Process for odor control

• US 5,071,622 A
• Filed: 09/15/1989
• Issued: 12/10/1991
• Est. Priority Date: 09/15/1989
• Status: Expired due to Fees

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Dunson, James B. Jr.
• Primary Examiner(s): Warden, Robert J.
• Assistant Examiner(s): Blythe, Stephanie
• Application Number:
  US07/406,480
• Time in Patent Office: 816 Days
• Field of Search: 422/1, 422/5, 210/916, 424/76.5, 424/76.6, 424/76.7
• US Class Current: 422/5
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: Y10S 210/916 Odor, e.g. including control or abatement

Abstract

This invention relates to a process for reducing odor perceived by a nearby community from an odor-emitting system, e.g., sewage treatment, etc., by adsorbing on core particles, as described, condensible components present in the system. The malodorous components then cannot adsorb in a film of condensible components on the aerosol to be carried by the aerosol plume into the surrounding community, but remain with the humid gas plume to be dispersed upward into the atmosphere. The process is useful for any system which contains condensible components and malodorous components and whose emissions form aerosols.

Claims

1. A process for substantially reducing the odor perceived by the community of an aerosol plume emitted from an odor-emitting system, the system having malodorous, low-boiling, hydrophobic components and relatively nonmalodorous, high-boiling, condensible, hydrophobic components, and water, the process comprising (a) contacting the relatively nonmalodorous, high-boiling, condensible, hydrophobic components of the water-containing odor-emitting system with effective amounts of water insoluble core particles reactive with or adsorptive to the relatively nonmalodorous, high-boiling, condensible, hydrophobic components, said particles having substantially all their surfaces exposed on the exterior of the particles, whereby the relatively nonmalodorous, high-boiling, condensible, hydrophobic components react with or are adsorbed to the core particles forming a coating thereon, thus substantially preventing the formation on the aerosol of a film of the relatively nonmalodorous, high-boiling, condensible, hydrophobic components which would entrap the malodorous, low-boiling, hydrophobic components on said aerosol, (b) preventing the relatively nonmalodorous, high-boiling, condensible, hydrophobic components from being carried into the community with said aerosol plume, and (c) dispersing residual malodorous, low-boiling, hydrophobic components into the atmosphere.

2. A process according to claim 1 wherein a portion of the malodorous, low boiling, hydrophobic components are entrapped in the relatively nonmalodorous, high-boiling, condensible hydrophobic components attached to the core particles.

3. A process according to claim 1 wherein the core particles have a mass-average minimum dimension between 0.01 to 10 micrometers.

4. A process according to claim 1 wherein the external surface area of the core particles is 1 to 400 square meters per gram.

5. A process according to claim 1 wherein the core particles are inorganic compounds selected from the group consisting of hydrated iron (III) oxide, hydrated aluminum hydroxide, hydrated zirconium oxide, hydrated manganese (IV) oxide, hydrated silica, iron sulfide, copper sulfide, zinc sulfide, calcium sulfate, barium sulfate, aluminum phosphate, and iron phosphate.

6. A process according to claim 5 wherein the core particles are hydrated iron (III) oxide.

7. A process according to claim 6 wherein the hydrated iron (III) oxide particles are formed in the system in situ.

8. A process according to claim 7 wherein the hydrated iron (III) oxide particles are precipitated by mixing an aqueous solution of ferric chloride (1 to 30 percent) and hydrochloric acid (0.05 to 1 percent), with an aqueous solution of sodium hydroxide (0.05 to 50 percent), wherein all percentages are by weight.

9. A process according to claim 1 wherein the core particles are organic compounds selected from the group consisting of starch, dextrin, cellulose, cellulose derivatives, metal precipitates of lignins and tannins, poly(cellulose acetate), polyesters, poly(vinyl ester), polyamides and polydiphenyl ether.

10. A process according to claim 3 wherein the core particles are in the form selected from the group consisting of colloidal, granular, fibrous, film, flake, fabric, and combinations thereof.

11. A process according to claim 1 wherein the malodorous, low-boiling, hydrophobic components are selected from the group consisting of organic aliphatic amines, pyridine, skatole, organic mercaptans, alkylsulfides, and dimethyldisulfide.

12. A process according to claim 1 wherein the condensible, relatively non-malodorous, high-boiling, condensible, hydrophobic components are selected from the group consisting of edible oils, animal fats, free fatty acids, greases, terpenes, waxes, and hydrocarbons.

13. A process according to claim 1 wherein the reactivity or adsorptivity of the core particles is enhanced by chemically treating the particle surfaces with oxidizing agents or reducing agents.

14. A process according to claim 13 wherein the oxidizing agent is hydrogen peroxide.

15. A process according to claim 1 wherein the reactivity or adsorptivity of the core particles is enhanced by adjusting the pH of the water phase environment in which the particle is suspended.

16. A process according to claim 1 wherein the reactivity or adsorptivity of the core particles is enhanced by applying a coupling agent to the particles.

17. A process according to claim 16 wherein the coupling agents are selected from the group consisting of rosin, tannic acid, aspirin, lecithin, odorless soaps, monosodium glutamate, urea, sucrose, dextrose, glucose, soluble starch, pyrogallol, organic zirconates, organic titanates, and organic silanes.

18. A process according to claim 12 wherein the core particles are hydrated iron (III) oxide.

19. A process according to claim 18 wherein a portion of the malodorous, low boiling hydrophobic components are adsorbed onto the relatively nonmalodorous, high-boiling, condensible, hydrophobic components attached to the core particles.

20. A process according to claim 1 wherein the core particles are hydrated iron (III) oxide activated by tannic acid.

21. A process according to claim 1 wherein the core particles are hydrated iron (III) oxide activated by lecithin.

22. A process according to claim 12 wherein the core particles are hydrated iron (III) oxide activated by tannic acid.

23. A process according to claim 12 wherein the core particles are hydrated iron (III) oxide activated by lecithin.

24. A process according to claim 1 wherein the core particles are the reaction product of ferrous sulfate and tannic acid with hydrogen peroxide which adsorbs, relatively nonmalodorous, high-boiling condensible hydrophobic phenols.

25. A process according to claim 1 wherein the core particles are the reaction product of ferric chloride and lecithin and the, relatively nonmalodorous, high-boiling condensible hydrophobic components are fatty acids.

26. A process according to claim 1 wherein the core particles are dextrin from corn syrup and the relatively nonmalodorous, high boiling condensible hydrophobic components are terpenoid phenolics.

27. A process according to claim 1 wherein the core particles are the product of ferrous chloride and hydrogen peroxide and the, relatively nonmalodorous, high-boiling condensible hydrophobic components ar phenolic compounds.

28. A process according to claim 1 wherein the core particles are manganese (IV) oxide and the relatively nonmalodorous, high-boiling condensible hydrophobic components are phenolic compounds.

29. A process according to claim 1 wherein the core particles are hydrated silica.

30. A process according to claim 1 wherein the core particles have an electrical charge opposite to that of the relatively nonmalodorous, high-boiling, condensible, hydrophobic components or have a chemical functionality that reacts with or adsorbs to the relatively nonmalodorous, high-boiling, condensible, hydrophobic components.