Processing liquid for use in DTR-photography with two toners

• US 5,063,136 A
• Filed: 05/17/1990
• Issued: 11/05/1991
• Est. Priority Date: 05/18/1989
• Status: Expired due to Fees

• Current Assignee: Agfa-Gevaert N.V.
• Original Assignee: Agfa-Gevaert N.V.
• Inventors: De Keyzer, Rene M., Odeurs, Raymond L., De brabandere, Luc A.
• Primary Examiner(s): Schilling, Richard L.
• Application Number:
  US07/524,382
• Time in Patent Office: 537 Days
• Field of Search: 430/233, 430/249, 430/248, 430/251, 430/449, 430/455, 430/456, 430/486, 430/487, 430/490, 430/965, 430/492
• US Class Current: 430/248
• CPC Class Codes: G03C 8/06 Silver salt diffusion transfer
• CPC Class Codes: G03C 8/243 Toners for the silver image
• CPC Class Codes: G03C 8/365 containing silver-halide solvents
• CPC Class Codes: Y10S 430/166 Toner containing

Abstract

An aqueous alkaline processing liquid suitable for use in the silver complex diffusion transfer (DTR-) process, wherein said liquid contains one or more alkanolamines, the said alkanolamine(s) consisting of one or more tertiary alkanolamines in an amount in the range from 0.15 mol to 1.5 mol/l, and one or more secondary alkanolamines in an amount higher than 5 mol % but not higher than 100 mol % with respect to the amount of tertiary alkanolamine(s), and said liquid also contains a mixture of a silver image toning agent A being 1-phenyl-1H-tetrazole-5-thiol or a tautomer thereof and at least one other silver image toning agent B being a 1-phenyl-1H-tetrazole-5-thiol or a tautomer thereof, wherein the phenyl nucleus is substituted with halogen, the toning agent A and toning agent(s) B being present in said liquid in a molar ratio from 1/15 to 15/1.

Claims

1. An aqueous alkaline processing liquid suitable for use in the silver complex diffusion transfer reversal (DTR-) process, wherein said liquid contains alkanolamines, the said alkanolamine(s) consisting of one or more tertiary alkanolamines in a total amount in the range from 0.15 mol to 1.5 mol/l, and one or more secondary alkanolamines in an amount higher than 5 mol % but not higher than 100 mol % with respect to the amount of tertiary alkanolamine(s), and said liquid also contains a mixture of a silver image toning agent A being 1-phenyl-1H-tetrazole-5-thiol or a tautomer thereof and at least one other silver image toning agent B being a 1-phenyl-1H-tetrazole-5-thiol or a tautomer thereof, wherein the phenyl nucleus is substituted with halogen, the toning agent A and toning agent(s) B being present in said liquid in a molar ratio from 1/15 to 15/1.

2. An aqueous alkaline processing liquid according to claim 1, wherein the concentration of the combination of said toning agents A and B in said liquid is between 30 mg and 300 mg/l.

3. An aqueous alkaline processing liquid according to claim 1, wherein said toning agent B is 1-(2,4-dichloro-phenyl)-1H-tetrazole-5-thiol or 1-(3,4-dichloro-phenyl)-1H-tetrazole-5-thiol.

4. An aqueous alkaline processing liquid according to claim 1, wherein the pKa value of said alkanolamine(s) is at least 8.5.

5. An aqueous alkaline processing liquid according to claim 1, wherein the pKa value of said tertiary alkanolamine(s) is at least 9.

6. An aqueous alkaline processing liquid according to claim 1, wherein said liquid contains an amount of inorganic alkaline substance(s) other than an alkali metal sulphite in an amount of at most 0.2 mol/l.

7. An aqueous alkaline processing liquid according to claim 1, wherein said liquid contains dissolved sulphite ions in a concentration in the range of 16 g to 76 g/l.

8. An aqueous alkaline processing liquid according to claim 1, wherein said liquid contains dissolved thiosulphate ions in a concentration in the range of 0.03 mol to 0.13 mol/l.

9. An aqueous alkaline processing liquid according to claim 1, wherein said tertiary alkanolamines are selected from the group consisting of DMEA, DEEA, MDEA and EDEA.

10. An aqueous alkaline processing liquid according to claim 1, wherein said secondary alkanolamines are selected from the group consisting of MMEA, MEEA, DEA and DIPA.

11. A silver complex diffusion transfer reversal (DTR-) process which is carried out by development of an information-wise exposed silver halide emulsion layer with a developing agent in the presence of a silver halide solvent to form diffusible silver complexes which diffuse into an image-receiving layer containing development nuclei, and in which said information-wise exposed photographic silver halide emulsion layer is moistened with an aqueous alkaline processing liquid, wherein said liquid contains one or more alkanolamines, the said alkanolamine(s) consisting of one or more tertiary alkanolamines in a total amount in the range from 0.15 mol to 1.5 mol/l, and one or more secondary alkanolamines in an amount higher than 5 mol % but not higher than 100 mol % with respect to the amount of tertiary alkanolamine(s), and said liquid also contains a mixture of a silver image toning agent A being 1-phenyl-1H-tetrazole-5-thiol or a tautomer thereof and at least one other silver image toning agent B being a 1-phenyl-1H-tetrazole-5-thiol or a tautomer thereof, wherein the phenyl nucleus is substituted with halogen, the toning agent A and toning agent(s) B being present in said liquid in a molar ratio from 1/15 to 15/1.

12. A silver complex diffusion transfer reversal process according to claim 11, wherein the moistening of said silver halide emulsion layer with said processing liquid proceeds while or before said layer is in relationship with an image-receiving layer to allow therein the transfer of complexed silver ions.

13. A silver complex diffusion transfer reversal process according to claim 12, wherein said image-receiving layer and/or a hydrophilic colloid layer in waterpermeable relationship therewith and/or a back layer at the side of the support opposite to that carrying the image receiving layer contains at least a part of said silver image toning agents.

14. A silver complex diffusion transfer process according to claim 13, wherein the coverage of said silver image toning agents in said layer(s) is in the range from 1 mg to 20 mg/m².

15. A silver complex diffusion transfer process according to claim 11, wherein at least a part of said silver image toning agents is present in the silver halide emulsion material in an anti-halation layer at the side of the support opposite to the side coated with a silver halide emulsion layer or between the support and the silver halide emulsion layer.

16. A silver complex diffusion transfer process according to claim 15, wherein the coverage of said silver image toning agents in said antihalation layer is in the range from 1 mg to 20 mg/m².

17. A silver complex diffusion transfer process according to claim 11 wherein said image receiving material contains a water-impermeable support coated with (1) an image receiving layer containing physical development nuclei dispersed in a waterpermeable binder and (2) a waterpermeable top layer free from development nuclei and containing a hydrophilic colloid, in such a way that

(i) the total solids coverage of said two layers (1) and (2) is at most 2 g/m2,

(ii) in layer (1) the coverage of the nuclei is in the range of 0.1 mg/m2 to 10 mg/m2, and the coverage of binder is in the range of 0.4 to 1.5 g/m2, and

(iii) in said top layer (2) the coverage of hydrophilic colloid is in the range of 0.1 to 0.9 g/m2.