Supercritical delignification of wood

• US 5,041,192 A
• Filed: 09/16/1988
• Issued: 08/20/1991
• Est. Priority Date: 09/16/1988
• Status: Expired due to Term

• Current Assignee: University of South Florida (State University System of Florida)
• Original Assignee: University of South Florida (State University System of Florida)
• Inventors: Chen, Shan L., Sunol, Aydin K.
• Primary Examiner(s): Hastings, Karen M.
• Application Number:
  US07/245,844
• Time in Patent Office: 1,068 Days
• Field of Search: 162/70, 162/72, 162/82, 162/90, 162/63, 162/77, 162/81, 162/83, 162/64
• US Class Current: 162/63
• CPC Class Codes: D21C 3/22 Other features of pulping processes

Abstract

An improved wood pulping process for the delignification of wood in a solvent wherein the solvent is a supercritical fluid under supercritical conditons and contains a delignification agent such as sodium hydroxide, sodium sulfide and/or sodium bisulfate.

Claims

1. Process for converting wood to pulp which comprises contacting wood with a supercritical fluid that contains a delignification agent comprising sodium hydroxide and/or sodium sulfide and/or sodium bisulfate under supercritical conditions sufficient to remove lignin, extractive and hemicellulose from the wood thereby making a full chemical pulp.

2. Process according to claim 1 wherein the supercritical fluid is a fluid selected from the group consisting of lower alkenes, lower alkanes, nitrous oxide, sulfur dioxide, ammonia, water, lower straight chain alcohols, amines, phenol, carbon dioxide, mixtures thereof, and other compounds with critical temperatures in the range of 5°

C. to 250°

C.

3. Process according to claim 2 wherein the supercritical conditions are a temperature from 5°

C. to 250°

C. and a pressure from 400 to 3500 pounds per square inch absolute.

4. Process according to claim 3 wherein the supercritical fluid is ammonia-water containing as the delignification agent sodium hydroxide and sodium sulfide.

5. Process for removing lignin from a lignin containing cellulosic material which comprises contacting the cellulose material with a supercritical fluid containing an active delignification agent comprising sodium hydroxide and/or sodium sulfide and/or sodium bisulfate under supercritical conditions whereby lignin is removed from the cellulosic material.

6. Process according to claim 5 wherein the supercritical fluid is a fluid selected from the group consisting of lower alkenes, lower alkanes, nitrous oxide, sulfur dioxide, ammonia, water, lower straight chain alcohols, amines, phenol, carbon dioxide, mixtures thereof, and other compounds with critical temperatures in the range of 5°

C. to 250°

C.

7. Process according to claim 6 wherein the supercritical conditions are a temperature from 5°

C. to 250°

C. and a pressure from 400 to 3500 pounds per square inch absolute.

8. Process according to claim 7 wherein the supercritical fluid is ammonia-water containing as the delignification agent sodium hydroxide and sodium sulfide.

9. Process for the delignification of a cellulosic material containing lignin which comprises impregnating the cellulosic material with a delignification agent comprising sodium hydroxide and/or sodium sulfide and/or sodium bisulfate and digesting the impregnated material in an ammonia based fluid comprising ammonia containing less than about 12% by weight water under supercritical conditions.

10. Process according to claim 9 wherein the delignification agent comprises an aqueous solution of sodium hydroxide and sodium sulfide.

11. Process according to claim 10 wherein supercritical conditions include a temperature from 5°

C. to 250°

C. and a pressure from 400 to 3500 pounds per square inch absolute.

12. Process for making paper which comprises impregnating wood with a first supercritical fluid containing a delignification agent comprising sodium hydroxide and/or sodium sulfide and/or sodium bisulfate under supercritical conditions, digesting the impregnated wood in the presence of a second supercritical fluid maintained under supercritical conditions sufficient to extract lignins, extractives and hemicellulose from the wood and to separate the wood into discrete fibers thereby producing a full chemical pulp, separating a liquor comprising the second fluid containing lignins, extractives and hemicellulose from the pulp and treating the pulp to conditions sufficient to convert the pulp to paper.

13. Process according to claim 12 wherein the first supercritical fluid comprises ammonia-water containing as the delignification agent sodium hydroxide and sodium sulfide.

14. Process according to claim 13 wherein the digesting of impregnated wood is conducted at a temperature in the range of 145°

C. and 160°

C. and a pressure from 1800 to 3000 pounds per square inch absolute.