Composition and method for purifying water

• US 5,071,587 A
• Filed: 05/31/1990
• Issued: 12/10/1991
• Est. Priority Date: 05/31/1990
• Status: Expired due to Term

• Current Assignee: Aqua Technica, Inc.
• Original Assignee: Aquatechnica Incorporated
• Inventors: Perman, Craig A.
• Primary Examiner(s): Silverman, Stanley S.
• Assistant Examiner(s): McCarthy, Neil M.
• Application Number:
  US07/531,346
• Time in Patent Office: 558 Days
• Field of Search: 210/702, 210/714, 210/723, 210/724, 210/725, 210/728, 210/729, 210/732-736, 210/679, 210/691, 210/694, 210/753, 210/754, 210/764, 252/175, 252/180, 252/181, 502/62, 502/63, 502/64, 502/67, 502/68, 502/72, 502/402, 502/514, 106/15.05, 106/18.35, 106/18.32
• US Class Current: 252/181
• CPC Class Codes: C02F 1/002 using small portable filters for producing potable water, e.g. personal travel or emergency equipment, survival kits, combat gear C02F1/003 takes precedence
• CPC Class Codes: C02F 1/283 using coal, charred products, or inorganic mixtures containing them
• CPC Class Codes: C02F 1/50 by addition or application of a germicide or by oligodynamic treatment C02F1/4606, C02F1/467, C02F1/76 take precedence
• CPC Class Codes: C02F 1/52 by flocculation or precipitation of suspended impurities C02F1/463 takes precedence
• CPC Class Codes: C02F 1/54 using organic material
• CPC Class Codes: Y10S 502/514 Process applicable either to preparing or to regenerating or to rehabilitating catalyst or sorbent

Abstract

The present invention provides a composition in dry form, preferably in the form of a tablet, containing a combination of ingredients which upon addition to contaminated water effectively removes turbidity, metal and organic contaminants in the water and thereby makes the water safer for drinking. The composition is particularly useful for personal use so that safe drinking water can be obtained by the simple addition of the composition to the water to remove the turbidity and contaminating materials contained therein. Preferably the composition contains bentonite clay, attapulgite clay, polymeric coagulant and/or flocculent, biocide, zeolite and activated charcoal. The invention also provides a method for treating water with the composition as well as a method for making the composition.

Claims

1. A composition for purifying water which comprises bentonite clay selected from the group consisting of swelling bentonite and acid activated bentonite;

zeolite;

biocide and an anionic or cationic polymeric ingredient selected from the group consisting of polymeric flocculents and coagulants;

said composition being in the form of a substantially dry powder;

said polymeric ingredient being cationic when the composition contains swelling bentonite and anionic when the composition contains acid activated bentonite and said polymeric ingredient being present in an amount to substantially neutralize the charge on the bentonite contained in the composition whereby flocs containing the bentonite clay are formed when said composition is added to water.

2. The composition of claim 1 which further contains attapulgite clay and the polymeric ingredient is contained in the composition in an amount to substantially neutralize the charge on the bentonite and attapulgite clay contained in the composition whereby flocs containing the bentonite and attapulgite are formed.

3. The composition of claim 2 wherein the bentonite is swelling bentonite.

4. The composition of claim 2 wherein the polymeric ingredient is a flocculent selected from the group consisting of polyacrylamide, polyacrylamide/acrylic acid copolymer and polyacrylamide/acrylate copolymer.

5. The composition of claim 4 wherein the ratio of bentonite to attapulgite clay is at least 1.5 to 1.

6. The composition of claim 2 wherein the polymeric ingredient is a coagulant selected from the group consisting of polydiallyldimethyl ammonium chloride;

quaternary condensation polymers of epichlorohydrin and dimethyl amine; and

quaternary ammonium vinyl polymers.

7. The composition of claim 4 which further includes a binder and the powder is formed into a tablet.

8. The composition of claim 6 which further includes a binder and the powder is formed into a tablet.

26. The composition of claim 1 wherein the biocide is sorbed into the bentonite, attapulgite or zeolite.

27. The composition of claim 2 wherein the polymeric material is sorbed on the attapulgite clay.

9. A composition for purifying water which consists of 100 parts by weight of swelling bentonite;

attapulgite clay in an amount up to about 67 parts by weight;

zeolite in an amount up to about 100 parts by weight;

activated charcoal in an amount up to about 100 parts by weight;

biocide in an amount up to about 1.5 parts by weight and polymeric flocculent in an amount up to about 2.5 parts by weight;

said biocide being selected from the group consisting of tetraglycine hydroperiodide and sodium dichloroisocyanurate; and

said flocculent being selected from the group consisting of cationic polyacrylamide, cationic polyacrylamide/acrylic acid copolymer and cationic polyacrylamide/acrylate copolymer; and

said composition being in the form of a substantially dry powder.

10. The composition of claim 9 which consists essentially of 100 parts by weight of swelling bentonite;

38.6 parts by weight of attapulgite clay;

100 parts by weight of zeolite;

38.6 parts by weight of activated charcoal;

1.04 parts by weight of biocide and .05 parts by weight of polyacrylamide.

11. The composition of claim 9 which further includes 25 parts by weight of binder and said composition is formed into a tablet.

12. A composition for purifying water which consists essentially of 100 parts by weight of acid activated bentonite;

attapulgite clay in an amount up to about 67 parts by weight;

zeolite in an amount up to about 67 parts by weight;

NaH₂ PO₄ in an amount up to about 2.4 parts by weight;

NaHCO₃ in an amount up to about 60 parts by weight of;

sodium dichloroisocyanurate in an amount up to about 8 parts by weight;

polymeric flocculent in an amount up to about 2 parts by weight; and

binder in an amount up to about 25 parts by weight;

wherein said flocculent is selected from the group consisting of anionic polyacrylamide, anionic polyacrylamide/acrylic acid copolymer and anionic polyacrylamide/acrylate copolymer; and

said composition is a substantially dry powder in the form of a tablet.

13. The composition of claim 12 which consists essentially of 100 parts by weight of acid activated bentonite;

about 59.5 parts by weight of attapulgite clay;

about 67 parts by weight of zeolite;

about 2 parts by weight of NaH₂ PO₄ ;

about 4 parts by weight of NaHCO₃ ;

about 6 parts by weight of sodium dichloroisocyanurate;

about 0.4 parts by weight of polyacrylamide/acrylate copolymer and about 19.8 parts by weight of microcrystalline cellulose binder.

14. A composition for purifying water which consists essentially of 100 parts by weight of acid activated bentonite;

silica gel in an amount up to about 62 parts by weight;

biocide in an amount up to about 6.8 parts by weight;

NaHCO₃ in an amount up to about 41 parts by weight;

polymeric flocculent in an amount up to about 1.0 parts by weight; and

binder in an amount up to about 55 parts by weight;

wherein said flocculent is selected from the group consisting of anionic polyacrylamide, anionic polyacrylamide/acrylic acid copolymer and anionic polyacrylamide/acrylate copolymer and said biocide is selected from the group consisting of sodium dichloroisocyanurate and tetraglycine hydroperiodide and said composition is a substantially dry powder in the form of a tablet.

15. The composition of claim 14 which consists of 100 parts by weight of activated bentonite;

about 49 parts by weight of silica gel;

about 4.1 parts by weight of sodium dichloroisocyanurate;

about 13.7 parts by weight of NaHCO₃ ;

about 0.3 parts by weight of polyacrylamide/acrylate flocculant and about 13.7 parts by weight of sodium carboxymethyl cellulose binder.

16. A composition for purifying water which consists essentially of 100 parts by weight of acid activated bentonite;

zeolite in an amount up to about 67 parts by weight;

silica gel in an amount up to about 63 parts by weight;

disodium pyrophosphate in an amount up to about 30 parts by weight;

sodium dichloroisocyanurate in an amount up to about 5 parts by weight;

polymeric flocculent in an amount up to about 0.25 parts by weight;

NaHCO₃ in an amount up to about 38 parts by weight; and

binder in an effective amount for forming the composition into a tablet;

said flocculent being selected from the group consisting of anionic polyacrylamide, anionic polyacrylamide/acrylic acid copolymer and anionic polyacrylamide/acrylate copolymer; and

said composition being a substantially dry powder in the form of a tablet.

17. A composition for purifying water which consists essentially of 100 parts by weight of swelling bentonite;

attapulgite clay in an amount up to about 66 parts by weight;

zeolite in an amount up to about 63 parts by weight;

biocide in an amount up to about 5.7 parts by weight;

polymeric flocculent in an amount up to about 5.7 parts by weight;

disodium pyrophosphate in amount up to about 34.3 parts by weight; and

binder;

said binder being present in an amount effective for forming the composition into a tablet;

said biocide being selected from the group consisting of tetraglycine hydroperiodide and sodium dichloroisocyanurate;

said polymeric flocculent selected from the group consisting of cationic polyacrylamide, cationic polyacrylamide/acrylic acid copolymer and cationic polyacrylamide/acrylate copolymer; and

said composition being a substantially dry powder in the form of a tablet.

18. The composition of claim 17 which consists essentially of 100 parts by weight of swelling bentonite;

about 42.9 parts by weight of attapulgite clay;

about 42.9 parts by weight of zeolite;

about 4.3 parts by weight of biocide;

about 5.7 parts by weight of polyacrylamide/acrylate copolymer;

about 28.6 parts by weight of NaHCO₃ ;

about 28.6 parts by weight of disodiumpyrophosphate and about 14.3 parts by weight of binder.

19. A composition for purifying water which consists essentially of 100 parts by weight of swelling bentonite;

about 46.2 parts by weight of attapulgite clay;

about 40 parts by weight of synthetic type A zeolite in sodium form;

about 3.7 parts by weight of polydiallyldimethyl ammonium chloride;

about 4.6 parts by weight of sodium dichoroisocyanurate;

about 30.8 parts by weight of NaHCO₃ ;

about 30.8 parts by weight of disodiumpyrophosphate;

said composition being in the form of a substantially dry powder.

20. The composition of claim 19 in the form of a tablet;

said composition additionally containing an effective amount of microcrystalline cellulose binder for forming the composition into a tablet.

21. A method of treating turbid contaminated water which comprises forming flocs in a container of water by dispersing the composition of claim 19 in the water;

allowing the flocs to settle; and

then separating the water from the flocs by means of decantation or filtration.

22. The method of claim 21 wherein the flocs are separated from the water by filtering the water containing the flocs through a filter having holes small enough to prevent the passage of the flocs therethrough and large enough to allow the turbidity to flow therethrough before treatment of the water.

23. A composition for purifying water, said composition formed by pretreating a dry solid powder with a liquid biocide;

said powder being selected from the group consisting of swelling bentonite, acid activated bentonite, attapulgite clay, zeolite and mixtures thereof;

drying the pretreated powder and then blending the powder with a polymeric flocculent or polymeric coagulant said polymeric flocculent and coagulant being cationic when the composition contains swelling bentonite and anionic when the composition contains acid activated bentonite.

24. The composition of claim 23 wherein the zeolite is first blended with a powder selected from the group consisting of swelling bentonite, acid-activated bentonite, attapulgite clay and mixtures thereof;

wherein said blending is performed by tumbling the ingredients in a tumbler with ceramic balls or pellets contained therein to break up the zeolite to form a homogeneous powder mixture;

said tumbling operation being conducted before the pretreatment step.

25. The composition of claim 23 wherein the polymeric coagulant has been sorbed onto the attapulgite clay by wetting the clay with an aqueous solution of polymeric coagulant and then allowing the solution to dry.