Treating contaminated effluents and groundwaters

• US 5,043,080 A
• Filed: 02/26/1990
• Issued: 08/27/1991
• Est. Priority Date: 02/26/1990
• Status: Expired due to Fees

• Current Assignee: Calgon Carbon Canada, Inc. (Kuraray Company Limited)
• Original Assignee: Solarchem Enterprises, Inc. (Kuraray Company Limited)
• Inventors: Stevens, R. D. Samuel, Brown, Pauline M., Buckley, J. Adele, Cater, Stephen R.
• Primary Examiner(s): Hruskoci, Peter
• Application Number:
  US07/484,282
• Time in Patent Office: 547 Days
• Field of Search: 210/748, 210/754, 210/759, 210/763, 210/908, 210/909
• US Class Current: 210/748.15
• CPC Class Codes: C02F 1/32 with ultraviolet light
• CPC Class Codes: C02F 1/722 Oxidation by peroxides
• CPC Class Codes: C02F 1/725 by catalytic oxidation
• CPC Class Codes: C02F 2103/06 Contaminated groundwater or leachate
• CPC Class Codes: C02F 2305/10 Photocatalysts
• CPC Class Codes: Y02W 10/37 using solar energy
• CPC Class Codes: Y10S 210/908 Organic
• CPC Class Codes: Y10S 210/909 Aromatic compound, e.g. pcb, phenol

Abstract

A method of treating a liquid effluent or groundwater containing organic contaminants is provided. The liquid effluent or groundwater containing the organic contaminants is contacted with hydrogen peroxide and transition metal ions. The hydrogen peroxide and transition metal ions are present in effective amounts based on the concentration of the organic contaminants in the liquid effluent or groundwater. The liquid effluent or groundwater is then irradiated with UV light having a poly- chromatic output between about 200 to 400 nm to decompose the organic contaminants. The ratio of hydrogen peroxide to transition metal ions is selected so as to favor the absorption of UV light by the hydrogen peroxide in the irradiation step.

Claims

1. A method of treating a liquid effluent or groundwater containing organic contaminants comprising the steps of:

(a) providing a liquid effluent or groundwater containing organic contaminants;

(b) contacting the liquid effluent or groundwater at a pH of between about 2 and 4 with hydrogen peroxide and transition metal ions, the hydrogen peroxide and transition metal ions being present in effective amounts based on the concentration of the organic contaminants in the liquid effluent or groundwater; and

(c) irradiating the liquid effluent or groundwater with UV light, the UV light having a polychromatic output between about 200 to 400 nm and an input power of at least about 1 Kw to decompose the organic contaminants;

wherein the ratio of hydrogen peroxide to transition metal ions is about 10;

1 to 1;

1 and is selected so as to favor the absorption of UV light by the hydrogen peroxide and the organic contaminant relative to the absorption of UV light by transition metal ions in step (c).

2. The method as claimed in claim 1, wherein the UV light used in step (c) has a polychromatic output between about 200 to 300 nm.

3. The method as claimed in any one of claims 1 or 2, wherein the transition metal ions are supplied by iron or copper compounds.

4. The method as claimed in any one of claims 1 or 2, wherein the transition metal ions are supplied by one or more of Fe(OH)₃, Fe₂ O₃, FeCl₃, or Fe₂ (SO₄)₃.

5. The method as claimed in any one of claims 1 or 2, wherein the transition metal ions are supplied by one or more of FeO, Fe(OH)₂, FeCl₂, FeCO₃ or FeSO₄.

6. The method as claimed in any one of claims 1 or 2 wherein the transition metal ions are supplied by FeSO₄ •

7H₂ O.

7. The method as claimed in any one of claims 1 or 2, wherein the organic contaminants are one or more compounds selected from the group consisting of benzene, toluene, xylene, napthalene, anthracene, chlorobenzene, trinitrotoluene, trichloroethane, trichloroethylene, or dioxane.

8. The method as claimed in any one of claims 1 or 2, wherein the organic contaminants are selected from at least one member of the group of compounds consisting of linear, branched and cyclic alkyls and alkenyls having 1 to 20 carbon atoms, said alkyls and alkenyls consisting of substituted and unsubstituted alkyls and alkenyls, substituents being selected from the group of radicals consisting of fluorine, chlorine, bromine, nitro, sulfo, carboxyl, hydroxyl of C₁ -C₁₀ -alkoxy;

aromatic and polyaromatic compounds, said aromatic and polyaromatic compounds consisting of substituted and unsubstituted aromatic and polyaromatic compounds, substituents being selected from the group of radicals consisting of linear and branched alkyls and alkenyls having 1 to 10 carbon atoms, fluorine, chlorine, bromine, nitro, sulfo, carboxyl, hydroxyl or C₁ -C₁₀ -alkoxy;

fused phenols; and

, ethers.

9. The method as claimed in any one of claims 1 or 2, wherein the organic contaminants are selected from at least one member of the group consisting of substituted and unsubstituted aromatic and polyaromatic compounds and ethers, substituents being selected from the group of radicals consisting of linear and branched alkyls having 1 to 10 carbon atoms, nitro, chloro and bromo.

10. The method as claimed in any one of claims 1 or 2, wherein the organic contaminants are selected from at least one member of the group consisting of phenolics, substituted and unsubstituted biphenyls and fused phenols, substituents being selected from the group consisting of linear and branched alkyls and alkenyls having 1 to 10 carbon atoms, fluorine, chlorine, bromine, nitro, sulfo, carboxyl, hydroxyl, and C₁ -C₁₀ -alkoxy.