Low level blasting composition

• US 5,071,496 A
• Filed: 05/16/1990
• Issued: 12/10/1991
• Est. Priority Date: 05/16/1990
• Status: Expired due to Fees

• Current Assignee: ETI Canada, Inc. (Incitec Pivot Limited)
• Original Assignee: ETI Explosives Technologies International, Inc.
• Inventors: Flinchman, Rufus, Coursen, David L.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US07/524,375
• Time in Patent Office: 573 Days
• Field of Search: 149/2, 149/21, 149/38, 149/40, 149/41, 149/42, 149/43, 149/47, 149/88, 149/89, 149/92, 102/313, 102/320, 102/322, 102/332
• US Class Current: 149/21
• CPC Class Codes: C06B 45/00 Compositions or products which are defined by structure or arrangement of component of product explosive charges of particular form or shape F42B1/00, F42B3/00
• CPC Class Codes: C06B 47/00 Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
• CPC Class Codes: C06B 47/145 Water in oil emulsion type explosives in which a carbonaceous fuel forms the continuous phase
• CPC Class Codes: E21B 43/263 using explosives
• CPC Class Codes: F42D 1/00 Blasting methods or apparatus, e.g. loading or tamping
• CPC Class Codes: F42D 1/045 Arrangements for electric ignition dynamo-electric generators H02K
• CPC Class Codes: F42D 1/10 Feeding explosives in granular or slurry form; Feeding explosives by pneumatic or hydraulic pressure

Abstract

A blasting agent is disclosed for use in a borehole having a pressure resistant closure. The blasting agent is used in combination with a primary initiating system comprised of a detonator and an initiator for the detonator. The blasting agent is preferably a semi-fluid explosive material having a predetermined sensitivity. The sensitivity is related to the borehole diameter and the initiating system'"'"'s strength, wherein the blasting agent upon initiation is transformed into explosive products by means of reaction front which consumes substantially all the blasting agent as the reaction front passes through the blasting agent. The reaction front has an average velocity of propagation of between 200 meters/second and 1,000 meters/second for at least 30% of the total length of blasting agent located in the borehole. Another aspect of the invention is a method of blasting wherein the average velocity of propagation of the explosive front in the blasting agent is in a range of between 200 m/sec and 1,000 m/sec.

Claims

1. A blasting agent for use in a bore hole having a pressure resistant closure and for use in combination with a primary initiating system comprising a detonator and a means for initiating said detonator, said blasting agent comprising:

a semifluid explosive material having a predetermined sensitivity, having regard to said bore hole diameter and said initiating system'"'"'s strength; and

wherein said blasting agent upon initiation is transformed into explosive products by means of a reaction front which consumes substantially all of said blasting agent as said reaction front passes through said blasting agent, wherein said reaction front has an average velocity of propagation of between 200 m/sec and 1000 m/sec for at least 30% of the total length of blasting agent located in said bore hole.

2. A blasting agent as claimed in claim 1 wherein said predetermined sensitivity is achieved by means of having a regulated content of liquid desensitizing ingredient.

3. A blasting agent as claimed in claim 2 wherein said liquid desensitizing ingredient is water.

4. A blasting agent as claimed in claim 1 wherein said blasting agent comprises 5-10% water;

40-85% inorganic oxidizing salts;

2-45% of fuel, said fuel comprising 0-10% carbonaceous fuels, 0-40% metallic fuel, 0-5.5% of at least one thickening agent and 0-45% of organic nitrate sensitizer, wherein said thickening agents, any gaseous particles, or sensitizers are not counted as fuels, in determining the above ranges.

5. A blasting agent as claimed in claim 4 wherein the inorganic oxidizing salts are selected from the group consisting of ammonium, sodium, potassium and calcium salts of nitric and perchloric acids and mixtures thereof.

6. A blasting agent as claimed in claim 4 wherein the carbonaceous fuels are selected from the group consisting of petroleum, distillation fractions of petroleum, fuel oil, bitumen, ground gilsonite, hydrocarbon oil, paraffin oil, ground coal, carbon black, starch, wood flour, sucrose, ethylene glycol, ethanol, methanol, formamide, and mixtures thereof.

7. A blasting agent as claimed in claim 4 wherein the metallic fuel is selected from the group consisting of flake, atomized, ground, foil aluminum, and powdered ferrosilicon.

8. A blasting agent as claimed in claim 4 in which at least one of the thickening agents is starch selected from the group consisting of maize starch, wheat starch, cassava starch, oat starch, and rice starch with or without purification and including pregelatinized forms thereof.

9. A blasting agent as claimed in claim 4 in which at least one of the thickening agents is an emulsifying agent, at least some of the fuel is a hydrophobic oil, and thickening occurs by shearing, mixing, or agitation to form an emulsion in which the internal phase is aqueous.

10. A blasting agent as claimed in claim 9, where said blasting agent is a semi-fluid aqueous composition, and in which at least some of the hydrophobic oil is a hydrocarbon oil.

11. A blasting agent as claimed in claim 9 in which the emulsifying agent is an alkali metal salt of a straight chain organic acid containing 12 to 22 carbon atoms.

12. A blasting agent as claimed in claim 9 wherein the emulsifying agent is sorbitan mono-oleate.

13. A blasting agent as claimed in claim 11 in which the salt is the sodium or potassium salt of oleic, linoleic, or stearic acids.

14. A blasting agent as claimed in claim 11 in which the salt is formed in place in the explosive composition by adding to the other ingredients an alkali metal hydroxide and a straight chain organic acid containing 12 to 22 carbon atoms.

15. A blasting agent as claimed in claim 9 in which at least one of the thickening agents is a water soluble or water dispersible polymer that can be crosslinked to form a gel and a crosslinker for that polymer, and where thickening occurs by crosslinking the dissolved or dispersed polymer.

16. A blasting agent as claimed in claim 15 in which the thickening agent is chosen from the group consisting of guar gum, polyacrylamide and copolymers of acrylamide and acrylic acid.

17. A blasting agent as claimed in claim 15 in which the crosslinking agent is selected from the group consisting of potassium antimony tartrate/potassium dichromate, sodium tetraborate, potassium pyroantimonate, and Tyzor LA titanium antimonium lactate.

18. A blasting agent as claimed in claim 4 which contains undissolved ammonium nitrate in the form of prills, ground prills, or a mixture of prills and ground prills.

19. A blasting agent as claimed in claim 4 wherein the organic nitrate sensitizer is selected from the group consisting of monomethylammonium nitrate, ethanolammonium nitrate, hexamine dinitrate, ethylene diamine dinitrate, urea nitrate, guanidine nitrate, 1-nitropropane, 2-nitropropane, and ethylene glycol mononitrate.

20. A blasting agent as claimed in claim 1 wherein said semifluid explosive mixture is a nonhomogeneous combination of at least two discreet explosive compositions.

21. A blasting agent as claimed in claim 20 wherein at least a first of said explosive compositions propagates an explosive reaction at velocities which decrease over time, and wherein at least a second of said explosive compositions propagates an explosive reaction at a constant velocity of at least 2000 m/sec, if each of said explosive compositions were to be used for an entire charge in boreholes of the diameter to be loaded with the blasting agent, and were to be initiated with a detonator of a size to be used with the blasting agent.

22. A blasting agent as claimed in claim 21 wherein said first explosive composition has a higher water content than said second explosive composition.

23. A blasting agent as claimed in claim 22 wherein when said blasting agent is in use in said borehole said second explosive composition is in the form of one or more elongated bodies.

24. The blasting agent as claimed in claim 23 wherein said elongated bodies have a ratio of length to thickness greater than 10.

25. A blasting agent as claimed in claim 21 wherein both said first and second explosive compositions are in the form of elongated bodies which are formed by simultaneously pumping streams of each of said explosive compositions into said borehole.

26. A blasting agent as claimed in claim 25 wherein said pumping step includes merging streams of said compositions in a hose.

27. A blasting agent as claimed in claim 21 wherein said explosive compositions are intermingled and have respectively higher and lower sensitivities.

28. A blasting agent as claimed in claim 23 wherein said explosive compositions are formed into elongate bodies and are pumped into a bag.

29. A blasting agent as claimed in claim 21 wherein at least one of said compositions is in the form of an elongate body which has a lower water content and which has a minor dimension of at least 0.5 cm, but not greater than one half the diameter of said borehole, for at least 80% of its volume fraction.

30. A blasting agent as claimed in claim 29 wherein said elongated bodies have a ratio of major dimension to minor dimension of at least 10 and are surrounded by regions of higher water content, and wherein said elongated bodies and said surrounding regions have been folded and compacted to fill substantially the entire bore.

31. A blasting agent as claimed in claim 30 wherein said minor dimension of the elongated bodies is within the range of 0.1 to 0.5 times the diameter of the borehole, and the surrounding regions are of a thickness in the range of 0.01 to 0.25 times said diameter, all prior to being folded and compacted.

32. A blasting agent as claimed in claim 1 or 2 wherein said average velocity of propagation of said reaction front is within the range of 250 m/sec to 700 m/sec for at least 60% of the total length of blasting agent located in said borehole.

33. A blasting agent as claimed in claim 1 or 2 wherein said average velocity of propagation of said reaction front is within the range of 300 m/sec to 600 m/sec for at least 60% of the total length of the blasting agent located in said borehole.

34. A blasting agent as claimed in claim 33 wherein said average velocity is with said range for at least 90% of said total length of blasting agent.

35. A blasting agent as claimed in claim 2 wherein said average velocity of propagation of said reaction front is within the range of 350 m/sec to 500 m/sec for substantially the entire length of said blasting agent located within said borehole.