Process for recovery of cellulose

• US 5,057,334 A
• Filed: 03/11/1991
• Issued: 10/15/1991
• Est. Priority Date: 07/13/1990
• Status: Expired due to Term

• Current Assignee: Fibred-Maryland, Inc.
• Original Assignee: Ort's Incorporated
• Inventors: Vail, William J.
• Primary Examiner(s): Cintins, Marianne
• Assistant Examiner(s): HEGGESTAD, HELEN F
• Application Number:
  US07/667,533
• Time in Patent Office: 218 Days
• Field of Search: 426/634, 426/436, 426/431, 426/478
• US Class Current: 426/634
• CPC Class Codes: A23L 29/262 Cellulose; Derivatives thereof, e.g. ethers
• CPC Class Codes: D21C 5/00 Other processes for obtaining cellulose, e.g. cooking cotton linters obtaining fibres for spinning D01C; Processes characterised by the choice of cellulose-containing starting materials
• CPC Class Codes: D21C 9/163 with peroxides

Abstract

The present invention is directed to a process for the production of an improved purified short fiber cellulose suitable for human consumption from agricultural by-product materials, such as legume hulls, preferably soybean hulls. The legume hulls are comminuted into a particulate feed which is admixed with water to form a slurry. The slurried particulate legume hulls are oxidized, hydrolyzed and extracted with a caustic oxidizing agent utilizing an initial pH of about 12 to effect solubilization of the greater portion of non-cellulose material in the feed. A solid cellulose containing material is thereafter removed from the slurry, for example, by filtration or centrifugation. The recovered solid mass is slurried in water and the resulting slurry if pH adjusted to about 7 by the addition of phosphoric acid. The resulting suspension is agitated and H₂ O₂ is added, and the mixture is heated to promote bleaching and breakdown of the non-cellulose components. The resulting mixture is subjected to a separation operation and a residue is recovered which consists primarily of microcrystalline alpha-cellulose fibers.

Claims

1. A process for the production of purified short fiber cellulose suitable for human consumption, from the hulls of edible legumes, comprising the steps of:

(a) forming a slurry of particulate legume hulls in water,

(b) adding caustic oxidizing agent to the slurry to raise the pH to about 12,

(c) maintaining a highly alkaline pH in said slurry for 61/2 to 23 hours during which the temperature of the slurry is maintained at 190°

F. to 210°

F. for at least 30 minutes, to oxidize, hydrolyze and extract the particulate legume hulls, thereby to solubilize the greater portion of the non-cellulose material present therein and form a pulp which consists predominantly of cellulose, in the slurry,

(d) separating the pulp from the slurry,

(e) redispersing the separated pulp in water to form a further slurry,

(f) adjusting the pH of the further slurry to be in the range of from about 6.5 to 7.5 by the addition of phosphoric acid,

(g) adding to the pH adjusted slurry resulting from (f) a bleaching effective amount of aqueous hydrogen peroxide solution, and mixing, and heating the resulting admixture to a below boiling temperature to promote breakdown of any non-cellulose material present and bleaching of the pulp, and

(h) separating from the resulting admixture a bleached pulp composition consisting predominantly of short fiber cellulose.

2. The process as in claim 1 in which the caustic oxidizing agent is selected from the group consisting of sodium hydroxide, potassium hydroxide and sodium carbonate.

3. The process as in claim 1 in which the pH of the further slurry is adjusted to a pH of 7.to 7.2 by the addition of phosphoric acid.

4. The process of claim wherein in step (g) said temperature ranges from 190°

F. to 210°

F.

5. The process of claim 4 wherein in step (g), said temperature ranges from 206°

F. to 210°

F.

6. The process of claim wherein in step (c), the temperature of the slurry is maintained at 200°

F. to 210°

F. for at least 30 minutes.

7. The process of claim 6 wherein in step (c), the temperature of the slurry is maintained at 200°

F. to 210°

F. for 8 to 12 hours.

8. The process of claim 7 wherein in step (g), said temperature ranges from 206°

F. to 210°

F.