Catalyst composition for oxidation of ethylene to ethylene oxide

• US 5,057,481 A
• Filed: 10/03/1988
• Issued: 10/15/1991
• Est. Priority Date: 02/20/1987
• Status: Expired due to Term

• Current Assignee: Dow Technology Investments LLC (Dow, Inc.)
• Original Assignee: Union Carbide Chemicals & Plastics Technology Corporation (Dow, Inc.)
• Inventors: Bhasin, Madan M.
• Primary Examiner(s): SHINE, WILLIAM
• Application Number:
  US07/251,814
• Time in Patent Office: 1,107 Days
• Field of Search: 502/208, 502/218, 502/317, 502/324, 502/347, 502/348, 502/224, 549/536
• US Class Current: 502/208
• CPC Class Codes: B01J 23/66 Silver or gold
• CPC Class Codes: C07D 301/10 with catalysts containing silver or gold

Abstract

This invention relates to the catalysts for the manufacture of ethylene oxide at commercial concentrations in the presence of carbon dioxide gas recycle which contains impregnated silver on a support and a mixture of cesium salts, at least one of which is a cesium salt in which the anions thereof are oxyanions of elements having an atomic number of 21 to 75 and being from groups 3b through 7b, inclusive, of the Periodic Table of the Elements.

Claims

1. A catalyst for the manufacture of ethylene oxide by the epoxidation of ethylene containing an impregnated silver metal on an inert, refractory solid support and an efficiency-enhancing amount, relative to the amount of silver metal of a mixture of cesium salts, at least one of which is a cesium salt in which the anion thereof is an oxyanion of an element having an atomic number of 21 to 75 and being from groups 3b through 7b, inclusive, of the Periodic Table of the Elements.

2. The catalyst of claim 1 in which at least one cesium salt is selected from the group of the manganates, tungstates, molybdates, vanadates, tantalates, titanates, zirconates and chromates.

3. The catalyst of claim 1 in which at least one cesium salt is a halide having an atomic number of 9 to 53 or an oxyanion of an element other than the oxygen therein having an atomic number of (i) 7 or (ii) 15 to 83 and being from groups 3a to 7a of the Periodic Table of the Elements.

4. The catalyst of claim 3 in which at least one cesium salt is cesium sulfate.

5. The catalyst of claim 3, in which at least one cesium salt is selected from the group of the manganates, tungstates, molybdates, vanadates, tantalates, titanates, zirconates and chromates.

6. The catalyst of claim 3 in which at least two cesium salts are oxyanions of elements having an atomic number of 15 to 83 and being from groups 3b to 7b, inclusive, and 3a to 7a, inclusive, of the Periodic Table of the Elements.

7. The catalyst of claim 1 in which at least two cesium salts are oxyanions of elements having an atomic number of 15 to 83 and being from groups 3b to 7b, inclusive, and 3a to 7a, inclusive, of the Periodic Table of the Elements.

8. The catalyst of claim 1 in which the cesium salts comprise said oxyanions and halides.

9. The catalyst of claim 1 in which the support is alpha-alumina.

10. The catalyst of claim 9 in which at least two cesium salts are oxyanions of elements having an atomic number of 15 to 83 and being from groups 3b to 7b, inclusive, and 3a to 7a, inclusive, of the Periodic Table of the Elements.

11. The catalyst of claim 9 in which at least one cesium salt is selected from the group of the manganates, tungstates, molybdates, vanadates, tantalates, titanates, zirconates and chromates.

12. The catalyst of claim 11 in which cesium salt comprises at least one of halide, sulfate and phosphate.

13. The catalyst of claim 12 in which the cesium salts having oxyanions of elements having atomic numbers of 21 to 75 and being from groups 3b to 7b of the Periodic Table of the Elements comprise at least about 30 mole percent of the total cesium salts.

14. The catalyst of claim 9 in which the cesium salts having oxyanions of elements having atomic numbers of 21 to 75 and being from groups 3b to 7b of the Periodic Table of the Elements comprise at least about 30 mole percent of the total cesium salts.

15. The catalyst of claim 14 which comprises cesium sulfate.

16. The catalyst of claim 9 in which at least one cesium salt comprises a manganate.

17. The catalyst of claim 9 in which at least one cesium salt comprises a tungstate.

18. The catalyst of claim 9 in which at least one cesium salt comprises a molybdate.

19. The catalyst of claim 9 in which at least one cesium salt comprises a vanadate.

20. The catalyst of claim 9 in which at least one cesium salt comprises a titanate.

21. The catalyst of claim 9 in which at least one cesium salt comprises a zirconate.

22. The catalyst of claim 9 in which at least one cesium salt comprises a chromate.

23. The catalyst of claim 9 in which at least one cesium salt comprises a cerate.

24. The catalyst of claim 9 in which at least one cesium salt comprises a tantalate.

25. The catalyst of claim 9, wherein said catalyst has been subjected to a process for making ethylene oxide by the reaction of ethylene and oxygen.

26. The catalyst of claim 25, wherein the process to which the catalyst was subjected involves the use of a gas phase inhibitor.

27. The catalyst of claim 26 in which the gas phase inhibitor is an organic chloride.

28. The catalyst of claim 1, wherein said catalyst has been subjected to a process for making ethylene oxide by the reaction of ethylene and oxygen.

29. The catalyst of claim 28, wherein the process to which the catalyst was subjected involves the use of a gas phase inhibitor.

30. The catalyst of claim 29 in which the gas phase inhibitor is an organic chloride.