Thermoplastic resin composition

• US 5,049,613 A
• Filed: 02/16/1989
• Issued: 09/17/1991
• Est. Priority Date: 02/24/1988
• Status: Expired due to Term

• Current Assignee: Denki Kagaku Kogyo Kabushiki Kaisha (TDK Corporation)
• Original Assignee: Denki Kagaku Kogyo Kabushiki Kaisha (TDK Corporation)
• Inventors: Murakami, Hiroshi, Shimizu, Sachio, Noda, Toshio, Miura, Tetsuji
• Primary Examiner(s): Carrillo, Ana L.
• Application Number:
  US07/310,903
• Time in Patent Office: 943 Days
• Field of Search: 525/179, 525/66
• US Class Current: 525/66
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers

Abstract

A thermoplastic resin composition comprising:

(A) from 10 to 50% by weight of a maleimide copolymer of from 30 to 70 mol % of an aromatic vinyl monomer, from 30 to 50 mol % of a maleimide monomer, from 3 to 20 mol % of an unsaturated dicarboxylic anhydride monomer and from 0 to 50 mol % of other copolymerizable monomer;

(B) from 40 to 80% by weight of a polyamide; and

(C) from 3 to 40% by weight of a polyolefin polymer modified by from 0.1 to 10% by weight of an unsaturated dicarboxylic anhydride monomer and/or an unsaturated carboxylic acid monomer,

wherein said maleimide copolymer is in the form of dispersed particles of from 0.01 to 1.0 μm.

Claims

1. A thermoplastic resin composition comprising:

(A) from 10 to 50% by weight of a maleic copolymer of from 30 to 70 mol % of an aromatic vinyl monomer, from 30 to 50 mol % of a maleimide monomer, from 3 to 20 mol % of an unsaturated dicarboxylic anhydride monomer and from 0 to 50 mol % of other copolymerizable monomer;

(B) from 40 to 80% by weight of a polyamide; and

(C) from 3 to 40% by weight of a polyolefin polymer of an olefin monomer, selected from the group consisting of ethylene, propylene, 1-butene, isobutylene, 2-butene, cyclobutene, 3-methyl-1-butene, 4-methyl-1-butene, 4-methyl-1-pentene, cyclopentene, 1-hexene, cyclohexene, 1-octene, 1-decene and 1-dodecene and mixtures thereof, or a copolymer of said monomer and a non-conjugated diene monomer selected from 4-ethylidenenorbornane and dicyclopentadiene or with an acrylate monomer, modified by from 0.1 to 10% by weight of an unsaturated dicarboxylic anhydride monomer or an unsaturated carboxylic acid monomer and mixtures thereof,

wherein said maleimide copolymer is in the form of dispersed particles of from 0.01 to 1.0 μ

m.

2. The thermoplastic resin composition according to claim 1, wherein the modified polyolefin polymer is in the form of particles having a non-specific shape and is substantially uniformly dispersed.

3. The thermoplastic resin composition according to claim 1, which further contains a metal salt of an organic acid or a fatty acid amide and mixtures thereof.

4. The thermoplastic resin composition according to claim 1, wherein said other copolymerizable monomer is an acrylate monomer.

5. The thermoplastic resin composition according to claim 1, wherein the aromatic vinyl monomer is a member selected from the group consisting of styrene, α

-methylstyrene, vinyl toluene, t-butylstyrene and a mixture thereof;

the maleimide monomer is a member selected from the group consisting of maleimide, N-methyl maleimide, N-ethyl maleimide, N-propyl maleimide, N-hexyl maleimide, N-cyclohexyl maleimide, N-phenyl maleimide, N-tolyl maleimide and a mixture thereof;

the unsaturated dicarboxylic acid anhydride monomer is a member selected from the group consisting of maleic anhydride, methylmaleic anhydride, 1,2-dimethylmaleic anhydride, ethylmaleic anhydride, phenylmaleic anhydride and a mixture thereof; and

said other copolymerizable monomer is a member selected from the group consisting of methyl (meth)acrylate, ethyl (meth)acrylate, butyl (meth)acrylate, hexyl (meth)acrylate, cyclohexyl (meth)acrylate, decyl (meth)acrylate, octadecyl (meth)acrylate, hydroxyethyl (meth)acrylate, methoxyethyl (meth)acrylate, glycidyl (meth}acrylate and a mixture thereof.

6. The thermoplastic resin composition according to claim 1, wherein the polyamide is a member selected from the group consisting of 6-nylon, 6,6-nylon, 6,9-nylon, 6,10-nylon, 6,12-nylon, 4,6-nylon, 11-nylon, 12-nylon, poly(hexamethylene terephthalamide), poly(hexamethylene isophthalamide), poly(m-xylyleneadipamide) and a mixture thereof.

7. The thermoplastic resin composition according to claim 1, wherein the modified polyolefin polymer is a polymer or copolymer of an olefin monomer selected from the group consisting of ethylene, propylene, 1-butene, isobutylene, 2-butene, cyclobutene, 3-methyl-1-butene, 4-methyl-1-butene, 4-methyl-1-pentene, cyclopentene, 1-hexene, cyclohexene, 1-octene, 1-decene, 1-dodecene and a mixture thereof, modified by from 0.1 to 10% by weight of a monomer selected from the group consisting of maleic anhydride, methylmaleic anhydride, 1,2-dimethylmaleic anhydride, ethylmaleic anhydride, phenylmaleic anhydride, acrylic acid, methacrylic acid and a mixture thereof.

8. A molded product prepared from a thermoplastic resin composition as defined in claim 1.