Closed loop reactant/product management system for electrochemical galvanic energy devices

• US 5,047,298 A
• Filed: 11/13/1990
• Issued: 09/10/1991
• Est. Priority Date: 11/13/1990
• Status: Expired due to Term

• Current Assignee: Energy Partners, L. C.
• Original Assignee: Perry Oceanographics, Inc.
• Inventors: Alessi, Donald P. Jr., Person, Abraham, Perry, John H. Jr., Misiaszek, Steven M.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US07/612,350
• Time in Patent Office: 301 Days
• Field of Search: 429/19, 429/17, 429/20, 429/26, 429/34, 429/25, 429/14, 429/24, 429/38, 429/39, 429/13
• US Class Current: 429/411
• CPC Class Codes: H01M 8/02 Details electrodes H01M4/86 - H01M4/98
• CPC Class Codes: H01M 8/04 Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

The present invention teaches a closed loop energy system including means capable of managing both the cooling cycle and the fuel/oxidant gas flow in conjunction with a fuel cell. The system includes a plurality of galvanic cells, gas flow conduit means, internal fluid flow conduit means, heat exchanger means, liquid-gas separator means, and gas repressurization means.

Claims

1. A closed loop reactant/product management system for electrochemical galvanic energy devices, the system comprising:

(a) a modular package comprising a plurality of galvanic cells, two internal gas flow conduit means for independently carrying each of two gaseous reactants, which form a liquid product within the galvanic cells, and an internal liquid flow conduit means for independently carrying a cooling liquid to the galvanic cells, the cooling liquid being derived from the liquid product;

(b) first and second gas supply connecting means each designed to provide make-up gaseous reactants, respectively, to the system;

(c) indirect heat exchanger means in fluid flow connection with the internal liquid flow conduit means;

(d) first and second liquid-gas separator means and first and second liquid reservoir means, the respective separator means and reservoir means being in open fluid flow connection, each of the reservoir means being designed to provide a liquid-free, gas-filled space in an upper portion thereof and to maintain liquid in the lower portion, the first reservoir means being in pressure-tight fluid flow connection with the heat exchanger means and with the respective internal liquid flow passage, each of the first and second reservoir means being in pressure-tight fluid flow connection with the respective first and second gas supply connecting means, and the first and second liquid-gas separator means being in pressure tight fluid flow connection with the respective gas flow conduit means; and

(f) gas repressurization means between each of the gas flow conduit means and the respective liquid-gas separator means, designed to increase the pressure of gas from the internal gas flow conduit means.

2. The closed loop reactant/product management system of claim 1, wherein each of the internal gas and liquid flow passages has an inlet and an outlet with respect to the modular package;

the first liquid-gas separator means and the first liquid reservoir means have a make-up gas inlet, a liquid inlet and a liquid outlet located at a lower portion of the reservoir means (the liquid outlet being in pressure-tight fluid flow connection with the inlet to the internal liquid flow passage), a repressurized gas inlet to the liquid-gas separator means and a gas outlet located at an uppe portion of the reservoir means;

the second liquid-gas separator and liquid reservoir means have a make-up gas inlet located at a lower portion of the reservoir means, an exhaust gas inlet to the liquid-gas separator means and a gas outlet located at an upper portion of the reservoir means;

the indirect heat exchanger means being in fluid flow connection intermediate the upper liquid inlet to the first reservoir means and the liquid outlet from the internal liquid flow passages; and

first and second gas inlet fluid connecting means between the upper gas outlet in each reservoir means and the gas inlets to the modular package.

3. The closed loop reactant/product management system of claim 2 further comprising a central microprocessor linked monitor and control system, the monitor and control system comprising:

first and second gas pressure sensors located adjacent to, and operably connected to, the inlet to the first and second internal gas flow passages, respectively;

first and second gas flow sensors located in fluid flow connection intermediate the first and second gas repressurization means and the first and second reservoir means, respectively;

and liquid flow sensor means located in fluid flow connection intermediate the inlet to the liquid flow passage and the first reservoir;

a central microprocessor linking the sensors and designed to receive data from the sensors and to compare such date with pre-programmed values, and to transmit signals in response to such comparisons; and

(e) fail/safe valves operably connected to the central microprocessor and designed to respond to the signals transmitted by the microprocessor.

4. A closed loop reactant/product management system for electrochemical galvanic energy devices, the system comprising:

fuel cell means comprising first and second internal reactant gas conduit means, and internal coolant liquid conduit means;

first and second reactant gas supply connecting means;

indirect heat exchanger means in fluid flow connection with the internal liquid flow conduit means;

first liquid-gas separator and liquid reservoir means in pressure-tight fluid flow connection with the heat exchanger means and with the internal liquid flow conduit means and with the first internal gas flow conduit means;

second liquid-gas separator and liquid reservoir means in pressure-tight fluid flow connection with the second internal gas flow conduit means and second gas supply connecting means; and

gas repressurization means between each of the internal gas flow conduit means and the liquid-gas separator means, respectively, designed to increase the pressure of gas from the internal gas flow conduit means.

5. The closed loop reactant/product management system according to claim 4, comprising liquid pumping means in fluid flow connection intermediate the first liquid reservoir means and the internal liquid flow conduit means for pumping a liquid product formed within the fuel cell means, by the two reactants, from the first reservoir means to the internal liquid conduit means, and further comprising means to humidify the first reactant gas utilizing the liquid product.

6. The closed loop reactant/product management system according to claim 5, comprising means to humidify the first reactant gas outside of the fuel cell means.

7. The closed loop reactant/product management system according to claim 4, wherein the gas supply connecting means comprises first and second pressure regulating means designed to reduce gas pressure from a high storage pressure to the pressure within the first and second internal gas conduit means.

8. The closed loop reactant/product management system according to claim 4, comprising a liquid diverter valve means, in fluid flow connection between the internal liquid conduit means, the heat exchanger means and the first reservoir means.

9. In a process for galvanically generating electricity comprising:

(a) separately passing an excess of a fuel and an oxidant gas through a stack of fuel cells;

separately withdrawing the excess fuel and the excess oxidant gas from the fuel cell stack, the oxidant gas being removed together with a product liquid; and

passing a coolant liquid past the fuel cells to remove excess heat therefrom;

the improvement comprising;

repressurizing each of the excess fuel and oxidant gases;

admixing the excess fuel and oxidant gases with additional fuel and oxidant gases, respectively;

separating out product liquid from the excess oxygen and admixing the separated product liquid with cooling liquid;

separating out and storing product liquid from the excess hydrogen; and

humidifying the fuel and oxidant gases with the separated product liquid before the gases are passed to the stack of fuel cells.