Coextrudable adhesives and products therefrom

• US 5,053,457 A
• Filed: 06/13/1989
• Issued: 10/01/1991
• Est. Priority Date: 06/13/1989
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Lee, I-Hwa
• Primary Examiner(s): Bleutge, John C.
• Assistant Examiner(s): Aylward, D. E.
• Application Number:
  US07/365,593
• Time in Patent Office: 840 Days
• Field of Search: 525/78
• US Class Current: 525/78
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C09J 123/08 Copolymers of ethene C09J123/16 takes precedence
• CPC Class Codes: C09J 151/06 grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers

Abstract

A coextrudable adhesive composition comprises a blend of (a) a copolymer of ethylene with alkyl acrylate or methacrylate comonomer and a grafted comonomer containing pendant carboxylic acid or carboxylic acid derivative functionality, and (b) a copolymer of ethylene with at least one comonomer selected from the group consisting of alpha olefins, nonconjugated dienes, vinyl esters of carboxylic acids, styrene, alkyl acrylates, and alkyl methacrylates, wherein component (b) is incompatible with component (a).

Claims

1. A coextrudable adhesive composition consisting essentially of:

(a) about 60 to about 95 percent of a blend of;

(i) about 1 to 100 percent by weight of a copolymer of ethylene with about 5 to about 40 weight percent of at least one copolymerized alkyl acrylate or methacrylate comonomer and a grafted comonomer containing pendant carboxylic acid or carboxylic acid anhydride functionality, wherein the amount of said grafted comonomer comprises about 0.03 to about 2.0 percent by weight of the total adhesive composition, and

(ii) 0 about 99 percent by weight of a copolymer of ethylene with about 5 to about 40 weight percent of at least one alkyl acrylate or methacrylate comonomer, wherein the copolymer of (i) and the copolymer of (ii) are mutually compatible; and

(b) about 5 to about 40 weight percent of a copolymer of about 40 to about 95 percent by weight ethylene with at least one comonomer selected from the group consisting of alpha olefins, nonconjugated dienes in an amount of 0 to about 10 weight percent, vinyl esters of carboxylic acids, styrene, alkyl acrylates, and alkyl methacrylates, wherein component (b) is incompatible with component (a).

2. The coextrudable adhesive composition of claim 1 wherein the amount of grafted comonomer in component (a)(i) comprises about 0.03 to about 0.4 percent by weight of the total adhesive composition.

3. The coextrudable adhesive composition of claim 1 wherein the amount of grafted comonomer in component (a)(i) comprises about 0.05 to about 0.3 percent by weight of the total adhesive composition.

4. The coextrudable adhesive composition of claim 1 wherein the copolymer of (a)(i) and the copolymer of (a)(ii) contain at least one said copolymerized comonomer in common, the amount of each such common comonomer in the copolymer of (ii) being within about 10% of the amount of the corresponding comonomer in copolymer (i), and the total amount of said copolymerized comonomers other than such common comonomers in either copolymer being less than about 10%.

5. The composition of claim 4 wherein each comonomer in the copolymer of (a)(ii) is within about 5 % of the amount of the corresponding comonomer in the copolymer of (a)(i).

6. The composition of claim 5 wherein the copolymer of (a)(i) and the copolymer of (a)(ii) consist of the same copolymerized comonomers.

7. The adhesive composition of claim 6 wherein the copolymer of (a)(i) is a binary copolymer of ethylene and about 15 to about 30 weight percent copolymerized methyl acrylate.

8. The coextrudable adhesive composition of claim 4 wherein component (b) is a copolymer of ethylene and at least one alkyl acrylate or methacrylate comonomer wherein such copolymer differs from the copolymers of (a) in the identity of said comonomers.

9. The coextrudable adhesive composition of claim 4 wherein component (b) is a copolymer of ethylene and at least one alkyl acrylate or methacrylate comonomer wherein such copolymer differs from the copolymers of (a) in further comprising a comonomer selected from the group consisting of acrylic acid, methacrylic acid, a monoalkyl ester of an unsaturated dicarboxylic acid, glycidyl acrylate, and glycidyl methacrylate.

10. The adhesive composition of claim 1 wherein component (b) is a copolymer of ethylene with about 10 to about 40 weight percent of an alpha olefin of 3 to 20 carbon atoms and 0 to about 10 weight percent of a non-conjugated diene.

11. The adhesive composition of claim 10 wherein component (b) is a copolymer of ethylene with about 20 to about 30 weight percent propylene and about 2 to about 8 weight percent 1-4-hexadiene.

12. The adhesive composition of claim 7 wherein component (b) is a copolymer of ethylene with about 10 to about 40 weight percent of an alpha olefin of 3 to 20 carbon atoms and 0 to about 10 weight percent of a non-conjugated diene.

13. The adhesive composition of claim 12 wherein component (b) is a copolymer of ethylene with about 20 to about 30 weight percent propylene and about 2 to about 8 weight percent 1-4-hexadiene.

14. The adhesive composition of claim 13 wherein the copolymer of ethylene, propylene, and diene is grafted with a comonomer containing pendant anhydride functionality.

15. The adhesive composition of claim 11 wherein the amount of grafted comonomer in the composition is about 0.03 to about 0.4 weight percent.

16. The adhesive composition of claim 11 wherein the amount of grafted comonomer in the composition is about 0.05 to about 0.3 weight percent.

17. The adhesive composition of claim 1 wherein the amount of component (a) is about 65 to about 85 percent and the amount of component (b) is about 15 to about 35 weight percent.

18. The adhesive composition of claim 1 wherein the amount of the grafted copolymer of (a)(i) comprises about 5 to about 20 weight percent of the blend of (a).

19. The composition of claim 1 wherein the carboxylic acid or carboxylic acid derivative is acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, crotonic acid, itaconic anhydride, maleic anhydride, dimethyl maleic anhydride monosodium maleate, maleic anhydride and maleic acid.

20. The composition of claim 1 wherein the carboxylic acid or carboxylic acid derivative is an anhydride.

21. The composition of claim 20 wherein the anhydride is maleic anhydride.

22. The composition of claim 1 wherein the amount of the grafted copolymer of (a)(i) comprises about 1 to about 31 weight percent and the amount of the ungrafted copolymer of (a)(ii) comprises about 69 to about 99 weight percent of the blend of (a).