Fluorosilicone rubber composition

• US 5,059,668 A
• Filed: 09/10/1990
• Issued: 10/22/1991
• Est. Priority Date: 01/20/1986
• Status: Expired due to Term

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Fukuda, Takeshi, Fukushima, Motoo
• Primary Examiner(s): Marquis, Melvyn I.
• Assistant Examiner(s): Glass, M.
• Application Number:
  US07/580,199
• Time in Patent Office: 407 Days
• Field of Search: 528/15, 528/31, 528/32, 528/42
• US Class Current: 528/15
• CPC Class Codes: C08G 77/24 halogen-containing groups
• CPC Class Codes: C08K 5/14 Peroxides
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/08 containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen

Abstract

The fluorine-substituted organopolysiloxane as the principal ingredient of the inventive silicone rubber composition has vinyl groups to serve as the crosslinking points at the molecular chain terminals while at least the penultimate siloxane unit or the silicon atom adjacent to the terminal silicon atom has no fluorine-substituted hydrocarbon group bonded to the silicon atom. Being freed from the steric hindrance due to the bulky fluorine-substituted hydrocarbon group bonded to the adjacent silicon atom, the vinyl group bonded to the terminal silicon atom can pertain to the crosslinking reaction much easier than otherwise so that the silicone rubber composition of the invention containing an organic peroxide or a combination of an organohydrogenpolysiloxane and a platinum catalyst as a curing agent can be rapidly cured to give a cured silicone rubber article having excellent resistance against oils and organic solvents as well as mechanical properties.

Claims

1. A curable fluorine-substituted organopolysiloxane composition which comprises, in admixture

(A) a polyorganosiloxane having a viscosity of at least 400 centipoise at 25°

C. and a molecular structure represented by the general formula;

space="preserve" listing-type="equation">X.sup.1 --O--(--SiR.sub.2 --O--)n--(--SiRR.sub.f --O--).sub.m --X.sup.2,

space="preserve" listing-type="equation">or

space="preserve" listing-type="equation">[X.sup.1 --O--(--SiR.sub.2 --O--).sub.n --(--SiRR.sub.f --O--).sub.m --].sub.p SiR.sub.4.sbsb.-p'"'"'

in which R is a monovalent hydrocarbon group selected from the class consisting of methyl, vinyl and phenyl groups, R_f is a fluorinated alkyl group having 3 to 10 carbon atoms, n is zero or a positive integer, m is a positive integer with the proviso that m;

(m+n) is in the range from 0.005 to 1, p is 2, 3 or 4, X¹ is a vinyl dimethyl siloxy-substituted silyl group represented by the general formula;

space="preserve" listing-type="equation">Vi--SiMe.sub.2 --(--O--SiMe.sub.2 --).sub.r--

in which Vi is a vinyl group, Me is a methyl group and r is a positive integer in the range from 1 to 30, and X² is a hydrogen atom or X¹ ; and

(B) a curing agent which is a combination of an organohydrogenpolysiloxane having at least three hydrogen atoms directly bonded to the silicon atoms in a molecule and a platinum catalyst.

2. The curable fluorine-substituted organopolysiloxane composition as claimed in claim 1 wherein the amount of the organohydrogenpolysiloxane is sufficient to provide from 0.5 to 4.0 moles of the silicon-bonded hydrogen atoms per mole of the vinyl groups in the component (A).

3. The curable fluorine-substituted organopolysiloxane composition as claimed in claim 1 wherein the amount of the platinum catalyst is in the range from 0.1 to 200 ppm by weight as platinum based on the component (A).