Continuous production of a photosensitive recording element

• US 5,049,478 A
• Filed: 09/26/1989
• Issued: 09/17/1991
• Est. Priority Date: 10/04/1988
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Telser, Thomas, Kurtz, Karl-Rudolf, Zuerger, Manfred, Koch, Horst
• Primary Examiner(s): Bowers, Jr., Charles L.
• Assistant Examiner(s): Chu, John S. Y.
• Application Number:
  US07/412,995
• Time in Patent Office: 721 Days
• Field of Search: 430/270, 430/271, 430/273, 430/281, 430/909, 430/910, 430/285, 156/324, 156/243, 156/244.27
• US Class Current: 430/270.1
• CPC Class Codes: G03F 7/16 Coating processes; Apparatus therefor applying coatings to base materials in general B05; applying photosensitive compositions to base for photographic purposes G03C1/74
• CPC Class Codes: Y10S 430/11 Vinyl alcohol polymer or derivative
• CPC Class Codes: Y10S 430/111 Polymer of unsaturated acid or ester

Abstract

A novel, improved continuous process for the production of a photosensitive recording element is described, whose photopolymerizable recording layer (A) consists of two or more individual strata (a_n) lying one on top of the other and firmly bonded to one another. The individual strata (a_n) may be of the same or roughly the same composition or of different compositions. In the novel, improved continuous process, the mixtures (a_n) used for the production of the individual strate (a_n) are prepared separately from one another and melted and, as separate molten material streams (a_n), are combined even before entering the nip of a calender, without the said streams mixing as a result of turbulence. During, before or directly after they have been combined, the molten material streams (a_n) are formed into molten sheet-like structures (a_n) lying one on top of the other, without the said streams mixing as a result of turbulence. Thereafter, the molten sheet-like structures (a_n) lying one on top of the other are introduced into the calender nip, one or both of the two outer molten sheet-like structures (a_n) in contact with the calender rollers forming a rotating melt bead or rotating bank. In the calender nip itself, the said sheet-like structures (a_n) are then calendered with production of the photopolymerizable recording layer (A) consisting of individual strata (a_n) lying one on top of the other and firmly bonded to one another.

Claims

1. A continuous process for the production of a photopolymerizable recording layer (A), in which the photopolymerizable recording layer (A) is produced from two or more individual strata (a_n) which lie one on top of the other, are firmly bonded to one another and have the same or roughly the same composition or different compositions, by firmly bonding the said strata in the nip of a calender in one operation, the said continuous process comprising the steps of

(1) separately melting the mixtures (a_n) used for the production of the individual strata (a_n) and combining the resulting, separate material streams (a_n) in the molten state even before they enter the calender nip, without mixing them through turbulence,

(2) shaping the molten material streams (a_n) to give molten sheet-like structures (a_n) lying one on top of the other, before they enter the calender nip, before, during or directly after the said streams have been combined, without mixing them through turbulence,

(3) introducing the molten sheet-like structures (a_n) lying one on top of the other into the calender nip, one or both of the two outer molten sheet-like structures (a_n) in contact with the calender rollers forming a rotating melt bead or rotating bank, and

(4) calendering the molten sheet-like structures (a_n) lying one on top of the other with production of the photopolymerizable recording layer (A) consisting of individual strata (a_n) which lie one on top of the other and are firmly bonded to one another.

2. A process as claimed in claim 1, wherein the time between the combination of the molten material streams (a_n) and entry of the molten sheet-like structures (a_n) lying one on top of the other into the calender nip is from 10 seconds to 5 minutes.

3. A process as claimed in claim 1, wherein, on entering the calender nip, the molten sheet-like structure (a_n) which forms the rotating melt bead or rotating bank has a melt flow index (MFI) which is 1.1 times greater than that of the directly adjacent molten sheet-like structure (a_n).

4. A process as claimed in claim 1, wherein the molten material streams (a_n) are combined in an adapter and are extruded from a slot die downstream of the adapter, as molten sheet-like structures (a_n) lying one on top of the other.

5. A process as claimed in claim 1, wherein the molten material streams (a_n) are combined in a multilayer die and extruded as molten sheet-like structures (a_n) lying one on top of the other.

6. A process as claimed in claim 4, wherein the molten mixtures (a_n) are prepared separately from one another in multiscrew devolatilizing extruders and are transported therein as molten material streams (a_n) to the adapter.

7. A process as claimed in claim 5, wherein the molten mixtures (a_n) are prepared separately from one another in multiscrew devolatilizing extruders and are transported therein as molten material streams (a_n) to the multilayer die.

8. A process as claimed in claim 4, wherein the mixtures (a_n) are prepared in single-screw extruders and are transported therein as molten material streams (a_n) to the adapter.

9. A process as claimed in claim 5, wherein the molten mixtures (a_n) are prepared in single-screw extruders and are transported therein as molten material streams (a_n) to the multilayer die.

10. A process as claimed in claim 1, wherein the molten mixtures (a_n) are prepared separately from one another in mixers and are transported as molten material streams (a_n), by means of single-screw extruders, multiscrew devolatilizing extruders or delivery pumps, to an adapter or to a multilayer die.

11. A process as claimed in claim 1, wherein the molten material streams (a_n) are filtered before being combined.

12. A process as claimed in claim 1, wherein one or more molten material streams (a_n) are themselves polymerizable and form a photopolymerizable individual stratum (a_n) in the course of the process, whereas each further molten material stream (a_n) becomes photopolymerizable only during or after contact with one or more of these photopolymerizable molten material streams (a_n) and thereafter likewise forms a photopolymerizable individual stratum (a_n).

13. A continuous process for the production of a photosensitive recording element having a photopolymerizable recording layer (A) and a temporary base (B), which process comprises preparing the photopolymerizable recording layer (A) by a process as claimed in claim 1, and further wherein the individual strata (a_n) lying one on top of the other are bonded in the calender nip, on a free side, to a temporary base (B), which can readily be peeled off again from the surface of the relevant outer individual stratum (a_n).

14. A continuous process for the production of a photosensitive recording element having a photopolymerizable recording layer (A) and a dimensionally stable base (B), which process comprises preparing the photopolymerizable recording layer (A) by a process as claimed in claim 1, and further wherein the individual strata (a_n) lying one on top of the other are firmly bonded in the calender nip on a free side, to a dimensionally stable base (B).

15. A process as claimed in claim 14, wherein the individual strata (a_n) lying one on the top of the other are bonded in the calender nip, on a free side, via an adhesion-promoting layer, to the dimensionally stable base (B).

16. A continuous process for the production of a photosensitive recording element having a photopolymerizable recording layer (A) and a smooth or matte cover sheet (D), which process comprises preparing the photopolymerizable recording layer (A) by a process as claimed in claim 1, and further wherein the individual strata (a_n) lying one on top of the other are bonded in the calender nip, on a free side, to a smooth or matte cover sheet (D), which can readily be detached again from the surface of the relevant individual stratum (a_n).

17. A process as claimed in claim 16, wherein the individual strata (a_n) lying one on top of the other are bonded in the calender nip, on a free side, via a smooth or matt top layer (C), to a cover sheet (D), which can readily be detached again from the surface of the relevant top layer (C).