Method of producing hydrogen-rich gas

• US 5,066,476 A
• Filed: 07/06/1990
• Issued: 11/19/1991
• Est. Priority Date: 08/02/1989
• Status: Expired due to Fees

• Current Assignee: Krupp-Koppers GmbH
• Original Assignee: Krupp-Koppers GmbH
• Inventors: Firnhaber, Bernhard, Wetzel, Rolf
• Primary Examiner(s): Langel, Wayne A.
• Application Number:
  US07/550,105
• Time in Patent Office: 501 Days
• Field of Search: 423/648.1, 48/197 R
• US Class Current: 423/648.1
• CPC Class Codes: C01B 2203/047 the impurity being carbon monoxide
• CPC Class Codes: C01B 2203/0475 the impurity being carbon dioxide
• CPC Class Codes: C01B 2203/0485 the impurity being a sulfur compound
• CPC Class Codes: C01B 3/50 Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification C01B3/14 takes precedence
• CPC Class Codes: C10J 2300/1846 Partial oxidation, i.e. injection of air or oxygen only
• CPC Class Codes: C10J 2300/1884 with one stream being synthesis gas
• CPC Class Codes: C10J 3/466 Entrained flow processes
• CPC Class Codes: C10J 3/86 combined with waste-heat boilers
• CPC Class Codes: C10K 1/004 Sulfur containing contaminants, e.g. hydrogen sulfide
• CPC Class Codes: C10K 1/005 Carbon dioxide
• CPC Class Codes: C10K 1/02 Dust removal
• CPC Class Codes: C10K 1/08 by washing with liquids; Reviving the used wash liquors gas washers B01D
• CPC Class Codes: C10K 3/04 reducing the carbon monoxide content , e.g. water-gas shift [WGS]
• CPC Class Codes: Y02P 20/129 Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Abstract

A gas with a hydrogen content of at least 85 volume percent of partial oxidation crude gas is produced in a method including cooling of the gas after waste heat boiler of a gasifier by adding converted circulating gas in a quenching zone. The resulting gas mixture after corresponding gas treatment is subjected to a CO-conversion and then separated into a circulating gas partial stream and a product gas partial stream. The circulating gas partial stream is supplied back after a corresponding compression to the quenching zone, while the product gas partial stream after a so-called acid gas washing is subjected to a further gas treatment in correspondence with a desired use.

Claims

1. A method of producing a hydrogen-rich gas with a hydrogen content of at least 85 volume percent by gasifying of finely grained to pulverulent fuels at temperatures above a slag melting point, comprising the steps of gasifying a finely grained to pulverulent fuel in a gasifier to produce a partial oxidation crude gas;

indirectly cooling the partial oxidation crude gas in a waste heat boiler arranged after the gasifier;

cooling again the partial oxidation crude gas after the waste heat boiler by adding converted circulating gas to the gas mixture;

subjecting the produced gas mixture to a dry de-dusting;

saturating the dedusted gas mixture with the use of a condensate produced during cooling of a product gas partial stream and washing at dew point of the gas mixture;

subjecting the purified gas mixture after heating to a CO-conversion in the presence of a sulfur resistant catalyst in a conversion reactor;

cooling a CO-poor gas leaving the conversion reactor to approximately its water vapor dew point and then subdividing in a circulating gas partial stream and a product gas partial stream;

supplying the circulating gas partial stream after a compression as the converted circulating gas to the partial oxidation crude gas after the waste heat boiler for cooling the partial oxidation crude gas; and

subjecting the product gas partial stream to a cooling for water vapor condensation, a de-sulfurization, a CO₂ removal, and a further gas treatment for a further utilization.

2. A method as defined in claim 1;

and further comprising adding further water vapor to the purified gas mixture for adjusting a ratio of hydrogen to carbon monoxide required for the conversion, prior to the CO-conversion.

3. A method as defined in claim 1, wherein said separation includes separation with a separation ratio x between the circulating gas partial stream and the product gas partial stream in the region between 0.5 and 4.

4. A method as defined in claim 1, wherein said separation includes separation with a separation ratio x between the circulating gas partial stream and the product gas partial stream in the region between 1 and 2.

5. A method as defined in claim 1, wherein said cooling of the partial oxidation crude gas by adding the converted circulating gas includes supplying the partial oxidation crude gas at temperatures between 600°

and 1,450°

C. to a quenching zone and mixing with the converted circulating gas, so that the temperature of the produced gas mixture is lowered to between 200° and

800°

C.

6. A method as defined in claim 5, wherein said supplying of the partial oxidation gas to the quenching zone includes supplying at the temperatures between 800°

and 1,200°

C.

7. A method as defined in claim 5, wherein the temperature of the produced gas mixture is lowered to the value between 300°

and 450°

C.

8. A method as defined in claim 1, wherein said subjecting the purified gas mixture to a CO-conversion includes conversion of the purified gas mixture such that between 60 and 95% of supplied carbon monoxide is converted.

9. A method as defined in claim 1, wherein said subjecting the purified gas mixture to a CO-conversion includes conversion of the purified gas mixture such that between 80 and 95% of supplied carbon monoxide is converted.

10. A method as defined in claim 1;

and further comprising the step of wet washing of the gas mixture, separating a partial stream of a loaded washing water on the wet washing, cleaning the separated partial stream and supplying it to a saturator.

11. A method as defined in claim 1;

and further comprising the steps of continuously analytically monitoring molar CO/H₂ ratio in the product gas partial stream, and maintaining this ratio during operational changes by changing the separation ratio.

12. A method as defined in claim 1;

and further comprising the step of changing the separation ratio by supplying a partial stream of the circulating gas partial stream in a quantity of 0.2 to 1.0 m³ /kg waterfree carbon to burners of the gasifier through a central lance and using the same instead of water vapor for temperature moderation during the gasification.

13. A method as defined in claim 12, wherein said supplying a partial stream of the circulating gas partial stream includes supplying the partial stream in a quantity of 0.3 to 0.6 Nm³ /kg waterfree carbon.