Treatment of ferromagnetic metal powders and magnetic recording media using the same

• US 5,062,904 A
• Filed: 10/02/1990
• Issued: 11/05/1991
• Est. Priority Date: 10/03/1989
• Status: Expired due to Term

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Yoden, Kenichi
• Primary Examiner(s): Sheehan, John P.
• Application Number:
  US07/592,453
• Time in Patent Office: 399 Days
• Field of Search: 148/105, 148/286, 148/287, 219/121.59
• US Class Current: 148/105
• CPC Class Codes: G11B 5/712 characterised by the surface treatment or coating of magnetic particles
• CPC Class Codes: H01F 1/061 with a protective layer
• CPC Class Codes: H01F 1/065 obtained by a reduction

Abstract

Disclosed are (1) methods for treating ferromagnetic metal powders which comprise synthesizing the ferromagnetic metal powders, and then exposing the ferromagnetic metal powders to plasma in an oxygen atmosphere, and (2) magnetic recording media comprising non-magnetic supports and magnetic layers formed thereon, the magnetic layers being mainly composed of ferromagnetic metal powders and binder resins, in which the ferromagnetic metal powders are treated by the methods described in (1). The ferromagnetic metal powders obtained by the above methods are excellent in oxidation stability, and the magnetic recording media using the above ferromagnetic metal powders are excellent in storage stability.

Claims

1. A method for treating a ferromagnetic metal powder which comprises forming ferromagnetic metal powder, and then exposing said ferromagnetic metal powder to a low temperature plasma in an oxygen atmosphere.

2. A method as in claim 1, wherein said ferromagnetic metal powder is formed by reducing a metal oxide in a reducing gas or by reducing a metal salt in a reducing solution.

3. A method as in claim 1, which comprises forming ferromagnetic metal powder, gradually oxidizing a surface of the ferromagnetic metal powder, and then exposing said ferromagnetic metal powder to a low temperature plasma in an oxygen atmosphere.

4. A method as in claim 3, wherein said ferromagnetic metal powder was obtained by reducing a metal oxide in a reducing gas or by reducing a metal salt in a reducing solution.

5. A method as in claim 1, wherein plasma exposure of the ferromagnetic metal powder is performed by placing the ferromagnetic metal powder in a reaction chamber, evacuating the reaction chamber with a rotary pump to a required degree of vacuum, then supplying an oxygen-containing gas onto surfaces of particles of the ferromagnetic metal powder, then adjusting the degree of vacuum in said reaction chamber to about 0.1 to 5 Torr, and applying a high frequency of about 10 to 50 MHz by application of 10 to 100 watts of electric power to generate plasma.

6. A method as in claim 5, wherein said oxygen-containing gas is supplied to the reaction chamber at a flow rate of about 1 to 30 cc/minute per g of the ferromagnetic metal powder.

7. A method as in claim 1, wherein said ferromagnetic metal powder has a specific surface area of at least 35 m² /g and a crystallite size of 150 to 250 Å

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