Manufacturing process of spray urethane elastomer

• US 5,059,671 A
• Filed: 12/21/1989
• Issued: 10/22/1991
• Est. Priority Date: 12/28/1988
• Status: Expired due to Fees

• Current Assignee: Mitsui Chemicals Incorporated (Mitsui Chemicals)
• Original Assignee: Mitsui Chemicals Incorporated (Mitsui Chemicals)
• Inventors: Ogura, Tetsuyoshi, Taniguchi, Kazuo, Imaoka, Kazuhiro, Sakaguchi, Hiroaki
• Primary Examiner(s): Foelak, Morton
• Assistant Examiner(s): TRUONG, DUC
• Application Number:
  US07/454,274
• Time in Patent Office: 670 Days
• Field of Search: 528/64, 528/61, 528/55, 528/48, 528/59, 528/49, 528/50, 528/75, 521/137, 521/99, 521/107
• US Class Current: 528/49
• CPC Class Codes: C08G 18/10 Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• CPC Class Codes: C08G 18/227 of antimony, bismuth or arsenic
• CPC Class Codes: C08G 18/4854 Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
• CPC Class Codes: C08G 18/6685 with compounds of group C08G18/3225 or polyamines of C08G18/38
• CPC Class Codes: C08G 2150/50 Compositions for coatings applied by spraying at least two streams of reaction components

Abstract

This invention relates to a process for manufacturing a spray urethane elastomer. More particularly it relates to a process for manufacturing a solventless, non-cellular spray urethane elastomer, which comprises spraying a partial prepolymer component having a high molar ratio of NCO/OH prepared from an organic polyisocyanate and from polytetramethylene ether glycol (PTMEG) having a molecular weight of 400 to 2000 and a resin component containing the PTMEG, a specified chain extender and an organobismuth compound catalyst onto a substrate by use of a two components high pressure spray machine.

According to the present invention, spraying only of the stock solutions by use of the two components high pressure spray machine accomplishes coating and the stock solutions are cured in one second to ten and several seconds after being sprayed without producing cells even when thick-coated. Therefore, the present invention makes it possible to effect wet-on-wet coating within a short period of time, resulting in making it possible to accomplish a coating having a predetermined thickness in a short period of time.

An elastomer, which has been coated, is excellent at modulus, tensile strength, elongation, tear strength, heat resistance, and the like, such as pipe, tank and the like, waterproof materials such as concrete for the roof and outside wall which need waterproofness, thick-coated protective coating for a thermal insulant such as rigid polyurethane foam, polystyrene foam, board or the like, seamless floor covering material, open mold molding by use of a mold made of metal or resin, and the like.

Claims

1. A process for manufacturing a solventless spray urethane elastomer which comprises spraying components (a) and (b) directly onto a substrate, using a two component high pressure spray machine equiped with a colliding and mixing type spray gun;

components (a) and (b) comprising;

(a) a partial prepolymer component prepared by reacting an organic polyisocyanate and a polytetramethylene ether glycol having a molecular weight of 400 to 2,000 at a NCO/OH molar ratio of 5 to 40; and

(b) a resin component prepared by mixing (i) a polytetramethylene ether glycol, having a molecular weight of 400 to about 2000, (II) an active aromatic polyamine chain extender free of electron attractive groups on the aromatic nucleus, and (III) an organobismuth catalyst.

2. A process according to claim 1, wherein said polyisocyanate is a purified or crude diphenylmethane diisocyanate, or modified diphenylmethane diisocyanate.

3. A process according to claim 1, wherein said chain extender is a sterically hindered aromatic polyamine substituted by at least one alkyl group having from 1 to 5 carbon atoms.

4. A process according to claim 1, wherein said organobismuth compound is bismuth trineodecanoate.

5. A process according to claim 1, wherein a low molecular weight glycol is mixed therewith in the reaction for the preparation of the partial prepolymer.