Microwave spectrometer

• US 5,057,782 A
• Filed: 08/16/1990
• Issued: 10/15/1991
• Est. Priority Date: 02/26/1988
• Status: Expired due to Fees

• Current Assignee: Monash University
• Original Assignee: Monash University
• Inventors: Brown, Ronald D., Crofts, Jonathan G., Godfrey, Peter D.
• Primary Examiner(s): Williams, Hezron E.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US07/555,391
• Time in Patent Office: 425 Days
• Field of Search: 324/636, 324/639, 73/23.2, 73/23.41, 73/23.42
• US Class Current: 324/639
• CPC Class Codes: G01N 22/00 Investigating or analysing materials by the use of microwaves or radio waves, i.e. electromagnetic waves with a wavelength of one millimetre or more G01N3/00 - G01N17/00, G01N24/00 take precedence

Abstract

A spectrometer for analyzing a sample substance which comprises a chamber (40) for supporting a sample to be analyzed. A gas drive circuit (42) communicates with the chamber (40) and the gas drive circuit (42) and chamber (40) are at least partly enclosed within a heated jacket (44). The gas flow through the gas circuit and chamber (40) entrains sample molecules in the flow and a nozzle (30) is provided to spray the gas flow and entrained molecules as a supersonic beam seeded with the molecules between a pair of plates (32 and 34) between which an electric field is created. The electrodes (32 and 34) comprise Stark electrodes. A microwave source (50) and a receiver (60) are arranged so that the source (50) produces a microwave beam which passes through the supersonic beam as the beam expands between the electrodes 32 and 34 which is detected by the detector 60. The detector 60 detects an absorption signal of the molecules which seed the supersonic beam.

Claims

1. A spectrometer for analyzing a sample substance, said spectrometer including:

(a) means for supporting the sample substance,

(b) means for providing a flow of gas through or over said substance such that molecules of said substance are entrained in said gas flow,

(c) nozzle means for receiving said gas flow entraining said molecules of the substance and for ejecting said flow of gas as a supersonic beam seeded with said molecules,

(d) means for creating an electric field in the vicinity of said beam which is ejected by said nozzle means,

(e) means for providing a source of electromagnetic radiation which passes through said beam in the vicinity of said electric field, and

(f) means for detecting said electromagnetic radiation to thereby detect an absorption signal of the molecules which has been modulated in frequency by said electric field.

2. The spectrometer of claim 1 wherein said means for creating an electric field comprises a pair of electrodes between which the beam and said electromagnetic radiation pass.

3. The spectrometer of claim 2 wherein the electrodes are supported in a vacuum cavity and pump means is provided to create a vacuum in said cavity.

4. The spectrometer of claim 1 wherein a cold trap is provided in said cavity to facilitate trapping of gas molecules in the gas flow to thereby facilitate maintenance of the vacuum in the cavity.

5. The spectrometer of claim 1 wherein the means for supplying a gas flow together with the sample is heated by a heating means to cause some vaporization of the substance so that it can be more easily entrained in the gas flow and wherein the gas flow is maintained at a predetermined temperature by the heating means to maintain the substance in the vapour state while not allowing deterioration of the substance.