Hop flavor which is odor forming impurity free

• US 5,041,300 A
• Filed: 04/30/1990
• Issued: 08/20/1991
• Est. Priority Date: 04/03/1987
• Status: Expired due to Fees

• Current Assignee: Kalamazoo Holdings, Inc.
• Original Assignee: Kalamazoo Holdings, Inc.
• Inventors: Todd, Paul H. Jr., Guzinski, James A.
• Primary Examiner(s): PADEN, CAROLYN A
• Application Number:
  US07/516,769
• Time in Patent Office: 477 Days
• Field of Search: 426/600, 568/377
• US Class Current: 426/600
• CPC Class Codes: C12C 3/08 Solvent extracts from hops
• CPC Class Codes: C12C 3/10 using carbon dioxide
• CPC Class Codes: C12C 3/12 Isomerised products from hops
• CPC Class Codes: C12C 5/026 Beer flavouring preparations
• CPC Class Codes: C12C 9/025 Preparation of hop extracts extraction with beerwort C12C9/02; Isomerisation of these extracts; Treatment of beerwort with these extracts; Surrogates of the hop

Abstract

Two-phase and salt-containing intermediate products and the final purified hop flavor which is essentially free of impurities and which purified isoalpha acid or isohumulone will therefore not produce fruity, estery, sour aromas when used to flavor beverages, e.g., beer or ale, are disclosed. A rapid test for the detection of such aromas, involving dissolution of the hop flavor in ethanol at a concentration of one-half percent w/v and allowing the solution to stand for four days, allows accelerated determination of the presence or absence of such aromas and the odor-forming impurities which cause the undesirable odors.

Claims

1. A hop flavor composition having an organic phase consisting essentially of a hop flavor selected from unreduced and reduced alpha acids and isoalpha acids and an aqueous phase at a pH of at least 4 and below 8.

3. The product of claim 1, wherein the pH is at least 7.

4. The product of any of claims 1-3, wherein the hop flavor is selected from humulone, isohumulone, dihydroisohumulone, tetrahydroisohumulone, and hexahydroisohumulone.

5. The product of any of claims 1 through 3, wherein the organic phase also comprises an organic solvent.

6. The product of any claims 1 through 3, wherein the aqueous phase also comprises ethanol.

2. The product of claim 2, wherein the pH is at least 6.

7. A beer flavored post-fermentation with an isoalpha acid or isohumulone flavoring agent, selected from unreduced and reduced alpha acids and isoalpha acids, which is essentially odor-causing-impurity free and which therefore has a more reproducible and acceptable flavoring and aroma, said flavoring agent being produced by separation of the flavoring agent as an organic phase from an aqueous solution containing undesirable odor-forming impurities at a pH above 4 in the presence of a food-grade water-soluble salt.

8. A beer flavored post-fermentation with an isoalpha acid or isohumulone flavoring agent of claim 7, wherein the flavoring agent is an isoalpha acid.

9. A beer flavored post-fermentation with an isoalpha acid or isohumulone flavoring agent of claim 8, wherein the isoalpha acid is selected from isohumulone, dihydroisohumulone, tetrahydroisohumulone, and hexahydroisohumulone.

10. A beer flavored post-fermentation with an isoalpha acid or isohumulone flavoring agent of claim 9, wherein the flavoring agent is a tetrahydroisuhumulone.

11. A composition having an organic phase consisting essentially of a flavoring agent selected from unreduced and reduced alpha acids and isoalpha acids and an aqueous phase which contains undesirable odor-forming impurities at a pH of at least 4, wherein the aqueous phase contains a food-grade water-soluble salt.

12. The product of claim 11, wherein the pH is at least 6.

13. The product of claim 12, wherein the pH is at least 7.

14. The composition of any claims 11, 12 or 13, wherein the flavoring agent is selected from humulone, isohumulone, dihydroisohumulone, tetrahydroisohumulone, and hexahydroisohumulone.

15. The product of any of claims 11-13, wherein the food-grade water-soluble salt is present at a concentration of at least one-half percent weight/volume.

16. The product of claim 15, wherein the food-grade water-soluble salt is present at a concentration sufficient to maintain no more than about nine percent of the flavoring agent in the aqueous phase.

17. The product of claim 15, wherein the food-grade water-soluble salt is present at a concentration of at least two percent weight/volume.

18. The product of any of claims 11-13 and 16-17, wherein the salt is sodium chloride.

19. The product of any of claims 11-13, 16 and 17, wherein the organic phase also comprises a food-grade organic solvent.

20. A hop flavor composition of claim 11, wherein the organic phase consists essentially of tetrahydroisohumulone and wherein the aqueous phase contains at least about one-half percent weight per volume of salt and wherein the pH is at least about 6.

21. The product of claim 20, wherein the aqueous phase also comprises ethanol.

22. A beer flavored post-fermentation with an isoalpha acid or isohumulone flavoring agent, selected from unreduced and reduced alpha acids and isoalpha acids, which is essentially odor-causing-impurity free and which therefore has a more reproducible and acceptable flavoring and aroma, said flavoring agent being produced by separation of the flavoring agent as an organic phase from an aqueous solution containing undesirable odor-forming impurities at a pH above 4 and below 8.

23. A beer flavored post-fermentation with an isoalpha acid or isohumulone flavoring agent of claim 22, wherein the flavoring agent is an isoalpha acid.

24. A beer flavored post-fermentation with an isoalpha acid or isohumulone flavoring agent of claim 23, wherein the isoalpha acid is selected from isohumulone, dihydroisohumulone, tetrahydroisohumulone, and hexahydroisohumulone.

25. A beer flavored post-fermentation with an isoalpha acid or isohumulone flavoring agent of claim 24, wherein the flavoring agent is a tetrahydroisohumulone.