Liquid segment polyurethane gel and couplers for ultrasonic diagnostic probe comprising the same

• US 5,039,774 A
• Filed: 05/30/1990
• Issued: 08/13/1991
• Est. Priority Date: 06/02/1988
• Status: Expired due to Term

• Current Assignee: Takiron Company Limited (Itochu Corporation)
• Original Assignee: Takiron Company Limited (Itochu Corporation)
• Inventors: Taniguchi, Masahiko, Boutani, Hidekazu, Shikinami, Yasuo, Tsuta, Kaoru
• Primary Examiner(s): WELSH JR, MAURICE
• Application Number:
  US07/530,517
• Time in Patent Office: 440 Days
• Field of Search: 528/60, 528/66, 128/632, 128/653 R, 128/660.01, 128/660.02, 128/660.06, 128/662.03
• US Class Current: 528/60
• CPC Class Codes: A61B 8/4281 characterised by sound-transmitting media or devices for coupling the transducer to the tissue
• CPC Class Codes: C08G 18/10 Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• CPC Class Codes: C08G 18/12 using two or more compounds having active hydrogen in the first polymerisation step
• CPC Class Codes: C08G 18/40 High-molecular-weight compounds C08G18/2805 takes precedence
• CPC Class Codes: C08G 18/48 Polyethers
• CPC Class Codes: C08G 18/4829 Polyethers containing at least three hydroxy groups C08G18/4833 - C08G18/5096 take precedence
• CPC Class Codes: C08G 2220/00 Compositions for preparing gels other than hydrogels, aerogels and xerogels
• CPC Class Codes: C08G 2270/00 Compositions for creating interpenetrating networks

Abstract

A one-component system polyurethane gel and a coupler for ultrasonic diagnostic probes comprising the same are disclosed. The gel is obtained by reacting a polyol having a room temperature liquid alkylene oxide chain and/or a polyurethane polyol prepolymer having a room temperature liquid alkylene oxide chain with a polyurethane polyisocyanate prepolymer having a room temperature liquid alkylene oxide chain. The gel causes no bleeding or evaporation of a dispersion medium and is therefore excellent in safety to the human body and preservation stability.

Claims

1. A coupler for a probe for ultrasonic diagnosis which comprises a liquid segment polyurethane gel obtained by reacting a polyol having an alkylene oxide chain which is liquid at room temperature and/or a polyurethane polyol prepolymer having an alkylene oxide chain which is liquid at room temperature with a polyurethane polyisocyanate prepolymer having an alkylene oxide chain which is liquid at room temperature, said gel having a socket into which the probe for ultrasonic diagnosis is to be inserted and a smooth part which is to be brought into planar contact with the skin.

2. A coupler as claimed in claim 1, wherein a ratio of terminal hydroxyl groups of said polyol and/or polyurethane polyol prepolymer to terminal isocyanato groups of said polyurethane polyisocyanate prepolymer, OH/NCO, is between 1 and 2.0.

3. A coupler as claimed in claim 1, wherein either one of said polyol and/or polyurethane polyol prepolymer and said polyurethane polyisocyanate prepolymer is at least bifunctional, with the other being at least trifunctional.

4. A coupler as claimed in claim 1, wherein said alkylene oxide chain in said polyol and/or polyurethane polyol prepolymer and said polurethane polyisocyanate prepolymer is selected from the group consisting of polymethylene glycol, polyethylene glycol, polypropylene glycol, polybutylene glycol, polytetramethylene glycol, polypentamethylene glycol, polyhexamethylene glycol, polyheptamethylene glycol, and a copolymer comprising two or more thereof.

5. A coupler as claimed in claim 1, wherein said polyol has a molecular weight of from about 150 to 6,000, said polyurethane polyol prepolymer has a molecular weight of from about 1,400 to 10,000, and said polyurethane polyisocyanate prepolymer has a molecular weight of from about 500 to 10,000.

6. A coupler as claimed in claim 1, wherein a proportion of the alkylene oxide chain in said gel is from about 75 to 90%.