Abrasion-resistant plastic articles

• US 5,051,308 A
• Filed: 01/25/1990
• Issued: 09/24/1991
• Est. Priority Date: 08/24/1987
• Status: Expired due to Term

• Current Assignee: Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Devins, John C., Reed, Clive W., Rzad, Stefan J.
• Primary Examiner(s): Sluby, P. C.
• Application Number:
  US07/469,983
• Time in Patent Office: 607 Days
• Field of Search: 428/412, 428/429, 428/447, 428/420, 428/702, 428/704
• US Class Current: 428/412
• CPC Class Codes: C08J 7/123 Treatment by wave energy or particle radiation C08J7/18 takes precedence
• CPC Class Codes: C23C 16/308 Oxynitrides
• CPC Class Codes: C23C 16/455 characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31536 Including interfacial reaction product of adjacent layers
• CPC Class Codes: Y10T 428/31612 As silicone, silane or siloxane
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

An abrasion-resistant article and method for making is disclosed. The article includes a plastic substrate and a gradational coating applied by plasma-enhanced chemical vapor deposition to the surface thereof.

Claims

1. An article comprising a plastic substrate and a coating disposed thereon, wherein said coating is characterized by a gradual transition from a composition consisting essentially of an interfacial material closest to the surface of the substrate to a composition consisting essentially of an abrasion-resistant material on the outer surface of said coating;

said interfacial material being selected from the group consisting of polymerization products of organosilicon, organometallic, acrylic and olefin materials, and said abrasion-resistant material being selected from the group consisting of silicon dioxide, silicon nitride, silicon oxynitride, silicon carbide, silicon carbonitride, boron oxide, boron nitride, aluminum oxide, aluminum nitride, titanium dioxide, tantalum oxide, iron oxide, germanium oxide, germanium carbide and mixtures thereof.

2. The article of claim 2 wherein the substrate is a polycarbonate material.

3. The article of claim 2 wherein a primer is disposed between the polycarbonate and the interfacial material.

4. The article of claim 2 wherein the interfacial material is a polymerization product of an olefinic monomer.

5. The article of claim 2 wherein the interfacial material is a polymerization product of an acrylic monomer.

6. The article of claim 2 wherein the interfacial material is a polymerization product of an organosilicon material.

7. The article of claim 6 wherein the organosilicon material is selected from the group consisting of hexamethyldisilazane, hexamethyldisiloxane, vinyl trimethylsilane and octamethylcyclotetrasiloxane.

8. The article of claim 2 wherein the abrasion-resistant material is selected from the group consisting of silicon carbide, silicon dioxide, silicon nitride, silicon oxynitride and mixtures thereof.

9. The article of claim 8 wherein the abrasion-resistant material is silicon dioxide.