Process and apparatus for multi-stage regeneration of catalyst in a bubbling bed catalyst regenerator and side mounted fast fluidized bed regenerator

• US 5,047,140 A
• Filed: 04/27/1990
• Issued: 09/10/1991
• Est. Priority Date: 04/27/1990
• Status: Expired due to Fees

• Current Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Original Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Inventors: Owen, Hartley, Schipper, Paul H.
• Primary Examiner(s): MYERS, HELANE ELEANORA
• Application Number:
  US07/515,943
• Time in Patent Office: 501 Days
• Field of Search: 208/113, 208/164, 208/153, 422/144, 422/147, 502/41, 502/43
• US Class Current: 208/113
• CPC Class Codes: C10G 11/182 Regeneration

Abstract

A process and apparatus are disclosed for achieving turbulent or fast fluidized bed regeneration of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. A closed coke combustor vessel is added alongside an existing regenerator vessel, and spent catalyst is discharged into a transfer pot beneath the existing dense bed, then into the coke combustor. Catalyst is regenerated in a turbulent or fast fluidized bed, and discharged into the dilute phase region above the existing bubbling dense bed. The discharge line preferably encompasses, and is in a heat exchange relationship with, the spent catalyst standpipe. Discharge catalyst is collected in the bubbling dense bed surrounding the coke combustor, and may be given an additional stage of regeneration. Catalyst may be recycled from the dense bed to the transfer pot.

Claims

1. A process for the fluidized catalytic cracking of a heavy feed to lighter more valuable products by mixing, in the base of a riser reactor, a heavy crackable feed with a source of hot regenerated catalytic cracking catalyst withdrawn from a catalyst regenerator, and cracking said feed in said riser reactor to produce catalytically cracked products and spent catalyst which are discharged from the top of the riser into a catalyst disengaging zone wherein cracked products are separated from spent catalyst, spent catalyst is discharged from said disengaging zone into a catalyst stripper contiguous with and beneath said disengaging zone and wherein said spent catalyst is contacted with a stripping gas to produce stripped catalyst, and said stripped catalyst is collected in a vertical standpipe beneath the stripping zone and then discharged from said standpipe into a catalyst regeneration zone contiguous with and beneath said stripping zone, and said regeneration zone comprises a single dense phase bubbling fluidized bed of catalyst to which an oxygen containing regeneration gas is added and from which hot regenerated catalyst is withdrawn and recycled to said riser reactor, characterized by:

discharging said stripped catalyst from said catalyst standpipe into a closed spent catalyst transfer vessel which is at least partially below said bubbling dense bed;

adding a fluidizing gas to said transfer vessel in an amount sufficient to fluidize the spent catalyst and transfer said spent catalyst via a transfer line into a coke combustor pod at an elevation above said transfer vessel and to a side of said regenerator vessel;

adding oxygen or an oxygen containing gas to said coke combustor vessel in an amount sufficient to provide a superficial vapor velocity which will maintain a majority of the catalyst therein in a state of turbulent or fast fluidization;

transferring catalyst and flue gas from said coke combustor into a transfer line connective with said dilute phase region within said regenerator vessel containing said bubbling fluidized bed; and

discharging and separating catalyst and flue gas from said transfer line in a disengaging means which directs separated catalyst from said transfer line down into said bubbling fluidized bed.

2. The process of claim 1 wherein the disengaging means comprises an a vertical cylinder which is axially aligned with and at least partially encloses said spent catalyst standpipe, said disengaging means having an inlet connective with the transfer line from the coke combustor and having upper and lower annular outlets within the dilute phase region above the bubbling dense bed.

3. The process of claim 1 wherein the disengaging means comprises a cyclone separator.

4. The process of claim 1 wherein hot regenerated catalyst is transferred from said bubbling dense bed down to said transport vessel to mix with spent catalyst.

5. The process of claim 4 wherein hot regenerated catalyst is transferred from said bubbling dense bed down to said transport vessel to mix with spent catalyst via a fixed flow catalyst transfer means.

6. The process of claim 5 wherein the fixed flow catalyst transfer means consists essentially of an open pipe connecting the bubbling dense bed to the transport vessel.

7. A process for the fluidized catalytic cracking of a heavy feed to lighter more valuable products by mixing, in the base of a riser reactor, a heavy crackable feed with a source of hot regenerated catalytic cracking catalyst withdrawn from a catalyst regenerator, and cracking said feed in said riser reactor to produce catalytically cracked products and spent catalyst which are discharged from the top of the riser into a catalyst disengaging zone wherein cracked products are separated from spent catalyst, spent catalyst is discharged from said disengaging zone into a catalyst stripper contiguous with and beneath said disengaging zone and wherein said spent catalyst is contacted with a stripping gas to produce stripped catalyst, and said stripped catalyst is collected in a vertical standpipe beneath the stripping zone and then discharged from said standpipe into a catalyst regeneration zone contiguous with and beneath said stripping zone, and said regeneration zone comprises a single dense phase bubbling fluidized bed of catalyst to which an oxygen containing regeneration gas is added and from which hot regenerated catalyst is withdrawn and recycled to said riser reactor, characterized by:

heating said stripped catalyst in said stripped catalyst standpipe by indirect heat exchange with a dilute phase of at least partially regenerated catalyst;

discharging said heated stripped catalyst into a closed spent catalyst transfer vessel which is at least partially below said bubbling dense bed;

adding combustion air to said transfer vessel in an amount sufficient to burn from 1 to 10% of the coke on the spent catalyst and to fluidize the spent catalyst and transfer it via a transfer line into a coke combustor pod at an elevation above said transfer vessel and to a side of said regenerator vessel;

adding additional oxygen or an oxygen containing gas to said coke combustor vessel in an amount sufficient to provide a superficial vapor velocity which will maintain a majority of the catalyst therein in a state of turbulent or fast fluidization;

transferring catalyst and flue gas from said coke combustor into a transfer line connective with said dilute phase region within said regenerator vessel containing said bubbling fluidized bed; and

discharging and separating catalyst and flue gas from said transfer line into a disengaging means comprising a vertical cylinder which is axially aligned with and at least partially encloses said spent catalyst standpipe, said disengaging means having an inlet connective with the transfer line from the coke combustor and having upper and lower annular outlets within the dilute phase region above the bubbling dense bed.