Measuring gas levels

• US 5,064,516 A
• Filed: 06/27/1988
• Issued: 11/12/1991
• Est. Priority Date: 07/16/1987
• Status: Expired due to Fees

• Current Assignee: Gas Research Institute (GTI Energy)
• Original Assignee: Gas Research Institute (GTI Energy)
• Inventors: Rupich, Martin W.
• Primary Examiner(s): TUNG, TA HSUNG
• Application Number:
  US07/211,576
• Time in Patent Office: 1,233 Days
• Field of Search: 204/1 TK, 204/402, 204/415, 204/432, 204/400, 204/153.1, 204/153.17
• US Class Current: 205/785.5
• CPC Class Codes: G01N 27/4045 for gases other than oxygen
• CPC Class Codes: G01N 27/48 using polarography, i.e. measuring changes in current under a slowly-varying voltage

Abstract

A method for measuring the amount of an electroactive gas in a gaseous mixture using an electrochemical cell, the cell including a working electrode (anode), counter electrode (cathode), an electrolyte in which oxygen reduction is inhibited, means for applying a variable potential across the electrodes, and means for measuring current flow between the electrode, the method involving contacting the gaseous mixture with the anode, applying a potential across the anode and cathode and cycling the applied potential between a potential level at which the gas in the gaseous mixture adsorbs onto the anode and a potential level at which the adsorbed gas in the gaseous mixture is oxidized, and measuring the current resulting from the anodic sweep portion of the potential cycle as a measure of the amount of the adsorbed gas in the gaseous mixture.

Claims

1. A method for measuring the amount of a predetermined gas in a gaseous mixture using an electrochemical cell having a working electrode, a counter electrode, and an electrolyte, said method comprising

contacting said gaseous mixture with said working electrode, and means for inhibiting the reduction of oxygen at said working electrode,

adsorbing an anion on said working electrode sufficiently strongly to resist its own displacement by oxygen but not so strongly as to resist its own displacement by said predetermined gas,

while said anion is adsorbed, applying a potential across said electrodes and cycling said applied potential, said cycling including an anodic sweep of said applied potential over a range between a potential level at which said predetermined gas in said gaseous mixture adsorbs onto said working electrode and a potential level at which said adsorbed predetermined gas is oxidized, said applied potential range including potentials at which oxygen is subject to reduction, and

measuring the current resulting from said anodic sweep.

2. The method of claim 1 wherein said predetermined gas is CO.

3. The method of claim 2 wherein

said working electrode is a fuel cell electrode on a support comprising an intimate mixture of hydrophobic polymer and platinum catalyst in contact with a current conducting wire,

said electrolyte is a liquid in contact with said working electrode,

said counter electrode is a fuel cell electrode on a support in contact with the upper surface of a separator, said separator being saturated with said liquid electrolyte and having a lower surface and an upper surface, said separator overlying said working electrode and extending past the edges of the support of said working electrode such that the central portion of said lower surface is in contact with said working electrode, said separator having pores of size, size distribution, and overall volume so as to maintain a constant level of saturation of said liquid electrolyte on said working electrode,

said cell further comprises a reference electrode and said reference electrode is a fuel cell electrode on said support supporting said counter electrode and in contact with said upper surface of said separator,

two porous hydrophobic polymer membranes, the first said membrane underlying said working electrode and the second said membrane overlying said counter electrode and said reference electrode, and

said electrochemical cell further comprises

a gas distribution screen underlying said first membrane, and

a housing,

4. The method of claim 1 wherein

said applying and cycling of said applied potential comprises correcting said measurement of said predetermined gas for background conditions by the steps of

(a) initially maintaining said applied potential at a first potential level at which said gaseous mixture adsorbed on said working electrode is oxidized and a protective layer of oxide is formed on said working electrode,

(b) reducing said applied potential to a second potential level at which said protective oxide is reduced,

(c) maintaining said applied potential at said second potential level to permit said predetermined gas in said gaseous mixture to adsorb onto said working electrode,

(d) sweeping said applied potential to a third potential level at which all of said adsorbed gaseous mixture is oxidized and measuring the current resulting from said potential sweep, said steps (a) through (d) comprising a measurement cycle,

(e) repeating steps (a), (b), and (d), said steps (a), (b), and (d) comprising a correction cycle, and

(f) integrating said current resulting from said measurement cycle and the current resulting from the potential sweep step of said correction cycle, the difference in integrals being a measure of said amount of said predetermined gas, corrected for background conditions.

5. The method of claim 1 wherein said anion is provided by a dissociable compound dissolved in said electrolyte.

6. The method of claim 5 wherein said dissociable compound is the acid of (B_z X_z)^-2, where B is boron, X is a halogen and z is equal to 10 or 12.

7. The method of claim 5 wherein said dissociable compound is hydrochloric acid.

8. The method of claim 1 wherein said anion is of the general formula (B_z X_z)^-2, where B is boron, X is a halogen, and z is equal to 10 or 12, or said anion is of the general formula X_-, where X is either chlorine, bromine, or iodine.

9. The method of claim 8, 6, or 7 wherein said electrolyte comprises sulfuric acid.

10. The method of claim 8, 6, or 7 wherein said electrolyte comprises phosphoric acid.