Process for increasing the reactivity of cellulose-containing materials

• US 5,037,663 A
• Filed: 02/02/1990
• Issued: 08/06/1991
• Est. Priority Date: 10/14/1981
• Status: Expired due to Term

• Current Assignee: Colorado State University Research Foundation
• Original Assignee: Colorado State University Research Foundation
• Inventors: Dale, Bruce E.
• Primary Examiner(s): Hastings, Karen M.
• Application Number:
  US07/474,646
• Time in Patent Office: 550 Days
• Field of Search: 127/37, 426/69, 426/319, 426/442, 426/447, 426/448, 426/807, 426/635, 162/63, 162/64, 162/81, 162/83, 162/90, 162/21, 162/23
• US Class Current: 426/69
• CPC Class Codes: A23K 10/30 from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms obtained by microbiological or biochemical processes, e.g. using yeasts or enzymes, A23K10/10
• CPC Class Codes: C08B 1/00 Preparatory treatment of cellulose for making derivatives thereof , e.g. pre-treatment, pre-soaking, activation
• CPC Class Codes: Y10S 426/807 Poultry or ruminant feed

Abstract

This process for increasing the reactivity of cellulose-containing materials such as animal feedstuffs involves contacting the material, in a pressure vessel, with a volatile liquid swelling agent e.g. ammonia, which has a vapor pressure greater than atmospheric pressure at ambient temperatures. The contact is maintained for a time period sufficient for the agent to swell the cellulose of the material. The pressure is then rapidly reduced to atmospheric pressure, thereby causing the agent to boil and explode the material. The rapid pressure reduction also causes some freezing of the cellulose. The swelling agent is separated from said cellulose-containing material and recovered for recycling. The process also increases the water holding capacity of cellulose-containing materials.

Claims

1. A method for increasing the reactivity of cellulosic materials, comprising:

a. contacting cellulose-containing material with liquid ammonia in a pressure vessel;

b. mixing said cellulose-containing material and liquid ammonia in said pressure vessel absent the application of thermal energy to the pressure vessel and its contents above the ambient air temperature surrounding the pressure vessel, at a pressure of at least the vapor pressure of liquid ammonia for the temperature in the pressure vessel, and for a time sufficient to wet and swell with liquid ammonia substantially all the cellulose in said material; and

c. reducing rapidly the pressure inside said pressure vessel to a point sufficient to boil liquid ammonia and explode or rupture the cellulose fiber structure.

3. The method of claim 1 or 2 wherein said pressure reduction is to atmospheric pressure.

4. The method of claims 1 or 2 wherein said cellulosic or cellulose-containing material is left in contact with said ammonia after said pressure reduction in order to further react the cellulose with ammonia.

5. The method of claim 1 or 2 further comprising recovering the volatized ammonia after said rapid pressure reduction.

6. The method of claim 5 further comprising recycling the ammonia for further processing of cellulose-containing material.

7. The method of claims 1 or 2 further comprising hydrolyzing said cellulose-containing material after said liquid ammonia pressure treatment.

8. The method of claims 1 or 2 further comprising fermenting said cellulose-containing material after said liquid ammonia pressure treatment.

2. A method for increasing the reactivity of cellulosic materials, comprising:

a. mixing cellulose-containing material and liquid ammonia in a pressure vessel;

b. pressurizing said mixture at a temperature in the pressure vessel about equal to the room temperature surrounding the pressure vessel, at a pressure substantially equal to or greater than the vapor pressure of liquid ammonia at said temperature, and for a time sufficient for the liquid ammonia to swell the cellulose in said cellulose-containing material; and

c. substantially instantaneously vaporizing at least a portion of said liquid ammonia by rapidly lowering the pressure inside said pressure vessel to explode or rupture the cellulose fiber structure.