Structure for electrically heatable catalytic core

• US 5,070,694 A
• Filed: 10/31/1990
• Issued: 12/10/1991
• Est. Priority Date: 10/31/1990
• Status: Expired due to Fees

• Current Assignee: Engelhard Corporation (BASF SE)
• Original Assignee: W R Grace & Company - CONN (WR Grace & Company)
• Inventors: Whittenberger, William A.
• Primary Examiner(s): Hart, Douglas
• Application Number:
  US07/606,130
• Time in Patent Office: 405 Days
• Field of Search: 60/300, 422/174, 422/180
• US Class Current: 60/300
• CPC Class Codes: F01N 2330/02 Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal
• CPC Class Codes: F01N 3/2026 directly electrifying the catalyst substrate, i.e. heating the electrically conductive catalyst substrate by joule effect
• CPC Class Codes: F01N 3/2814 all sheets, plates or foils being corrugated
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

There is provided an improved electrically heatable core for an electrically heatable catalytic converter. The core is characterized by a plurality of corrugated thin metal strips secured to an electrically conductive central core or tube. Alternating with the corrugated thin metal strips are narrow strips of brazing metal in an axially staggered pattern. These strips are spirally wound and fused to braze them together in a unified monolith. A retainer shell is supplied to hold the monolith together. The core is placed in a housing fitted with insulated means for conducting electric current to the monolith to effect heating. The housing is then inserted in an exhaust line where it is effective to control start-up pollution, and where the monolith is constrained against telescoping.

Claims

1. An electrically heatable core for an electrically heatable catalytic converter comprising (a) a central electrically conductive core, (b) a monolith wound about said central core including (1) a plurality of corrugated thin metal strips of substantially equal length secured to said central electrically conductive core, and (2) a plurality of fused narrow brazing strips having a width of from about 1/4 to about 1/10 of the width of said corrugated thin metal strips and a length substantially equal to the length of said corrugated thin metal strips, said brazing strips being in alternating relation with said corrugated thin metal strips and in staggered relation with respect to a centrally located plane normal to the longitudinal axis of said central core, said brazing strips being fused to the adjacent corrugated thin metal strips, and (c) a steel retaining shell surrounding said spirally wound monolith.

2. An electrically heatable core as defined in claim 1 having a current conducting binding post radially extending from said steel retaining shell.

3. An electrically heatable core as defined in claim 1 having a current conducting binding post attached to said electrically conducting core.

4. An electrically heatable core as defined in claim 1 wherein the corrugated thin metal strips are secured to the central core at their midpoints.

5. An electrically heatable core as defined in claim 4 wherein the corrugated thin metal strips are spot welded to the central core.

6. An electrically heatable core as defined in claim 1 wherein the corrugated thin metal strips are stainless steel.

7. An electrically heatable core as defined in claim 6 wherein the stainless steel is a ferritic stainless steel.

8. An electrically heatable core as defined in claim 1 wherein the corrugated thin metal strips have a coating of a refractory metal oxide on at least one surface thereof.

9. An electrically heatable core as defined in claim 8 wherein the refractory metal oxide is alumina.

10. An electrically heatable core as defined in claim 8 wherein the refractory metal oxide is gamma alumina.

11. An electrically heatable core as defined in claim 1 wherein a fused layer of thin brazing metal is disposed between the spirally wound monolith and the retaining shell.

12. An electrically heatable core as defined in claim 8 wherein a noble metal catalyst is supported on the refractory metal oxide surface of the corrugated thin metal strips.

13. An electrically heatable core as defined in claim 12 wherein the noble metal is selected from platinum, palladium, rhodium, ruthenium and mixtures of two or more of such metals.

14. An electrically heatable catalytic converter comprising (a) a housing, (b) an end cap at each end of said housing including a nipple adapted to accommodate an exhaust pipe, (c) an electrically heatable core comprising (I) a central electrically conductive core, (II) a monolith spirally wound about said central core including (1) a plurality of corrugated thin metal strips of substantially equal length secured to said central electrically conductive core, and (2) a plurality of fused thin narrow brazing strips having a width of from about 1/4 to about 1/10th of the width of said corrugated thin metal strips and a length substantially equal to the length of said corrugated thin metal strips, said brazing strips being in alternating relation with said corrugated thin metal strips and in staggered relation with respect to a centrally located plane normal to the longitudinal axis of said central core, said brazing strips being fused to the adjacent corrugated thin metal strips, (3) a refractory metal oxide coating on at least one surface of said corrugated thin metal strips, (4) a noble metal catalyst supported on said refractory metal oxide coating, and (III) a steel retaining shell surrounding said spirally wound monolith;

(d) means for electrically insulating said electrically heatable core from said housing, and (e) means for supplying electrical power from a voltage source to said electrically heatable core.