Complete oil analysis technique

• US 5,071,527 A
• Filed: 06/29/1990
• Issued: 12/10/1991
• Est. Priority Date: 06/29/1990
• Status: Expired due to Term

• Current Assignee: University of Dayton
• Original Assignee: University of Dayton
• Inventors: Kauffman, Robert E.
• Primary Examiner(s): TUNG, TA HSUNG
• Application Number:
  US07/545,842
• Time in Patent Office: 529 Days
• Field of Search: 204/153.1, 204/412, 204/434, 324/439, 324/450
• US Class Current: 205/786
• CPC Class Codes: G01N 27/48 using polarography, i.e. measuring changes in current under a slowly-varying voltage
• CPC Class Codes: G01N 33/03 Edible oils or edible fats
• CPC Class Codes: G01N 33/2805 investigating the resistance to heat or oxidation to the weather, to corrosion, or to light G01N17/00
• CPC Class Codes: G01N 33/2888 Lubricating oil characteristics, e.g. deterioration lubricating properties G01N33/30

Abstract

A method and apparatus is disclosed for the complete analysis of used oils, lubricants, and fluids. The method can monitor antioxidant depletion, oxidation initiators buildup, product buildup, or liquid contamination or combinations thereof. The method can be performed either on-line or off-line but is preferably an on-line system, either a built-in system or a dip-stick type system, having a working microelectrode, a reference electrode, and an auxiliary electrode. A sample is contacted by the electrodes and subjected to cyclic voltammetric analysis, whereby a varying electric current is produced within the sample. The current is measured and recorded, and the conductance is measured. The remaining useful life of the oil, lubricant, or fluid is then determined from the wave heights of the oxidation and reduction peaks, and the contamination is determined from the conductance.

Claims

1. A method for analyzing oil for antioxidant depletion, oxidation initiator buildup, product buildup, or liquid contamination, or combinations thereof, comprising the steps of:

bringing electrodes into contact with a sample of oil;

applying an electric potential of a first value to the sample to produce an electric current therethrough;

varying the potential from the first value to a second value to produce an oxidation reaction;

varying the potential from the second value to the first value to produce a reduction reaction;

varying the potential from the first value to a third value to produce a reduction reaction;

varying the potential from the third value to the first value to produce an oxidation reaction;

measuring and recording the current during the oxidation and reduction reactions; and

measuring the conductance of the oil.

2. The method of claim 1 wherein said electrodes include a working microelectrode, a reference electrode and an auxiliary electrode.

3. The method of claim 1 wherein two or more of antioxidant depletion, oxidation initiator buildup, product buildup or liquid contamination are simultaneously monitored.

4. The method of claim 1, wherein the first, second, and third potential values are within the range of +120 V and -120 V.

5. The method of claim 4, wherein the first, second and third potential values are +30 V, 0 V, and -30 V, respectively.

6. The method of claim 5 wherein the potential is varied at the rate of 1 V/sec.

7. The method of claim 1, wherein the step of bringing electrodes into contact with the sample includes attaching the electrodes on-line.

8. The method of claim 7, wherein the step of measuring and recording the current is done continuously.

9. The method of claim 7, wherein the step of measuring and recording the current is done intermittently.

10. The method of claim 1, wherein the step of bringing electrodes into contact with the sample includes placing the electrodes in an on-line sample reservoir, and then removing the electrodes from the sample reservoir when the analysis is concluded.

11. The method of claim 10, comprising the further step of attaching a temperature probe or heating element to the electrodes.

12. The method of claim 1 wherein the step of bringing electrodes into contact with the sample includes extracting a portion of the oil from the system, mixing with a solvent to produce a sample to be analyzed, and placing the sample into an off-line electrolytic cell.

13. The method of claim 12 wherein the solvent is a nonpolar solvent.

14. An on-line method for analyzing oil for antioxidant depletion, oxidation initiator buildup, product buildup, or liquid contamination, or combinations thereof, comprising the steps of:

attaching electrodes to a source of a sample of oil,

applying an electric potential of a first value to the sample to produce an electric current therethrough;

varying the potential from the first value to a second value to produce an oxidation reaction;

varying the potential from the second value to the first value to produce a reduction reaction;

varying the potential from the first value to a third value to produce a reduction reaction;

varying the potential from the third value to the first value to produce an oxidation reaction;

measuring and recording the current during the oxidation and reduction reactions; and

measuring the conductance of the oil.

15. The method of claim 14 wherein said electrodes include a working microelectrode, a reference electrode and an auxiliary electrode.

16. The method of claim 15 wherein said electrodes are placed in a chamber attached to a use container for said oil.

17. The method of claim 15 wherein said electrodes are placed in a chamber attached to a return line for said oil.

18. An on-line method for analyzing oil for oxidation initiator buildup, product buildup, and liquid contamination, comprising the steps of:

placing electrodes with a temperature probe or heating element attached thereto in an on-line sample reservoir,

applying an electrical potential of a first value to a sample in said on-line sample reservoir to produce an electric current therethrough;

varying the potential from first value to a second value to produce an oxidation reaction;

varying the potential from the second value to the first value to produce a reduction reaction;

varying the potential from the first value to a third value to produce a reduction reaction;

varying the potential from the third value to the first value to produce an oxidation reaction;

measuring and recording the current during the oxidation and reduction reactions;

measuring the conductance of the oil and

removing the electrodes and temperature probe or heating element from said on-line sample reservoir when the analysis is concluded.

19. The method of claim 18 wherein said electrodes include a working microelectrode, a reference electrode and an auxiliary electrode.