Oil recovery process for use in fractured reservoirs

• US 5,042,580 A
• Filed: 07/11/1990
• Issued: 08/27/1991
• Est. Priority Date: 07/11/1990
• Status: Expired due to Fees

• Current Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Original Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Inventors: Cullick, Alvin S., Hazlett, Randy D.
• Primary Examiner(s): Suchfield, George A.
• Application Number:
  US07/551,226
• Time in Patent Office: 412 Days
• Field of Search: 166/252, 166/271, 166/273, 166/274, 166/275
• US Class Current: 166/252.1
• CPC Class Codes: C09K 8/60 Compositions for stimulating production by acting on the underground formation
• CPC Class Codes: E21B 43/16 Enhanced recovery methods for obtaining hydrocarbons
• CPC Class Codes: E21B 43/164 Injecting CO2 or carbonated water in combination with organic material C09K8/594

Abstract

A process for recovering oil from fractured formations is provided which involves altering the wettability of the formation, particularly at the interface of the fracture and rock matrix. The process of the present invention improves the ability of injected fluids flowing in the fracture to enter the rock matrix to displace oil. When employed in conjunction with a water-wet fractured oil-bearing formation, the process comprises the steps of: injecting a wettability agent capable of transforming the water-wet fractured formation from water-wet to oil-wet; contacting the oil-wet fractured formation with the wettability agent so injected at a fracture/matrix interface; injecting an oil miscible solvent; and recovering oil. A process for use with an oil-wet fractured oil-bearing formation is also provided.

Claims

1. A process for recovering oil from a water-wet fractured oil-bearing formation having an injection well and production well in fluid communication with a substantial portion of the formation, comprising the steps of:

(a) injecting a wettability agent selected from the group consisting of cationic surfactants, anionic surfactants, silanes, fatty acid complexes and aromatic/asphaltic oils, said wettability agent capable of transforming the water-wet fractured formation from water-wet to oil-wet;

(b) contacting the water-wet fractured formation with the wettability agent injected in step (a) at a fracture/matrix interface;

(c) injecting an oil miscible fluid; and

(d) recovering oil.

2. The process of claim 1, wherein the wettability agent is a water soluble Werner-type chrome complex in which trivalent chromium atoms are coordinated with a ligand of a carboxylic acid.

3. The process of claim 2, wherein the ligand of the carboxylic acid of the Werner-type chrome complex contains a hydrocarbon radical having two to eight carbon atoms.

4. The process of claim 1, wherein the oil miscible fluid is an oil-miscible solvent selected from the group of consisting of ethane, propane, butane, pentane, hexane and mixtures thereof.

5. The process of claim 1, wherein the oil miscible fluid is carbon dioxide.

6. The process of claim 1, further comprising the step of waterflooding via the injection well to recover oil from the production well until economic oil recovery is exceeded, wherein said waterflooding step is conducted prior to said step of injecting a wettability agent.

7. The process of claim 6, wherein the wettability agent is a water soluble Werner-type chrome complex in which trivalent chromium atoms are coordinated with a ligand of a carboxylic acid.

8. The process of claim 7, wherein the ligand of the carboxylic acid of the Werner-type chrome complex contains a hydrocarbon radical having two to eight carbon atoms.

9. The process of claim 6, wherein the oil miscible fluid is an oil-miscible solvent selected from the group of consisting of ethane, propane, butane, pentane, hexane and mixtures thereof.

10. The process of claim 6, wherein the oil miscible fluid is carbon dioxide.

11. A process for enhancing the recovery of oil from a fractured oil-bearing formation having an initial wettability characteristic at a fracture-matrix interface and further having an injection well and production well in fluid communication with a substantial portion of the formation, comprising the steps of:

(a) determining the initial wettability characteristic at the fracture-matrix interface;

(b) injecting a wettability agent capable of transforming the initial wettability characteristic at the fracture-matrix interface;

(c) contacting the fractured formation with the wettability agent injected in step (a) at the fracture-matrix interface;

(d) injecting a flooding fluid; and

(e) recovering oil.

12. The process of claim 11, wherein the wettability agent is selected from the group consisting of cationic surfactants, anionic surfactants, silanes, fatty acid complexes and aromatic/asphaltic oils.

13. A process for recovering oil from an oil-wet fractured oil-bearing formation having an injection well and production well in fluid communication with a substantial portion of the formation, comprising the steps of:

(a) conducting a miscible fluid flood to recover oil until economic oil recovery is exceeded;

(b) injecting a wettability agent capable of transforming the oil-wet fractured formation from oil-wet to water-wet;

(c) contacting the oil-wet fractured formation with the wettability agent injected in step (b) at a fracture-matrix interface;

(d) injecting a water-based flooding fluid; and

(e) recovering oil.

14. The process of claim 13, wherein the wettability agent is a chemical agent having a hydrophobic tail and a hydrophilic head, the hydrophobic tail capable of attaching to an oil-wet rock surface.

15. The process of claim 13, wherein the oil miscible fluid is an oil-miscible solvent selected from the group of consisting of ethane, propane, butane, pentane, hexane and mixtures thereof.

16. The process of claim 13, wherein the oil miscible fluid is carbon dioxide.