

1. A copper paste composition comprising about 95 to about 70 percent by weight of inorganic components and about 5 to about 30 percent by weight of organic vehicle components, said inorganic components comprising a powdered refractory material, and copper powder including cuprous oxide powder and cupric oxide powder in amounts such that about 10 to about 15 parts by weight of cuprous oxide powder, about 12 to about 17 parts by weight of cupric oxide powder, and about 7 to about 12 parts by weight of powdered refractory material, are included for each 100 parts by weight of copper powder.

2. The copper paste composition of claim 1 wherein said copper powder has a mean particle size of about 0.5 to about 3 μ

m and an oxygen content between about 0.05 and about 0.15 percent by weight.

3. The copper paste composition of claim 2 wherein said cuprous oxide powder has a particle size range from about 0.5 to about 5 μ

m.

4. The copper paste composition of claim 3 wherein said cuprous oxide powder has a particle size range from about 0.5 to about 2 μ

m.

5. The copper paste composition of claim 2 wherein said organic vehicle components include a solvent and a resin.

6. The copper paste composition of claim 5 wherein said solvent is selected from the group consisting of terpineol, C₁₀ to C₁₈ alcohols, and mixtures thereof.

7. The copper paste composition of claim 5 wherein said resin is selected from the group consisting of cellulosic resins, acrylic resins, methacrylic resins, terpene resins and mixtures thereof.

8. The copper paste composition of claim 5 wherein said organic vehicle components include about 10 percent or less by weight of resin.

9. The copper paste composition of claim 2 further comprising about 5 parts or less by weight of an inorganic oxide per 100 parts by weight of said copper powder.

10. The copper paste composition of claim 9 wherein said inorganic oxide is selected from the group consisting of vanadium oxide, lead oxide, antimony oxide and mixtures thereof.

11. The copper paste composition of claim 5 wherein said organic vehicle components further include a plasticizer.

12. The copper paste composition of claim 11 wherein said plasticizer is dibutyl phthalate.

13. The copper paste composition of claim 1 wherein said powdered refractory material is glass.

14. The copper paste composition of claim 13 wherein said glass powder has a softening point of between about 300°

C. and about 600°

C.

15. A copper paste composition for low temperature firing comprised of copper powder with an oxygen content between about 0.05 to 0.15 weight percent, cuprous oxide powder, cupric oxide powder, and organic vehicle components in amounts such that about 10 to about 15 parts by weight of cuprous oxide powder and about 12 to about 17 parts by weight of cupric oxide powder are included for each 100 parts by weight of copper powder.

16. In a copper paste composition for low temperature firing wherein copper powder is blended into a paste including a binder, a solvent and a powdered refractory material, the paste is applied to a substrate and fired at a temperature sufficient to remove the solvent and the binder from the copper powder and the powdered refractory material and to adhere the copper powder, bound in the refractory material adhered to the substrate, the improvement comprising the copper powder including about 10 to about 15 parts by weight of cuprous oxide powder and about 12 to about 17 parts by weight of cupric oxide powder for each 100 parts by weight of copper powder.